无氟连铸保护渣冶金性能的研究进展

doi:10.11896/cldb.20100199

材料导报

2022, Vol. 36

Issue (11): 20100199-7 https://doi.org/10.11896/cldb.20100199

金属与金属基复合材料

无氟连铸保护渣冶金性能的研究进展

韩秀丽¹, 赵凯², 刘磊¹, 闫晓鹏², 杜亮¹, 王程¹

1 华北理工大学矿业工程学院,河北唐山 063210
2 华北理工大学冶金与能源学院,河北唐山 063210

Research Progress of Metallurgical Properties of Fluorine-free Continuous Casting Mold Fluxes

HAN Xiuli¹, ZHAO Kai², LIU Lei¹, YAN Xiaopeng², DU Liang¹, WANG Cheng¹

1 College of Mining Engineering, North China University of Science and Technology, Tangshan 063210, Hebei, China
2 College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, Hebei, China

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摘要传统保护渣含较多的氟化物,会造成连铸设备腐蚀和环境污染等问题,保护渣无氟化已然成为绿色冶金的客观要求。目前无氟保护渣的研究取得了一定进展,但其冶金性能不稳定,在工业生产中尚未得到广泛应用,仍有一些性能的影响机理和机制有待深入探究。因此,本文从无氟保护渣的熔化性能、粘度性能以及结晶性能三个方面综述了近年来国内外关于结晶器无氟保护渣冶金性能的研究现状,分析了无氟保护渣各项物化性能研究成果,并对目前无氟保护渣的工业应用进行总结,指出了连铸无氟保护渣进一步的研究方向,即从分子动力学和热力学方面研究熔渣成分、结构对其性能的影响,旨在为绿色无氟保护渣的开发提供理论依据。

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关键词: 保护渣无氟冶金性能连铸

Abstract: Traditional mold fluxes contain a large quantity of fluorides, which will corrode continuous casting equipment and pollute the environment. Non-fluorination of mold fluxes has been an objective requirement of green metallurgy. Although significant progresses has been achieved in the relevant research, the unstable metallurgical performances of fluorine-free mold fluxes limit their industrial applications, and the factors influencing the metallurgical properties remain undetermined. This paper reviews the worldwide efforts in exploring the metallurgical properties of fluorine-free mold fluxes in recent years, including melting properties, viscosity properties and crystallization properties, and analyzes relevant research results of various physical and chemical properties. It also contains a summary of current industrial applications of fluorine-free mold fluxes and a prospective discussion on the future trends, in which further investigations on the influence of composition and structure of slag on its performance from the aspects of molecular dynamics and thermodynamics are suggested. This review is expected to provide some guidance for the development of fluorine-free mold fluxes.

Key words: mold fluxes fluorine-free metallurgical properties continuous casting

发布日期: 2022-06-09

ZTFLH:

TF777

基金资助: 国家自然科学基金(51774140;51574105);河北省高校基本科研业务费项目(JQN2020038);河北省研究生创新资助项目(CXZZBS2021101)

通讯作者: hanxl1965@126.com

作者简介: 韩秀丽,华北理工大学教授,博士研究生导师。1987年河北地质学院矿产普查与勘探专业本科毕业,1994年北京科技大学矿产普查与勘探专业硕士研究生毕业,自1987年至今,在华北理工大学矿业工程学院工作。主要研究方向为工艺矿物学及矿物材料。近年来,主持完成国家自然科学基金项目4项、河北省自然科学基金及科技攻关项目12项,完成河北钢铁集团等企业横向课题60余项,获省部级科技进步奖5项,出版著作3部,发表学术论文100余篇。

引用本文:

韩秀丽, 赵凯, 刘磊, 闫晓鹏, 杜亮, 王程. 无氟连铸保护渣冶金性能的研究进展[J]. 材料导报, 2022, 36(11): 20100199-7.
HAN Xiuli, ZHAO Kai, LIU Lei, YAN Xiaopeng, DU Liang, WANG Cheng. Research Progress of Metallurgical Properties of Fluorine-free Continuous Casting Mold Fluxes. Materials Reports, 2022, 36(11): 20100199-7.

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http://www.mater-rep.com/CN/10.11896/cldb.20100199 或 http://www.mater-rep.com/CN/Y2022/V36/I11/20100199

1 Liu G Z. China Metallurgy, 2013, 23(8), 38(in Chinese).
刘国志. 中国冶金, 2013, 23(8), 38.
2 Wang X J, Wu B B, Zhu L G, et al. Foundry Technology, 2016, 37(9), 1914(in Chinese).
王杏娟, 武宾宾, 朱立光, 等. 铸造技术, 2016, 37(9), 1914.
3 Wang X J, Qu S, Liu Ran, et al. Materials Reports, 2021, 35(Z1), 467(in Chinese).
王杏娟, 曲硕, 刘然, 等. 材料导报, 2021, 35(Z1), 467.
4 Tang P, Gao J X, Wen G H. Steelmaking, 2017, 33(3), 1(in Chinese).
唐萍, 高金星, 文光华. 炼钢, 2017, 33(3), 1.
5 Xu K P. Study of Al₂O₃ dissolution into mold flux for high manganese high aluminum steel. Master's Thesis, Chongqing University, China, 2018(in Chinese).
徐坤朋. 高锰高铝钢保护渣吸收Al₂O₃夹杂的研究. 硕士学位论文, 重庆大学,2018.
6 Zhang C, Cai D X. In: Conference Record of the 16th China Annual Steelmaking Conference. Shenzhen, 2010, pp. 432.
7 Zhang L, Wang W L, Shon I L, et al. In: Conference Record of the 11th China Iron and Steel Annual Meeting. Beijing, 2017, pp. 134.
8 Qiu B, Yuan S Q, Cao Y L, et al. Continuous Casting, 2009(2), 44(in Chinese).
邱斌, 袁守谦, 曹余良, 等. 连铸, 2009(2), 44.
9 Chen Y Y, Li X Y, Xu J Y, et al. Wide and Heavy Plate, 2019, 25(5), 26(in Chinese).
陈永艳, 李晓阳, 徐金岩, 等. 宽厚板, 2019, 25(5), 26.
10 Cai Z Y. Effects of CeO₂ on physical and chemical properties of mold flux for casting rare earth alloy heavy rail steel. Ph.D. Thesis, University of Science and Techonogy Beijing, China, 2019(in Chinese).
蔡泽云. CeO₂对稀土重轨钢保护渣物化性能的影响研究. 博士学位论文, 北京科技大学, 2019.
11 Liu Y Q, Tang P, Wen G H, et al. The Chinese Journal of Nonferrous Metals, 2006(3), 550(in Chinese).
刘永庆, 唐萍, 文光华,等. 中国有色金属学报, 2006(3), 550.
12 Zhu L G, Wang X J. Theories and application of continuous casting mold fluxes, Metallurgical Industry Press, China, 2015(in Chinese).
朱立光, 王杏娟. 连铸保护渣理论与实践, 冶金工业出版社, 2015.
13 Qiu B. Study on fluoride-free mold flux of thin slab continous casting. Master's Thesis, Xi'an University of Architecture and Technology, China, 2009(in Chinese).
邱斌. 薄板坯连铸无氟保护渣的研究.硕士学位论文, 西安建筑科技大学, 2009.
14 Wu B B. Study on metallurgical behavior of fluorine free mold powder. Master's Thesis, North China University of Science and Technology, China, 2017(in Chinese).
武宾宾. 无氟连铸保护渣冶金行为研究.硕士学位论文, 华北理工大学, 2017.
15 Zhang F, Wang Y C, Dong F, et al. Special Steel, 2010, 31(4), 28(in Chinese).
张芳, 王艺慈, 董方,等. 特殊钢, 2010, 31(4), 28.
16 Shen L, Chou S T, Liu Z H, et al. Research on Iron and Steel, 2009, 37(5), 54(in Chinese).
沈乐, 仇圣桃, 刘志宏,等. 钢铁研究, 2009, 37(5), 54.
17 Liu Y Q. Study on melting and rheological properties of fluoride-free mold fluxes. Master's Thesis, Chongqing University, China, 2006(in Chinese).
刘永庆.连铸无氟结晶器保护渣的熔融及流变特性研究.硕士学位论文, 重庆大学, 2006.
18 Koyama K, Nagano K, Nagano Y, et al. Nippon Steel Technical Report, 1987,34,41.
19 Pinheiro C A M, Samarasekera I V, Brimacombe J K, et al. Ironmaking & Steelmaking, 2000, 27(2),144.
20 Cao W S, Gao X J, He R F. Special Steel, 2021, 42(1), 25(in Chinese).
曹树卫, 高新军, 贺瑞飞. 特殊钢, 2021, 42(1), 25.
21 Sun L G,Jia S,Li X. Continuous Casting, 2020(4), 70(in Chinese).
孙丽钢,贾生,李鑫. 连铸, 2020(4), 70.
22 Wang X J, Jin H B, Zhu L G, et al. Materials Reports B:Research Papers, 2019, 33(8), 1395(in Chinese).
王杏娟,靳贺斌,朱立光, 等. 材料导报:研究篇,2019,33(8),1395.
23 Wang X J, Wu B B, Zhu L G, et al. Iron Steel Vanadium Titanium, 2017, 38(4), 135(in Chinese).
王杏娟, 武宾宾, 朱立光, 等. 钢铁钒钛, 2017, 38(4), 135.
24 Zhang L, Wang W L, Xie S L, et al. Journal of Non-Crystalline Solids, 2017, 460, 113.
25 Fox A B, Mills K C, Lever D, et al. ISIJ International, 2005, 45(7), 1051.
26 Li G R, Wang H M, Li J S, et al. Special Steel, 2005(3), 16(in Chinese).
李桂荣, 王宏明, 李敬生, 等. 特殊钢, 2005(3), 16.
27 Liu Y Q, Tang P, Wen G H, et al. The Chinese Journal of Nonferrous Metals, 2006(3), 550(in Chinese).
刘永庆, 唐萍, 文光华,等. 中国有色金属学报, 2006(3), 550.
28 Zhang Y F, Han X L, Liu L, et al. Research on Iron and Steel, 2016, 44(1), 58(in Chinese).
张翼飞, 韩秀丽, 刘磊,等. 钢铁研究, 2016, 44(1), 58.
29 Nakada H, Susa M, Seko Y, et al. ISIJ International, 2008, 48(4), 446.
30 Susa M, Mills K C, Richardson M J, et al. Ironmaking & Steelmaking, 1994, 21(4), 279.
31 Han X L, Li C C, Liu L N, et al. Advanced Materials Research Vols, 2011, 284, 1253.
32 Liu L N, Han X L, Li C C, et al. Advanced Materials Research Vols, 2011, 284, 1311.
33 Jia B, Shi J L, Wen G H, et al. Journal of Iron and Steel Research, 2006(2), 21(in Chinese).
贾碧, 施金良, 文光华,等. 钢铁研究学报, 2006(2), 21.
34 Miao S T, Wen G H, Tang P, et al. Journal of Iron and Steel Research, 2006(10), 20(in Chinese).
苗胜田, 文光华, 唐萍,等. 钢铁研究学报, 2006(10), 20.
35 Dong F, Wang Y C, Wang B F. Special Steel, 2006, 27(6), 7(in Chinese).
董方, 王艺慈, 王宝峰. 特殊钢, 2006, 27(6), 7.
36 Xiao M Y, Wang Y C, Zhang F, et al. Foundry Technology, 2010, 31(7), 918(in Chinese).
肖茂元, 王艺慈, 张芳,等. 铸造技术, 2010, 31(7), 918.
37 Xue Z Q, Dong F. Science & Technology of Baotou Steel, 2015, 41(4), 55(in Chinese).
薛志强, 董方. 包钢科技, 2015, 41(4), 55.
38 Wang Y C, Zhang F, Dong F. Foundry Technology, 2010, 31(1), 88(in Chinese).
王艺慈, 张芳, 董方. 铸造技术, 2010, 31(1), 88.
39 Zhang H Z, Li S C. Xinjiang Iron and Steel, 2011(4), 15(in Chinese).
张怀忠, 李世晨. 新疆钢铁, 2011(4), 15.
40 Mills K C, Courtney L, Fox A B, et al. Thermochimica Acta, 2002, 391(1-2), 175.
41 Zhao Y H, Tang P, Wen G H. The Chinese Journal of Process Enginee-ring, 2008, 8(S1), 205(in Chinese).
赵艳红, 唐萍, 文光华. 过程工程学报, 2008, 8(S1), 205.
42 Liu H, Wen G H, Tang P. The Chinese Journal of Process Engineering, 2008, 8(S1), 266(in Chinese).
刘慧, 文光华, 唐萍. 过程工程学报, 2008, 8(S1), 266.
43 Sardemann J, Schrewe H. Steelmaking Conference Processings, 1991, 74(4), 719.
44 Kashiwaya Y, Cicutti C E, Cramb A W, et al. ISIJ International, 1998, 38(4), 348.
45 Liu L. Study on influence rules of mineral composition on crystallization properties for casting mold powder. Master's Thesis, Hebei United University, China, 2013(in Chinese).
刘磊. 连铸保护渣矿物成分对其结晶性能的影响规律研究. 硕士学位论文, 河北联合大学, 2013.
46 Taylor R. Ironmaking & Steelmaking, 1998, 15(4), 187.
47 Miao S T. Research on crystallization properties of the fluoride-free mold fluxes based on TiO₂. Master's Thesis, Chongqing University, China, 2006(in Chinese).
苗胜田. 含钛无氟连铸结晶器保护渣结晶性能研究.硕士学位论文, 重庆大学, 2006.
48 Zhang L X. World Metals, 2017(B3), 7(5), 129(in Chinese).
张莉霞. 世界金属导报, 2017(B3), 7(5), 129.
49 Wang Z, Shu Q F, Hou X M, et al. Ironmaking & Steelmaking, 2012, 39(3), 210.
50 Han W D, Chou S T, Zhang X Z, et al. Journal of Iron and Steel Research, 2007(3), 14(in Chinese).
韩文殿, 仇圣桃, 张兴中,等, 钢铁研究学报, 2007(3), 14.
51 Wang W L, Cai D X, Zhang L. ISIJ International,2018,58(11),1957.
52 Wang Q, Lu Y J, He S P, et al. Ironmaking & Steelmaking, 2011, 38(4), 297.
53 Wei J. Fundamental research of low-fluorine/fluorine-free mold fluxes for casting medium carbon steel. Master's Thesis, Central South University, China, 2014(in Chinese).
魏娟. 中碳钢低氟/无氟连铸结晶器保护渣的基础研究.硕士学位论文, 中南大学, 2014.
54 Cai D X, Wang W L, et al. Journal of Iron and Steel Research International, 2019, 26(4), 385.
55 Cai D X, Zhang C. Journal of Inner Mongolia University of Science and Technology, 2012, 31(3), 247(in Chinese).
蔡得祥, 张晨. 内蒙古科技大学学报, 2012, 31(3), 247.
56 Wang W L, Cramb A W. ISIJ International, 2005, 45(12), 1864.
57 Ozawa S, Susa M, Goto T, et al. ISIJ International, 2006, 46(3), 413.
58 Chen J Y, Wang W L, Zhou L J, et al. Journal of Iron and Steel Research International, 2021, 28(5), 552.
59 Costa I T D, Cássio S C, José R O, et al. Journal of Materials Research and Technology, 2019, 3(4), 253.
60 Yang J, Zhang J, Ostrovski O, et al. Metallurgical and Materials Transa-ctions B, 2019, 50(4), 1766.
61 Zhu L G, Yuan Z P, Xiao P C, et al. Iron & Steel, 2020, 55(11), 69(in Chinese).
朱立光, 袁志鹏, 肖鹏程, 等. 钢铁, 2020, 55(11), 69.
62 Shibata H, Kondo K, Suzuki M, et al. ISIJ International, 1996, 36(S1), 179.
63 Zhao C B, Li X Y, Xu J Y, et al. Wide and Heavy Plate, 2020, 26(3), 15(in Chinese).
赵春宝, 李晓阳, 徐金岩等. 宽厚板, 2020, 26(3), 15.
64 Klug J L, Pereira M M S M, Nohara E L, et al. Ironmaking & Steelma-king, 2016, 43(8), 559.
65 Wen G H, Sridhar S, Tang P, et al. ISIJ International, 2007, 47(8), 1117.
66 Cai W J, Yang J, Deng L Q, et al. Steelmaking, 2021, 37(2), 37(in Chinese).
蔡文菁, 杨健, 邓丽琴, 等. 炼钢, 2021, 37(2), 37.

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