Abstract: Functional film is a kind of product with photoelectricity, magnetism, absorption, separation and the ability to response to stimulus functional properties, which shows large demand and application prospects. However, resources of functional film are mostly non-renewable fossil-based, which limits its development. Nanocellulose material (including derivatives of nanocellulose that are chemically modified) is one of the most promising materials to study regarding the development of nanotechnology, which plays an important role in improving the performance of functional film and promoting its sustainable development. Nanocellulose material is currently widely used in functional films in the food industry, water treatment industry, new energy fields, batteries and other fields. The role and advantages of nanocellulose material in these functional films are mainly reflected in the following aspects: first, high degree of crystallization, large specific surface area and excellent mechanical properties make nanocellulose material a good candidate as a reinforcement phase to combine with matrix in forming functional films for strength enhancement. According to different demand, nanocellulose mate-rials with different sizes, morphologies or surface modification groups can be used to improve the interfacial bonding strength with the matrix, thus making the functional film to achieve ideal mechanical properties. Secondly, due to its good film-forming properties, nanocellulose material can also be used as matrix materials for functional films. In addition to film formation alone, nanocellulose materials can also be combined with other materials to form films, especially with other biomass materials to make biofilm materials with smooth surfaces and good barrier properties, which has a great impact on the expansion of packaging film applications. Next, the high water absorption, swelling and adsorption properties of nanocellulose material are helpful to improve the performance of functional films such as ultrafiltration film. Furthermore, based on the advantages of stable structure, various possibilities of surface modification and excellent biocompatibility, nanocellulose material can be utilized as good carrier mate-rials and supporting reinforcement materials combined with specific functional materials (such as photoelectric, magnetic, responsive, etc. pro-perties) to prepare functional film materials with application value, making nanocellulose material plays an increasingly important role in conductive films, battery separators and other functional films. Compared with traditional functional film materials, the introduction of nanocellulose materials will bring new vigor and vitality to functional film research area in the aspects of enhancing mechanical performance, reducing cost, better biocompatibility and environmental protection. Therefore, based on a large amount of research references, in this paper we summarized the research application progress of nanocellulose material in packaging film, ultrafiltration film, conductive film, battery separator and other functional film, analyzed the working mechanism of nanocellulose material and its application advantages in different functional film. Furthermore, prospects for potential application of nanocellulose material in functional film materials were presented.
1 Wang H, Xu H Y, Yan H. Functional Materials Information,2006,3(1),13(in Chinese). 汪浩,徐海燕,严辉.功能材料信息,2006,3(1),13. 2 Liu F, Tao K, Du X D, et al. Chemical Production and Technology,2012,19(39),9(in Chinese). 刘富,陶慷,杜旭东,等.化工生产与技术,2012,19(39),9. 3 Geyer R, Jambeck J R, Law K L. Science Advances,2017,3(7),e1700782. 4 Klemm D, Kramer F, Moritz S, et al. Angewandte Chemie International Edtion,2011,50(24),5438. 5 Thakur V K. Cellulose-Based Graft Copolymers:Structure and Chemistry, CRC Press,US,2015. 6 Dufresne A. Nanocellulose: From Nature to High Performance Tailored Materials, De Gruyter, Germany,2012. 7 Yang L, Zhang L, Webster T J. Advanced Engineering Materials,2011,13(6),B197. 8 Dufresne A. Materials Today,2013,16(6),220. 9 Wei J, Zhou Y, Lyu Y Y, et al. ACS Sustainable Chemistry & Enginee-ring,2019,7(15),12887. 10 Zhou Y, Wei J, Lv Y Y, et al. ACS Sustainable Chemistry & Enginee-ring,2019,7(12),10690. 11 Grainger D W, Castner D G. Advanced Materials,2008,20(5),867. 12 Xing J, Tao P, Wu Z, et al. Carbohydrate Polymers,2019,207,447. 13 Gómez H. C, Serpa A, Velásquez-Cock J, et al. Food Hydrocolloids,2016,57,178. 14 Galiano F, Briceño K, Marino T, et al. Journal of Membrane Science,2018,564,562. 15 Xu X, Liu F, Jiang L, et al. ACS Applied Materials & Interfaces,2013,5(8),2999. 16 Neto W P F, Silverio H A, Vieira J G, et al. Macromolecular Symposia,2012,319(1),93. 17 Zhang Z, Wu Q, Song K, et al. ACS Sustainable Chemistry & Enginee-ring,2015,3(4),574. 18 Silverio H A, Neto W P F, Pasquini D. Journal of Nanomaterials,2013,2013,1. 19 Azeredo H M C, Rosa M F, Mattoso L H C. Industrial Crops and Pro-ducts,2017,97,664. 20 Asad M, Saba N, Asiri A M, et al. Carbohydrate Polymers,2018,191,103. 21 Li J, Zhou M, Cheng Gm, et al. Carbohydrate Polymers,2019,210,429. 22 Dufresne A. Philosophical Transactions Mathematical Physical Engineering Science,2018,376(2112),1. 23 Li Q, Chen W S, Yu H P, et al. Scientia Silvae Sinicae,2013(8),126(in Chinese). 李勍,陈文帅,于海鹏,等.林业科学,2013(8),126. 24 Wang L F, Shankar S, Rhim J W. Food Hydrocolloids,2017,63,201. 25 Yu Z L, Sun L, Wang W, et al. Industrial Crops and Products,2018,112,412. 26 Sarwar M S, Niazi M B K, Jahan Z, et al. Carbohydrate Polymers,2018,184,453. 27 Chowdhury R A, Nuruddin M, Clarkson C, et al. ACS Applied Materials & Interfaces,2018,11(1), 1376. 28 Khan A, Khan R A, Salmieri S, et al. Carbohydrate Polymers,2012,90(4),1601. 29 Dai L, Long Z, Chen J, et al. ACS Applied Materials & Interfaces,2017,9(6),5477. 30 Trovatti E, Fernandes S C M, Rubatat L, et al. Cellulose,2012,19(3),729. 31 Nguyen V T, Gidley M J, Dykes G A. Food Microbiology,2008,25(3),471. 32 Shahmohammadi Jebel F, Almasi H. Carbohydrate Polymers,2016,149,8. 33 Wang W, Yu Z L, Alsammarraie F K, et al. Food Hydrocolloids,2020,100,105441. 34 Orasugh J T, Saha N R, Sarkar G, et al. Carbohydrate Polymers,2018,188,168. 35 Orasugh J T, Saha N R, Rana D, et al. Industrial Crops and Products,2018,112,633. 36 Eliasson J. Nature,2015,517(7532),6. 37 Shannon M A, Bohn P W, Elimelech M, et al. Nature,2008,452(7185),301. 38 Zhou W Y, Bahi A, Li Y J, et al. RSC Advances,2013,3(29),11614. 39 Voisin H, Bergstrom L, Liu P, et al. Nanomaterials (Basel),2017,7(3),57. 40 Bai H L, Li S, Zhang L P. Modern Chemical Industry,2011,31(z1),142(in Chinese). 白浩龙,李帅,张力平.现代化工,2011,31(z1),142. 41 Hadi P, Yang M Y, Ma H Y, et al. Journal of Membrane Science,2019,579,162. 42 Jiang Q, Tian L, Liu K K, et al. Advanced Materials,2016,28(42),9400. 43 Xu T, Jiang Q, Ghim D, et al. Small,2018,14(15),e1704006. 44 Chen J, Hou T, Zhou J J, et al. Functional Materials,2018,49(2),02141(in Chinese). 陈进,侯婷,周建军,等.功能材料,2018,49(2),02141. 45 Malakhov A O, Anokhina T S, Petrov D A, et al. Petroleum Chemistry,2018,58,10. 46 Zhou J J, Guo Y Y, Zhang H, et al. Materials Reports B: Research Papers,2016,30(33),4(in Chinese). 周建军,郭莹莹,张欢,等.材料导报:研究篇,2016,30(33),4. 47 Qin D, Zhang D, Shao Z, et al. RSC Advances,2016,6(80),76336. 48 Lyu J, Zhang G, Zhang H, et al. Carbohydrate Polymers,2017,174,190. 49 Hao Z, Chang D, Lokendra P, et al. Bioresources,2019,3(14),7494. 50 Nystrom G, Mihranyan A, Razaq A, et al. Journal of Physical Chemistry B,2010,114(12),4178. 51 Lyu Y, Zhou Y, Shao Z, et al. Journal of Materials Science: Materials in Electronics,2019,30(9),8585. 52 Zhou J, Yuan Y, Tang J, et al. Energy Storage Materials,2019,23,594. 53 Lyu S Y, Fu F, Wang S Q, et al. Scientia Silvae Sinicae,2015,51(117),9(in Chinese). 吕少一,傅峰,王思群,等.林业科学,2015,51(117),9. 54 Sasso C, Zeno E, Petit-Conil M, et al. Macromolecular Materials and Engineering,2010,295(10),934. 55 Hu W, Chen S, Yang Z, et al. Journal of Physical Chemistry B,2011,115(26),8453. 56 Liu D Y, Sui G X, Bhattacharyya D. Composites Science and Technology,2014,99,31. 57 Wang Z, Carlsson D O, Tammela P, et al. ACS Nano,2015,9(7),7563. 58 Olivier C, Mougel J B, Bertoncini P, et al. Journal of Renewable Mate-rials,2017,6(3),237. 59 Qi H, Schulz B, Vad T, et al. ACS Applied Materials & Interfaces,2015,7(40),22404. 60 Koga H, Saito T, Kitaoka T, et al. Biomacromolecules,2013,14(4),1160. 61 Hamedi M M, Hajian A, Fall A B, et al. ACS Nano,2014,8(3),2467. 62 Wang X, Gao K Z, Shao Z Q, et al. Journal of Power Sources,2014,249,148. 63 Tian W, Vahidmohammadi A, Reid M S, et al. Advanced Materials,2019,31,e1902977. 64 Septevani A A, Evans D A C, Hosseinmardi A, et al. Small,2018,14(46),e1803439. 65 Oun A A, Shankar S, Rhim J W. Critical Reviews in Food Science and Nutrition,2020,60(3),435. 66 Schutz C, Sort J, Bacsik Z, et al. PLoS One,2012,7(10),e45828. 67 Roig-Sanchez S, Jungstedt E, Anton-Sales I, et al. Nanoscale Horiz,2019,4(3),634. 68 Qin Y, Yi J N, Wu Y Q, er al. Scientia Silvae Sinicae,2018,54(3),134(in Chinese). 卿彦,易佳楠,吴义强,等.林业科学,2018,54(3),134. 69 Zhou S, Nyholm L, Stromme M, et al. Accounts of Chemical Research,2019,52(8),2232. 70 Zhang T, Yang L, Yan X, et al. Small,2018,14(47),e1802444. 71 Lasrado D, Ahankari S, Kar K. Journal of Applied Polymer Science,2020,48959. 72 Chiappone A, Nair J R, Gerbaldi C, et al. Journal of Power Sources,2011,196(23),10280. 73 Liu C T, Shao Z Q, Wang J Q, et al. RSC Advances,2016,6(100),97912. 74 Wang Z, Pan R, Xu C, et al. Energy Storage Materials,2018,13,283. 75 Pan R J, Sun R, Wang Z H, et al. Nano Energy,2019,55,316. 76 Kim H, Guccini V, Lu H R, et al. ACS Applied Energy Materials,2019,2(2),1241. 77 Hänninen A, Sarlin E, Lyyra I, et al. Carbohydrate Polymers,2018,202,418. 78 Yang Q, Zhang C, Shi Z, et al. ACS Applied Nano Materials,2018,1(9),4972. 79 Song N, Jiao D J, Ding P, et al. Journal of Materials Chemistry C,2016,4(2),305. 80 Uetani K, Okada T, Oyama H T. Journal of Materials Chemistry C,2016,4(41),9697. 81 Yan C, Wang J, Kang W, et al. Advanced Materials,2014,26(13),2022. 82 Wang Y, Shao Z, Wang F, et al. European Polymer Journal,2017,86,85.
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2021, Vol. 35 
