普鲁士蓝及普鲁士蓝类化合物材料在钠离子电池中的研究进展

doi:10.11896/cldb.20050261

材料导报

2021, Vol. 35

Issue (23): 23050-23056 https://doi.org/10.11896/cldb.20050261

无机非金属及其复合材料

普鲁士蓝及普鲁士蓝类化合物材料在钠离子电池中的研究进展

李欢, 何妍妍, 周国伟

齐鲁工业大学(山东省科学院)化学与化工学院,山东省高校轻工精细化学品重点实验室,济南 250353

Progress in Sodium Ion Batteries of Prussian Blue and Prussian Blue Analogs Materials

LI Huan, HE Yanyan, ZHOU Guowei

Key Laboratory of Fine Chemicals in Universities of Shandong,School of Chemistry and Chemical Engineering, Qilu University of Technology(Shandong Academy of Sciences), Jinan 250353, China

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摘要近年来,普鲁士蓝(PB)及普鲁士蓝类化合物(PBAs)用于钠离子电池电极材料方面的研究逐渐深入。作为金属有机框架(MOFs)材料,PB及PBAs是具有可调控的化学组成和物理性质的简单配位聚合物。PB及PBAs可直接作为高性能钠离子电池正极材料,也可以通过与其他材料复合用于钠离子电池正极;此外,利用PB及PBAs作为前驱体制备各类具有纳米结构的金属化合物(如金属氧化物、金属硫化物、金属硒化物和金属磷化物等)及金属化合物复合材料,并用于钠离子电池负极。本文简要介绍了PB、PBAs和以它们为前驱体制备的金属化合物及复合材料在钠离子存储方面的应用研究进展。

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关键词: 普鲁士蓝及普鲁士蓝类化合物钠离子半/全电池正极材料负极材料复合材料

Abstract: In recent years, Prussian blue (PB) and Prussian blue analogs (PBAs) materials have been widely studied in application of sodium ion batte-ries (SIBs). PB and PBAs, asa kind of metal organic framework (MOFs) material, are simple coordination polymers with adjustable chemical composition and physical properties. Firstly, PB, PBAs and their composites can be used as high-performance cathode materials for SIBs directly. Otherwise, PB and PBAs can also be used as precursors to prepare various nanostructured metal compounds (such as metal oxides, metal sulifides, metal selenides and metal phosphides) and their composites, which could be used as high-performance anode materials for SIBs. In this study, we will introduce the research progresses of PB, PBAs and their derived metal compounds in application of sodium ion storage.

Key words: PB and PBAs sodium ion half/full battery cathode material anode material composite material

出版日期: 2021-12-10 发布日期: 2021-12-23

ZTFLH:

TM911

基金资助: 国家自然科学基金(51972180;51572134);山东省重点研发计划 (2019GGX102070);济南市高校院所创新团队项目(2018GXRC006)

通讯作者: heyanyan@qlu.edu.cn;gwzhou@qlu.edu.cn

作者简介: 李欢,硕士研究生,主要研究方向为钠离子电池和锂离子电池电极材料的制备和机理研究。在Chemical Engineering Journal, Nano Research, Chinese Journal of Catalysis发表SCI论文3篇,申请国家发明专利两件。
何妍妍,理学博士,主要从事能源存储材料的设计合成和机理研究。主持山东省自然科学基金与齐鲁工业大学博士启动基金,在Energy Storage Materials, Journal of Mater-ials Chemistry A, Chemical Engineering Journal, Nano Research等期刊发表SCI收录论文20篇,申请国家发明专利4件。
周国伟,博士,二级教授,博士研究生导师,山东省有突出贡献中青年专家,山东省优秀科技工作者,享受国务院政府特殊津贴。2001年获山东大学博士学位,2002和2005年分别在韩国釜庆大学和香港科技大学从事博士后研究。主要从事介孔材料的可控制备及在催化、能源存储与转化等领域研究。主持国家自然科学基金4项,在 Chemical Engineering Journal, Journal of Materials Chemistry, Chemical Communications等期刊上发表SCI收录论文110余篇。获山东省科学技术奖二等奖3项,获国家授权发明专利40余件。

引用本文:

李欢, 何妍妍, 周国伟. 普鲁士蓝及普鲁士蓝类化合物材料在钠离子电池中的研究进展[J]. 材料导报, 2021, 35(23): 23050-23056.
LI Huan, HE Yanyan, ZHOU Guowei. Progress in Sodium Ion Batteries of Prussian Blue and Prussian Blue Analogs Materials. Materials Reports, 2021, 35(23): 23050-23056.

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http://www.mater-rep.com/CN/10.11896/cldb.20050261 或 http://www.mater-rep.com/CN/Y2021/V35/I23/23050

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