Abstract: Recently, carbon fiber reinforced cement-based composites (CFRC) has been concerned considerably due to its strong Seebeck effect. The electrical conduction mechanism, CFRC-Seebeck effect reinforcement approaches, and potential applications of CFRC are reviewed in this paper. The carrier types of CFRC is mainly related to ionic, electronic and hole carriers, and the hole carriers play the most important role. The Seebeck coefficient of about 30 μV/℃ can be obtained by adding carbon fibers or carbon nanotubes. The steel fiber reinforced cement-based composites belongs to an n-type semiconductor, and its Seebck coefficient can be increased to 68 μV/℃. The CFRC-Seebeck coefficient of 100.28 μV/℃ can be obtained by mixing Bi2O3, and the largest Seebeck coefficients of 3 300 μV/℃ and 2 500 μV/℃ can be obtained by adding ZnO and Fe2O3, respectively. These studies have effectively promoted the research and development of CFRC in the fields of urban heat harvesting, energy conservation in buildings, the waste heating collection and structural self-sensing.
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