碳空位对过渡金属碳化物陶瓷性能的调控研究综述

doi:10.11896/cldb.24120017

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Abstract Carbon vacancy transition metal carbide ceramics, also known as non-stoichiometric transition metal carbide ceramics, is a type of ceramic material derived from transition metal carbides. The preparation of this material involves precise controlling of the internal carbon content, intentionally reducing the ratio of carbon to the ideal stoichiometric proportion, which induces the formation of carbon vacancies. The formation of these vacancies has a significant impact on the physical and chemical properties of the ceramics. Compared to traditional ceramics, this type of material mainly uses binary transition metal carbides or high-entropy carbide ceramics as the base. The introduction of carbon vacancies significantly affects several material properties, including enhanced toughness and plasticity, reduced thermal conductivity, and improved density. In addition, the presence of carbon vacancies also plays a role in enhancing phase stability, reducing sintering temperatures, and improving oxidation resistance. In the field of functional materials, the introduction of carbon vacancies enhances the material's hydrogen storage and catalytic performance. Due to their outstanding structural and functional characteristics, these materials exhibit great potential and prospects in aerospace, nuclear industries, and industrial manufacturing fields that require high-temperature resistance, oxidation resistance, and excellent mechanical properties.

Key words： carbon vacancy carbide ceramics property regulation high-entropy carbides functional material

Published: 10 January 2026 Online: 2026-01-09

CLC number:

TQ174

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	Articles by authors
	HU Pengfei
	LIN Jie
	YANG Jiaxin
	JIANG Yun
	XIE Chen

Cite this article:

HU Pengfei,LIN Jie,YANG Jiaxin, et al. A Review on the Regulation of Transition Metal Carbide Ceramics Properties by Carbon Vacancies[J]. Materials Reports, 2026, 40(1): 24120017-11.

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https://www.mater-rep.com/EN/10.11896/cldb.24120017 OR https://www.mater-rep.com/EN/Y2026/V40/I1/24120017

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