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《材料导报》期刊社  2018, Vol. 32 Issue (14): 2508-2512    https://doi.org/10.11896/j.issn.1005-023X.2018.14.033
  高分子与聚合物基复合材料 |
PMDA对废旧HIPS的修复作用
吴晓露, 李迎春, 武海花, 孔宇飞
中北大学材料科学与工程学院,太原 030051
Repairing Effect of PMDA on Recycled HIPS
WU Xiaolu, LI Yingchun, WU Haihua, KONG Yufei
School of Materials Science and Engineering, North University of China, Taiyuan 030051
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摘要 采用均苯四甲酸二酐(PMDA)为扩链剂,通过双螺杆挤出机将废旧高抗冲聚苯乙烯塑料(rHIPS)与PMDA进行熔融共混,成功实现了rHIPS的分子结构以及相界面的修复。研究了PMDA含量对rHIPS的相对分子质量、力学性能、动态力学性能、熔体流动性和断面形貌特征的影响。结果表明:PMDA与rHIPS发生了扩链反应,相对分子质量也得到了明显提升;当PMDA含量为0.9%(质量分数,下同)时,rHIPS/PMDA共混物的冲击强度达到10.8 kJ/m2,提高了57%;随PMDA含量的增加熔融指数先减小后趋于平缓,储能模量和损耗模量升高,试样的冲断面形貌变得粗糙,相界面模糊。
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吴晓露
李迎春
武海花
孔宇飞
关键词:  废旧高抗冲聚苯乙烯  均苯四甲酸二酐  扩链  冲击强度    
Abstract: Recycled high impact polystyrene plastic(rHIPS) was chain extended by pyromellitic dianhydride (PMDA) in twin-screw extruder, and the effects of PMDA content on molecular weight, mechanical properties, dynamic mechanical properties, melt fluidity and morphology of rHIPS were studied. The results indicated that, PMDA and rHIPS had a chain extension reaction, and the rlaive molecular weight was improved obviously. When the PMDA content was 0.9% (mass fraction, the same below), the impact strength of the rHIPS/PMDA blends reached 10.8 kJ/m2 and increased by 57%. With the increase of PMDA, the melting index decreased first and then tended to be smooth.The modulus of energy storage and loss modulus were increased, the fracture surface becamerough and the phase interface was blurred.
Key words:  recycled high impact polystyrene    pyromellitic dianhydride    chain extension    impact strength
               出版日期:  2018-07-25      发布日期:  2018-07-31
ZTFLH:  TQ322.2  
基金资助: 国家科技支撑计划资助项目(2014BAC03B06)
通讯作者:  李迎春,教授,主要从事废旧塑料的回收改性研究 E-mail:liyingchun@nuc.edu.cn   
作者简介:  吴晓露:女,1994年生,硕士研究生, 主要从事废旧塑料的回收改性研究 E-mail:454478159@qq.com
引用本文:    
吴晓露, 李迎春, 武海花, 孔宇飞. PMDA对废旧HIPS的修复作用[J]. 《材料导报》期刊社, 2018, 32(14): 2508-2512.
WU Xiaolu, LI Yingchun, WU Haihua, KONG Yufei. Repairing Effect of PMDA on Recycled HIPS. Materials Reports, 2018, 32(14): 2508-2512.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.14.033  或          http://www.mater-rep.com/CN/Y2018/V32/I14/2508
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