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材料导报  2019, Vol. 33 Issue (z1): 283-287    
  金属与金属基复合材料 |
镁粉表面钙磷涂层的制备与性能
万晔1, 刘晶1,2, 谭丽丽2, 陈军修2, 东家慧2, 杨柯2
1 沈阳建筑大学材料科学与工程学院,沈阳 110168
2 中国科学院金属研究所,沈阳 110016
Preparation and Properties of Magnesium Powder with Calcium Phosphate Coatings
WAN Ye1, LIU Jing1,2, TAN Lili2, CHEN Junxiu2, DONG Jiahui2, YANG Ke2
1 School of Materials Science and Engineering, Shenyang Jianzhu University,Shenyang 110168
2 Institute of Metal Research,Chinese Academy of Sciences, Shenyang 110016
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摘要 镁粉的耐蚀性较差,在镁粉表面制备合适的Ca-P涂层,不仅能提高镁基金属的耐蚀性能,还能提高材料的成骨活性。镁粉经氟处理后可制备两种不同的Ca-P涂层:一种是将氟处理之后的镁粉直接浸泡在钙磷混合液中,通过沉积法在表面形成钙磷涂层;另一种是将镁粉经氟处理后,再经聚多巴胺(Polydopamine,PDA)处理,然后通过沉积法制备钙磷涂层。分析其微观形貌和结构,并通过浸泡实验分析镁粉表面涂层的耐蚀性能。结果表明:氟处理/Ca-P涂层较薄,约1.5 μm,氟处理/PDA/Ca-P涂层较厚,约2.3 μm;后者表面沉积的羟基磷灰石(Hydroxycarbo-nated apatite, HA)比前者沉积的HA厚,且氟处理/PDA/Ca-P涂层的耐蚀性更好,主要归因于PDA具有粘结性和耐蚀性。
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万晔
刘晶
谭丽丽
陈军修
东家慧
杨柯
关键词:  镁粉  钙磷涂层  聚多巴胺  耐腐蚀性能    
Abstract: The corrosion resistance of magnesium powder is poor, therefore, a suitable Ca-P coating is prepared on the surface of magnesium powder. The coating not only can improve the corrosion resistance of magnesium powder, but also increase the osteogenesis ability of the powder. After the treatment of magnesium powder with fluorine, followed two different Ca-P coatings are prepared. One is that the magnesium powder after fluorine treatment was directly immersed in the calcium phosphate mixture solution, and the calcium phosophate coating was formed on the surface by deposition. Another coating was prepared by the deposition of polydopamine (PDA) firstly after fluorine treatment, followed by calcium phosphate deposition method. The microstructures and structures of magnesium powder with different coatings were analyzed. The corrosion resistance of the surface coating of magnesium powder was analyzed by immersion test. The results showed that the HF/PDA/Ca-P coating was thicker, about 2.3 μm, and its corrosion resistance was better than that of the HF/Ca-P-coated magnesium powder, about 1.5 μm. The HA deposited on the surface of the HF/PDA/Ca-P coating was thicker than the HA deposited on the HF/Ca-P coating. The corrosion resistance of the HF/PDA/Ca-P coating was the best, which is mainly attributed to the ability of adhesion and corrosion resistance of PDA.
Key words:  magnesium powder    calcium phosphate coating    polydopamine    corrosion resistance
               出版日期:  2019-05-25      发布日期:  2019-07-05
ZTFLH:  R318.08  
基金资助: 中国生物医用材料研究和组织器官置换重点项目(2016YFC1100604)
作者简介:  万晔,沈阳建筑大学教授,硕士研究生导师,“材料物理与化学”方向学术负责人。2005年于中国科学院金属研究所获得工学博士学位,曾任职于美国弗吉尼亚大学,并被聘为Senior Scientist。国际电化学协会、美国腐蚀工程师协会等会员,国家自然科学基金评审专家、辽宁省科技评审专家、沈阳市科技评审专家,先后获得“辽宁省优秀科技人才”、“我心目中的好老师”、“女教职工先进个人”、“优秀研究生指导教师”等荣誉称号。完成国家、省、部级等科研项目20多项,获辽宁省技术发明三等奖、华夏科学技术三等奖等各种奖励6项,在国内外学术刊物上发表论文60多篇,其中38篇被SCI或EI收录,出版专著1部,授权发明专利9项。谭丽丽,中科院金属研究所研究员,博士生导师。主要从事医用金属材料与器件的研究与开发工作,近年来在可降解镁基金属内植入物研发方面取得一系列研究成果。作为课题负责人主持国家科技支撑计划项目、国家重点研发计划项目和国家自然科学基金项目,作为课题骨干参与多项国家973、863项目、中科院知识创新工程项目等。并负责与多家著名医疗器械公司合作进行相关器件的临床转化工作。已发表包括Biomaterials在内的学术论文120余篇,撰写英文书籍2个章节,中文书籍4个章节,授权国家发明专利15项。lltan@imr.ac.cn
引用本文:    
万晔, 刘晶, 谭丽丽, 陈军修, 东家慧, 杨柯. 镁粉表面钙磷涂层的制备与性能[J]. 材料导报, 2019, 33(z1): 283-287.
WAN Ye, LIU Jing, TAN Lili, CHEN Junxiu, DONG Jiahui, YANG Ke. Preparation and Properties of Magnesium Powder with Calcium Phosphate Coatings. Materials Reports, 2019, 33(z1): 283-287.
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http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2019/V33/Iz1/283
1 甘俊杰, 等.纯镁表面Ca-P微弧氧化涂层的制备及性能研究.南京理工大学,2013.
2 Seitz J M, Eifler R, Bach F W, et al. Journal of Biomedical Materials Research Part A,2015,102(10),3744.
3 Yamasaki Y, Yoshida Y, Okazaki M, et al. Biomaterials,2003,24(27),4913.
4 Staiger M P, Pietak A M, Huadmai J, et al. Biomaterials,2006,27(9),281.
5 Shadanbaz S, Dias G J. Acta Biomaterialia,2012,8(1),20.
6 李绮, 刘新杰, 王泽庆, 等. 材料研究学报,2011,25(2),193.
7 Zhao H, et al. RSC Advances,2015,5(31),24586.
8 Makar G L, Kruger J. Metallurgical Reviews,1993,38(3),138.
9 Monjo M, et al. Biomaterials,2008,29(28),3771.
10 Zhou R, et al. Journal of Membrane Science,2014,466(18),18.
11 Bernsmann F, et al. J Colloid Interface Sci,2010,344(1),54.
12 Ou J, et al. Applied Surface Science,2009,256(3),894.
13 Hong S, et al. Nanomedicine,2011,6(5),793.
14 Waite J H. Nature Materials,2008,7(1),8.
15 Zhou J, Yang Y, Zhang C Y. Chemical Reviews,2015,115(21),11669.
16 Liu J, Zheng X, Yan L, et al. ACS Nano,2016,12(2),486.
17 Nozik A J. Nano Letters,2010,10(8),2735.
18 Xu X, Zhuang J, Wang X. Journal of the American Chemical Society,2008,130(37),12527.
19 Kelly K L, et al. Cheminform,2003,34(16),668.
20 M L, SK C, N W. Analyst,2015,140(2),386.
21 Kim S, Park C B. Biomaterials,2010,31 (25),6628.
21 Lee H, Dellatore S M, et al. Science,2007,318(5849),426.
22 屈钧娥, 陈玉林,等. 腐蚀与防护,2015,36(11),2309.
23 万晔, 王艳娜, 王强, 等.材料导报:研究篇,2011,25(3),66.
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