Please wait a minute...
《材料导报》期刊社  2017, Vol. 31 Issue (21): 37-45    https://doi.org/10.11896/j.issn.1005-023X.2017.021.006
  材料综述 |
蓝光激发余辉型荧光粉的研究进展*
陈毕达1, 甘贵生1, 2, 吴懿平1, 区燕杰3
1 华中科技大学材料科学与工程学院,武汉 430074;
2 重庆理工大学材料科学与工程学院,重庆 400054;
3 卓然光电有限公司,江门 529000
Advances in Persistence Phosphors Activated by Blue-light
CHEN Bida1, GAN Guisheng1,2, WU Yiping1, OU Yanjie3
1 College of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074;
2 College of Materials Science and Engineering,Chongqing University of Technology, Chongqing 400054;
3 Zhuoran Optoelectronics Co.Ltd, Jiangmen 529000
下载:  全 文 ( PDF ) ( 3233KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 白光LED具有节能、环保、响应速度快等优点,逐渐成为新一代照明光源,其普遍采用蓝光LED芯片激发黄色YAG∶Ce3+荧光粉合成白光的模式。由于这类LED加入直流(DC)/交流(AC)转换器和散热器,使得市售灯具价格偏高,严重阻碍了白光LED的进一步推广。AC-LED采用市电直接驱动,是LED发展的必然方向,余辉型荧光粉使得AC-LED变成了可能。主要针对应用于AC-LED的具有蓝光激发余辉功能的荧光粉的国内外研究现状进行了总结,并对用于消除LED频闪的余辉发生时间、余辉时间长度进行了计算,对余辉强度、余辉衰减速率进行了初步判断,得出荧光粉的余辉时间为6.67 ms≤Tx≤10 ms,余辉强度最小值需大于0.032 mcd/m2,余辉衰减速率满足式(1),且余辉发生在T/2~2T/3时对于消除频闪最有益。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
陈毕达
甘贵生
吴懿平
区燕杰
关键词:  荧光粉  余辉  蓝光激发  AC-LED  频闪    
Abstract: As it is energy savings, environmental friendliness and fast switching, white light-emitting diode (w-LED) has become the new generation of lighting sources. It is commonly used that applying blue LED chip to excite the yellow YAG∶Ce3+ phosphor to synthesis white light. However, adding the DC (direct current)/AC (alternating current) conversion and heat-dissipation radiators makes the w-LED too expensive, which restricts the further development of w-LED seriously. AC-LED, a LED device driven by city power, is the inevitable direction of LED development. Furthermore, it is possible that applying afterglow phosphors in AC-LED. This paper provides a review of the persistence phosphors motivated by blue light in AC-LED, and the length of afterglow time is calculated. What’s more, the afterglow intensity and the decay rates are analyzed at the same time. The results of the paper showed that the afterglow decay time of phosphors is Tx(6.67 ms≤Tx≤10 ms), and the minimum value of afterglow intensity is greater than 0.032 mcd/m2. Meanwhile, the decay rate of afterglow satisfied the forum (1) in the text, and the afterglow is occurred at T/2—2T/3,which is the most beneficial to eliminate flicker effect.
Key words:  phosphors    afterglow    blue-light activated    AC-LED    flicker effect
               出版日期:  2017-11-10      发布日期:  2018-05-08
ZTFLH:  O614  
基金资助: 中国博士后科学基金(2015M582221);广东省科技项目(2013B090600031)
通讯作者:  甘贵生,男,1982年生,博士,副教授,研究方向为电子封装材料 E-mail:ggs@cqut.edu.cn;
吴懿平,男,1957年生,博士,教授,博士研究生导师,研究方向为电子封装技术 E-mail:ypwu@mail.hust.edu.cn   
作者简介:  陈毕达:男,1994年生,硕士研究生,研究方向为电子封装技术 E-mail:cbdeer@163.com
引用本文:    
陈毕达, 甘贵生, 吴懿平, 区燕杰. 蓝光激发余辉型荧光粉的研究进展*[J]. 《材料导报》期刊社, 2017, 31(21): 37-45.
CHEN Bida, GAN Guisheng, WU Yiping, OU Yanjie. Advances in Persistence Phosphors Activated by Blue-light. Materials Reports, 2017, 31(21): 37-45.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.021.006  或          http://www.mater-rep.com/CN/Y2017/V31/I21/37
1 Yuan X F, Shi X B, Shen M R, et al. Luminescent properties of Pr3+ doped (Ca,Zn)TiO3:Powders and films[J]. J Alloys Compd, 2009,485(1-2):83.
2 Allen M. Preferred embodiment to LED light string: US, 20030015968[P]. 2004-12-14
3 颜重光. 发展迅速的AC直接驱动LED光源技术[J]. 电子产品世界, 2009(2):64(in Chinese).
Yan Chongguang. The rapid development of the AC LED light source technology[J]. Electron Product World, 2009(2):64.
4 满瑞,李秋俊.AC-LED 的研究现状与发展[J]. 电源技术,2011,36(7):1068(in Chinese).
Man R,Li Q J.Current research and development of AC LED[J].Chin J Power Sources, 2011,36(7):1068.
5 Choi B H, Park I K, Kim D H. Ac light emitting device, driving device thereof, and driving method thereby:WO 2010058923[P].2010-03-11.
6 Wilkins A, Veitch J, Lehman B. LED lighting flicker and potential health concerns[C]∥Energy Conversion Congress & Exposition. Atlanta, 2010.
7 Gao Yuan, Li Lisong, Philip K T Mok. An AC powered converter-free LED driver with low flicker[C]∥ Asia & South Pacific Design Automation Conference. Macao, 2016.
8 Ma H, Lai J, Zheng C, et al. A high-efficiency quasi-single-stage bridgeless electrolytic capacitor-free high-power AC-DC driver for supplying multiple LED strings in parallel[J]. IEEE Trans Power Electron, 2016,31(8):5825.
9 Chen L, Zhang Y S, Xue C, et al. The green phosphor SrAl2O4∶Eu2+, R3+ (R=Y, Dy) and its application in alternating current light-emitting diodes[J]. Funct Mater Lett, 2013, 6:1350047.
10Chiao-Wen Yeh,Ye Li,Jing Wang, et al. Appropriate green phosphor of SrSi2O2N2∶Eu2+,Mn2+ for AC LEDs[J]. Optics Express, 2012, 20(16):18031.
11Chen L, Zhang Y, Liu F Y, et al. A new green phosphor of SrAl2O4∶Eu2+, Ce3+,Li+for alternating current driven light-emitting diodes[J].Mater Res Bull, 2012,47:4071.
12Blasse G. New luminescent materials[J].Chem Mater, 1989, 1(3):294.
13Tuomas Aitasalo, Jorma H?ls, H?gne Jungner, et al. Thermoluminescence study of persistent luminescence materials:Eu2+ and R3+-doped calcium aluminates, CaAl2O4∶Eu2+,R3+[J]. J Phys Chem B,2006,110(10):4589.
14Brito H F, H?ls J, Laamanen T, et al. Persistent luminescence machanisms:Human imagination at work[J].Opt Mater Express,2012,2(4):371.
15丁清秀,刘洪楷.无机发光材料[M].北京:化学工业出版社,1980:1.
16Wu Xiao. First-principles study on strontium aluminate long afterglow luminescent materials [D].Shenyang: Shenyang University of Technology, 2016(in Chinese).
吴霄.铝酸锶长余辉发光材料的第一性原理研究[D].沈阳:沈阳工业大学,2016.
17Xu Jiao. Preperation and photoluminescence properties of long-persistent phosphorescence doped with lanthanides [D].Lanzhou:Lanzhou University, 2015(in Chinese).
徐娇. 稀土长余辉材料的制备及发光性能研究[D].兰州:兰州大学,2015.
18Zeng Wei. Synthesis and luminescent properties of oxide yellow long persistent phosphors [D].Lanzhou:Lanzhou University,2016(in Chinese).
曾巍. 氧化物黄色长余辉材料的合成及发光性能研究[D]. 兰州:兰州大学,2016.
19Eeckhout K V D, Smet P F, Poelman D. Persistent luminescence in Eu2+-doped compounds:A review[J].Materials,2010,3(4):2536.
20Blasse G,Wanmaker W L,Wter Vrugt J, et al. Fluorescence of Eu2+activated silicates[J]. Philips Res Rep, 1968, 23:189.
21Barry T L. Equilibria and Eu2+Luminescenceof subsolidus phases bounded by Ba3MgSi2O8,Sr3MgSi2O8,and Ca3MgSi2O8[J]. J Electrochem Soc, 1968, 115(7):733.
22Jia D D, Wang X J, Yen W M. Delocalization, thermal ionization and energy transfer in singly doped and codoped CaAl4O7 and Y2O3[J].Phys Rev B,2004, 69:235113.
23Dorenbos P. Mechanism of persistent luminescence in Eu2+ and Dy3+ codoped aluminate and silicate compounds[J]. J Electrochem Soc, 2005, 152, H107.
24Bos A J J, Duijvenvoorde R M V, Kolk E V D, et al. Thermoluminescence excitation spectroscopy: A versatile technique to study persistent luminescence phosphors[J]. J Lumin, 2011, 131(7):1465.
25Bo Wang, Lin Hang, Yu Yunlong, et al.Ce3+/Pr3+∶YAGG:A long persistent phosphor activated by blue-light[J].J Am Ceram Soc,2014, 97(8):2539.
26Mu Zhongfei, Wang Yinhai, Hu Yihua, et al. The afterglow and thermoluminescence properties ofY3Al5O12∶Ce3+[J]. Acta Phys Sin, 2011,60(1):182(in Chinese)
牟中飞,王银海,胡义华,等. Y3Al5O12∶Ce3+的余辉和热释光特性[J]. 物理学报, 2011, 60(1):182.
27Jumpei Ueda, Keisuke Kuroishi, Setsuhisa Tanabe. Bright persistent ceramic phosphors of Ce3+-Cr3+-codoped garnet able to store by blue light[J]. Appl Phys Lett, 2014, 104(10):101904.
28Jumpei Ueda, Kotaro Aishima, Nishiura S, et al.Afterglow luminescence in Ce3+-doped Y3Sc2Ga3O12 ceramics[J].Appl Phys Express, 2011, 4(4):257.
29Xu Jian, Ueda Jumpei, Kuroishi K, et al. Fabrication of Ce3+-Cr3+ co-doped yttrium aluminium gallium garnet transparent ceramic phosphors with super long persistent luminescence[J]. Scr Mater,2015,102:47.
30Chen Hui, Lin Hang, Xu Ju,et al. Chromaticity-tunable phosphor-in-glass for long-lifetime high-power warm W-LEDs[J]. J Mater Chem C, 2015, 3(31):8080.
31Lin Zebin, Lin Hang, Xu Ju, et al. A chromaticity-tunable garnet-based phosphor-in-glass colorconverter applicable in w-LED[J].J Eur Ceram Soc, 2016,36(7):1723.
32Lin Hang, Wang Bo, Xu Ju, et al. Phosphor-in-glass for high-po-wered remote-type white AC-LED[J]. ACS Appl Mater Interfaces,2014, 6(23):21264.
33Jumpei Ueda, Keisuke Kuroishi, Setsuhisa Tanabe. Yellow persistent luminescence in Ce3+-Cr3+-codoped gadolinium aluminum gal-lium garnet transparent ceramics after blue-light excitation[J].Appl Phys Express, 2014, 7(6):297.
34Li Y Q, van Steen J E J, van Krevel J W H, et al. Luminescence properties of red-emitting M2Si5N8∶Eu2+ (M=Ca, Sr, Ba) LED conversion phosphors[J]. J Alloys Compd, 2006, 417(1-2):273.
35Xie R J, Hirosaki N, Suehiro T, et al. A simple, efficient synthetic route to Sr2Si5N8∶Eu2+-based red phosphors for white light-emitting diodes[J]. Cheminform, 2006, 38(4):5578.
36Wang Bo, Lin Hang, Xu Ju, et al. Design,preparation,and characterization of a novel red long-persistent perovskite phosphor:Ca3Ti2O7∶Pr3+[J].Inorg Chem, 2015, 54(23):11299.
37中国科学院福建物质结构研究所.一种AC-LED用镨掺杂钙钛矿型红色余辉发光材料及其制备方法:CN, 105295911[P].2016-02-03.
38Lin Hang, Xu Ju, Huang Qingming, et al. Bandgap tailoring via si doping in inverse-garnet Mg3Y2Ge3O12∶Ce3+ persistent phosphor potentially applicable in AC-LED[J]. ACS Appl Mater Interfaces,2015,7:21835.
39四川新力光源股份有限公司,中国科学院长春应用化学研究所.一种交流 LED发光装置:CN, 102468413[P].2014-10-29.
40天津理工大学.蓝光激发的橙红光磷光体及制备方法与余辉二极管:CN, 101186819[P].2008-05-28.
41江门市远大发光材料有限公司.一种具有余辉特性的高显色白光LED器件:CN, 102629655[P].2012-08-08.
42中山大学.一种黄色长余辉发光材料及其制备方法:CN, 103131415[P].2015-01-28.
43中国科学院福建物质结构研究所.一种用于AC-LED的黄色余辉微晶玻璃及其制备技术:CN, 104529165[P].2015-04-22.
44Lin Hang, Wang Bo, Huang Qingming, et al. Lu2CaMg2 (Si1-x-Gex)3O12∶Ce3+solid-solution phosphors: Bandgap engineering for blue-light activated afterglow applicable to AC-LED[J]. J Mater Chem C, 2016, 4:10329.
45Liang Yanjie. Design, preparation and properties of yttrium vanadate upconversion luminescent nanomaterials and germinate-based persistent phosphors[D].Jinan: Shandong University,2016(in Chinese).
梁延杰.钒酸钇上转换发光纳米材料和锗酸盐基长余辉发光材料的设计、制备与性能[D].济南:山东大学,2016.
46Rea M S. The IESNA lighting handbook: Reference&application[M]. New York: Illuminating Engineering society of North America, 2000: 44.
47Sakai R, Katsumata T, Komuro S,et al. Effect of composition on the phosphorescence from BaAl2O4∶Eu2+,Dy3+ crystals[J]. J Lumin, 1999, 85(1):149.
48Yuan Z X,Chang C K,Mao D L, et al. Effect of composition on the luminescent properties of Sr4Al14O25∶Eu2+,Dy3+phosphors[J]. J Alloys Compd, 2004, 377(1-2):268.
[1] 张晓英,周梓良,杨伟光,王锋. 掺Eu2+蓝光长余辉材料发光性能影响因素[J]. 材料导报, 2019, 33(15): 2497-2504.
[2] 任强, 魏腾跃, 武秀兰, 霍哲哲, 王保兴. Eu3+对Na3Gd2(BO3)3∶Tb3+发光性能的影响及其能量传递[J]. 《材料导报》期刊社, 2017, 31(6): 7-10.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed