可依次检测汞、硫离子的双功能比色传感器的设计与研究

doi:10.11896/cldb.19110094

材料导报

2020, Vol. 34

Issue (24): 24010-24013 https://doi.org/10.11896/cldb.19110094

无机非金属及其复合材料

可依次检测汞、硫离子的双功能比色传感器的设计与研究

程晓红¹, 代思思², 和平², 屈少华¹, 汪竞阳¹

1 湖北文理学院低维光电材料与器件湖北省重点实验室,襄阳441053
2 湖北文理学院化学工程学院,襄阳441053

Design and Research of Dual Functional Colorimetric Sensor for Successive Detection of Hg²⁺ and S^2-

CHENG Xiaohong¹, DAI Sisi², HE Ping², QU Shaohua¹, WANG Jingyang¹

1 Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Hubei University of Arts and Science, Xiangyang 441053, China
2 College of Chemical Engineering, Hubei University of Arts and Science, Xiangyang 441053, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 3628KB )
输出: BibTeX | EndNote (RIS)

摘要本工作报道了一种含二甲氨基二硫代甲酸基团的化合物C1,其可与汞离子形成稳定的络合物C1-Hg(Ⅱ),引起分子内电荷转移效率及紫外-可见吸收光谱的明显变化。同时,络合物C1-Hg(Ⅱ)亦可作为硫离子的比色传感器,通过间接的方法实现对硫离子的高效检测。在该络合物的溶液中加入硫离子之后,其最大吸收峰红移了近135 nm,溶液从浅黄色变为深红色,对硫离子的检出限低达1.5×10^-6 mol/L。重要的是,络合物C1-Hg(Ⅱ)具有较高的选择性,对除硫离子之外的其他阴离子无明显的光谱响应。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	程晓红
	代思思
	和平
	屈少华
	汪竞阳

关键词: 双功能传感器比色法偶氮苯汞离子硫离子

Abstract: In this work, compound C1 was designed and synthesized as a dual-functional sensor for Hg²⁺ and S^2-. In compound C1, the carbamodithioate unit had an exceptionally strong affinity towards Hg²⁺ and then formed the C1-Hg(Ⅱ) complex, which would induce the changes on intramolecular charge transfer (ICT) efficiency and the concomitant UV-vis spectra. Furthermore, the C1-Hg(Ⅱ) complex could serve as an indirect sensor towards sulfide anion. Upon the addition of S^2-, the absorption spectra of C1-Hg(Ⅱ) complex shifted by ~135 nm with the color changing from light yellow to deep red. The detection limit was determined to be as low as 1.5×10^-6 mol/L and the mixture system displayed high selectivity to S^2- over other anions.

Key words: dual-functional sensor colorimetric approach azobenzene mercury sulfide anion

出版日期: 2020-12-25 发布日期: 2020-12-24

ZTFLH:

O622.4

基金资助: 湖北省自然科学基金(2018CFB454);湖北文理学院教师科研能力培育基金(2020kypyfy031);湖北文理学院学科开放基金(XK2020042)

通讯作者: chengxiaohong0807@126.com

作者简介: 程晓红,湖北文理学院低维光电材料与器件湖北省重点实验室,讲师。2013年毕业于武汉大学有机/高分子光电功能材料湖北省重点实验室。研究方向为新型化学传感器的设计、合成及其传感性能。

引用本文:

程晓红, 代思思, 和平, 屈少华, 汪竞阳. 可依次检测汞、硫离子的双功能比色传感器的设计与研究[J]. 材料导报, 2020, 34(24): 24010-24013.
CHENG Xiaohong, DAI Sisi, HE Ping, QU Shaohua, WANG Jingyang. Design and Research of Dual Functional Colorimetric Sensor for Successive Detection of Hg²⁺ and S^2-. Materials Reports, 2020, 34(24): 24010-24013.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.19110094 或 http://www.mater-rep.com/CN/Y2020/V34/I24/24010

1 Fitzgerald W F, Lamborg C H, Hammerschmidt C R.Chemical Reviews, 2007, 107(2), 641.
2 Vupputuri S, Longnecker M P, Daniels J L, et al.Environment Research, 2005, 97, 195.
3 Li D, Wieckowska A, Willner I.Angewandte Chemie-International Edition, 2008, 47(21), 3927.
4 White B R, Liljestrand H M, Holcombe J A. Analyst, 2008, 133, 65.
5 Xing Y, Zhu Q, Zhou X, et al. Micrichimica Acta, 2020, 187(4), 214.
6 Ren X, Xu Q. Langmuir, 2009, 25, 29.
7 Li T, Dong S, Wang E. Analytical Chemistry, 2009, 81, 2144.
8 Kim H N, Guo Z, Zhu W, et al. Chemistry Society Review, 2011, 40, 79.
9 Shan Y, Yao W, Liang Z, et al.Dyes and Pigments, 2018, 156, 1.
10 Ding J, Li H, Xie Y, et al.Polymer Chemistry, 2017, 8(14), 2221.
11 Sharma V, Saini A K, Mobin S M.Journal of Materials Chemistry, 2016, 4(36), 6154.
12 Wu G, He S, Peng H, et al.Analytical Chemistry, 2014, 86(21), 10955.
13 Sharma V, Saini A K, Mobin S M. Journal of Materials Chemistry C, 2016, 4(14), 2466.
14 Pan S, Li K, Li L, et al. Chemical Communication, 2018, 54, 4955.
15 Gao Y, Ma T, Ou Z, et al. Talanta, 2018, 178, 663.
16 Ruan Z, Shan Y, Gong Y, et al. Journal of Materials Chemistry C, 2018, 6, 773.
17 Chen L, Park S J, Wu D, et al.Chemical Communication, 2018, 55(12), 1766.
18 Cheng X, Li Q, Li C, et al. Chemistry-A European Journal, 2011, 17, 7276.
19 Duan Q, Zhang M, Sheng C, et al.Analytical Science, 2017, 33(10), 1169.
20 Chen C, Wang R, Guo L, et al. Organic Letters, 2011, 13, 1162.
21 Cheng X, Li S, Zhong Z, et al. Journal of Fluorescence, 2014, 24, 1727.
22 Cheung S M, Chan W H. Tetrahedron, 2006, 62(35), 8379.
23 Chen C, Wang R, Guo L, et al. Organic Letters, 2011, 13(5), 1162.
24 Chung Y M, Raman B, Kim D S, et al. Chemical Communication, 2006, 42(2), 186.
25 Beer P D, Hayes E J. Coordination Chemistry Reviews, 2003, 240(1-2), 167.
26 Kaur P, Kaur H, Singh K. Analyst, 2013, 138(2), 425.
27 Rostami A, Mark S T.Macromolecular Rapid Communications, 2012, 33(1), 21.
28 Wang B, Li P, Yu F.Chemical Communication, 2013, 49(10), 1014.
29 Lou X, Mu H, Gong R, et al.Analyst, 2011, 136, 684.
30 Zhang L, Lou X, Yu Y, et al.Macromolecules, 2011, 44, 5186.
31 Cao X, Lin W, He L.Organic Letters, 2011, 13, 4716.
32 Wang G, Chen Z, Wang W, et al. Analyst, 2011, 136(1), 174.
33 Cao X, Lin W, He L.Organic Letters, 2011, 13(17), 4716.
34 Liu L, Dong X, Xiao Y, et al.Analyst, 2011, 136(10), 2145.
35 Pearson R G. Journal of the American Chemical Society, 1963, 85, 3533.
36 Wang G, Qi H, Yang X.Luminescence, 2013, 28, 97.
37 Zheng H, Yan M, Fan X, et al.Chemical Communication, 2012, 48, 2243.
38 Yu H, Xiao Y, Guo H, et al.Chemistry-A European Journal, 2011, 17(11), 3179.
39 Dong Y, Liu T, Wan X, et al.Sensors and Actuators B: Chemical, 2017, 241, 1139.

[1]	李焕焕, 张东东, 许子昂, 董瑶, 赵义平, 陈莉. 荧光碳点改性无纺布的制备及在汞(Ⅱ)检测中的应用[J]. 材料导报, 2020, 34(2): 2163-2168.
[2]	喻炎, 马凤森, 陆佳骏, 陈海波. 纤维素类可吸收止血材料的体外细胞毒性评价[J]. 材料导报, 2018, 32(6): 874-880.
[3]	高伟,赵广杰. 硝酸表面氧化改性木质活性碳纤维[J]. 《材料导报》期刊社, 2018, 32(10): 1688-1694.

[1]	Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[2]	WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[3]	GUO Hongjian, JIA Junhong, ZHANG Zhenyu, LIANG Bunu, CHEN Wenyuan, LI Bo, WANG Jianyi. Microstructure and Tribological Properties of VN/Ag Films Fabricated by Pulsed Laser Deposition Technique[J]. Materials Reports, 2017, 31(2): 55 -59 .
[4]	WANG Wenjin, WANG Keqiang, YE Shenjie, MIAO Weijun, CHEN Zhongren. Effect of Asymmetric Block Copolymer of PI-b-PB on Phase Morphology and Properties of IR/BR Blends[J]. Materials Reports, 2017, 31(2): 96 -100 .
[5]	HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[6]	YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
[7]	ZHANG Le, ZHOU Tianyuan, CHEN Hao, YANG Hao, ZHANG Qitu, SONG Bo, WONG Chingping. Advances in Transparent Nd∶YAG Laser Ceramics[J]. Materials Reports, 2017, 31(13): 41 -50 .
[8]	YAN Zhilong, LI Yongsheng, HU Kai, ZHOU Xiaorong. Progress of Study on Phase Decomposition of Duplex Stainless Steel[J]. Materials Reports, 2017, 31(15): 75 -80 .
[9]	SHI Yu, ZHOU Xianglong, ZHU Ming, GU Yufen, FAN Ding. Effect of Filler Wires on Brazing Interface Microstructure and Mechanical Properties of Al/Cu Dissimilar Metals Welding-Brazing Joint[J]. Materials Reports, 2017, 31(10): 61 .
[10]	DONG Fei,YI Youping,HUANG Shiquan,ZHANG Yuxun,. TTT Curves and Quench Sensitivity of 2A14 Aluminum Alloy[J]. Materials Reports, 2017, 31(10): 77 -81 .

Viewed

Full text

Abstract

Cited

Shared

Discussed