| METALS AND METAL MATRIX COMPOSITES |
|
|
|
|
|
| Research Progress on the Effects of Mo and W on the Microstructure and Application Properties of Polycrystalline Ni-based Cast Superalloys |
| XIE Shulei1,2,3, OU Meiqiong1,3, HOU Kunlei1,3, WANG Min1,3,*, MA Yingche1,3,*
|
1 Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2 School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
3 CAS Key Laboratory of Nuclear Materials and Safety Assessment, Shenyang 110016, China |
|
|
|
|
Abstract Polycrystalline Ni-based cast superalloys are mainly used for large-sized and complex high temperature components of aircraft engine casings that require integral casting. With the improvement of engine performance and the increase of component service temperature, the alloying degree of polycrystalline Ni-based cast superalloys is also rising. Mo and W elements play an important strengthening role in high-temperature alloys, mainly improving the mechanical properties of the alloy through solid solution strengthening effect and the participation in second phase precipitation. At present, the strengthening effects and related mechanisms of Mo and W elements have been extensively studied. This article mainly summarizes the distribution of Mo and W elements, and their effects on the morphology and stability of dendrites, carbides, TCP, and γ/γ′ structures. Current researches on the influence and related mechanisms of the two elements on the strength, welding, and oxidation resistance of alloys are also summarized.
|
|
Published: 10 January 2026
Online: 2026-01-09
|
|
|
|
|
1 Li X, Ou M, Wang M, et al. Journal of Materials Science & Technology, 2021, 73, 108.
2 Xie J, Ma Y, Xing W, et al. Journal of Materials Science, 2019, 54(4), 3558.
3 Zhang L L, Chen J Y, Tang X, et al. Acta Metallurgica Sinica, 2023, 59(9), 1253(in Chinese).
张雷雷, 陈晶阳, 汤鑫, 等. 金属学报, 2023, 59(9), 1253.
4 Zhang L L, Chen J Y, Ren X D, et al. Journal of Materials Engineering, 2024, 52(4), 120 (in Chinese).
张雷雷, 陈晶阳, 任晓冬, 等. 材料工程, 2024, 52(4), 120.
5 Hou K, Wang M, Zhao P, et al. Journal of Alloys and Compounds, 2022, 905, 164187.
6 Chauvet E, Kontis P, Jägle E A, et al. Acta Materialia, 2018, 142, 82.
7 Idowu O A, Ojo O A, Chaturvedi M C. Materials Science and Enginee-ring A, 2007, 454, 389.
8 Dai P C, Wu J, Wang Z X. Bao-Steel Technology, 2017(2), 29(in Chinese).
代朋超, 吴静, 王资兴. 宝钢技术, 2017(2), 29.
9 Jiang H, Xiang X, Dong J. Journal of Alloys and Compounds, 2022, 929, 167086.
10 Bi Z, Dong J, Zheng L, et al. Journal of Materials Science & Technology, 2013, 29(2), 187.
11 Bai G, Li J, Hu R, et al. Materials Science and Engineering A, 2011, 528(6), 2339.
12 Su R, Hao D, He P, et al. Journal of Alloys and Compounds, 2023, 967, 171744.
13 Pan Q, Zhao X, Yue Q, et al. Journal of Materials Research and Technology, 2022, 20, 3074.
14 Chen Y, Slater T J A, Bai M, et al. Acta Materialia, 2016, 110, 295.
15 Cheng Y, Zhao X B, Yue Q Z, et al. Rare Metal Materials and Engineering, 2023, 52(7), 2599(in Chinese).
程远, 赵新宝, 岳全召, 等. 稀有金属材料与工程, 2023, 52(7), 2599.
16 Academic Committee of the Superallys. China superalloys handbook (finalbook), China Standard Publishing House, China, 2012, pp. 3(in Chinese).
中国金属学会高温材料分会. 中国高温合金手册(下卷). 中国标准出版社, 2012, pp. 3.
17 Yuan Ji J, Zhang Z, Chen J, et al. Vacuum, 2023, 211, 111923.
18 Zhang J, Lu F, Zhang C, et al. Vacuum, 2022, 197, 110863.
19 Tu Y, Mao Z, Seidman D N. Applied Physics Letters, 2012, 101(12), 121910.
20 Xue C, Yu H, Peng T, et al. Solid State Communications, 2024, 394, 115696.
21 Xia P H, Wang W Q, Shi S Y, et al. Rare Metal Materials and Engineering, 2024, 53(7), 2025(in Chinese).
夏鹏辉, 王伟强, 史淑艳, 等. 稀有金属材料与工程, 2024, 53(7), 2025.
22 Jia L, Cui H, Yang S, et al. Journal of Materials Research and Technology, 2023, 23, 5368.
23 Zhang Z, Han Q, Liu Z, et al. Materials Science and Engineering A, 2022, 861, 144379.
24 Jena A, Atabay S E, Brochu M. Materials Science and Engineering A, 2022, 850, 143524.
25 Shi J, Guo C, Li C, et al. Calphad, 2022, 76, 102381.
26 Tan Q, Zhu G, Zhou W, et al. Journal of Alloys and Compounds, 2022, 913, 165196.
27 Song X D, Huo Y L, Song X Q, et al. Journal of Materials Science, 2023, 58(10), 4657.
28 Jiang K, Sheng N, Sun S, et al. Journal of Materials Engineering and Performance, 2022, 31(10), 7881.
29 Zhou T, Feng W, Zhao H, et al. Progress in Natural Science, Materials International, 2018, 28(1), 45.
30 Hua H Y, Xie J, Shu D L, et al. Acta Metallurgica Sinica, 2020, 56(2), 161(in Chinese).
华涵钰, 谢君, 舒德龙, 等. 金属学报, 2020, 56(2), 161.
31 Qu D P, Liu J S, Gu X, et al. Special Casting & Nonferrous Alloys, 2015, 35(7), 779(in Chinese).
曲殿鹏, 刘家胜, 顾欣, 等. 特种铸造及有色合金, 2015, 35(7), 779.
32 Shui L, Fu J. High Temperature Materials and Processes, 2022, 41(1), 555.
33 Huang Z, He X, Chen K, et al. Journal of Alloys and Compounds, 2022, 912, 165107.
34 Zhao Y, Hou L, Li X, et al. Materials Characterization, 2023, 200, 112914.
35 Kalinushkin E P, Bol'shakova V A, Nonko D L, et al. Metal Science and Heat Treatment, 1999, 41(2), 65.
36 Li X, Jia C, Jiang Z, et al. JOM, 2020, 72, 4139.
37 Zhang L, Huang Z, Jiang L, et al. Materials Science and Engineering A, 2019, 744, 481.
38 Tai W, Zhang R, Cui C, et al. Crystals, 2023, 13(11), 1582.
39 Li D, Cai W, Liu Z, et al. Vacuum, 2022, 198, 110859.
40 Huang M, Ma Y, Wu Y, et al. Journal of Alloys and Compounds, 2024, 975, 172929.
41 Gong L, Chen B, Zhang L, et al. Journal of Materials Science & Technology, 2018, 34(5), 811.
42 Zhao P, Gu Y, Yang S, et al. Metallurgical and Materials Transactions B, 2023, 54(2), 698.
43 Shuang G A O, Song Z, Bo H E, et al. Transactions of Nonferrous Metals Society of China, 2022, 32(2), 559.
44 Peng P, Liu Z, Xu Y, et al. China Foundry, 2023, 20(5), 376.
45 Cheng Y, Zhao X, Xia W, et al. Progress in Natural Science, Materials International, 2022, 32(6), 745.
46 Hu P, Zhao W, Ru Y, et al. Journal of Materials Science, 2022, 57(27), 12916.
47 Song W, Wang D, Tang C, et al. Materials Science and Engineering A, 2023, 883, 145481.
48 Tian S G, Xia D, Li T, et al. Journal of Aeronautical Materials, 2008(4), 12(in Chinese).
田素贵, 夏丹, 李唐, 等. 航空材料学报, 2008(4), 12.
49 Yang D Y, Jin T, Zhao N R, et al. Journal of Aeronautical Materials, 2003(S1), 17(in Chinese).
阳大云, 金涛, 赵乃仁, 等. 航空材料学报, 2003(S1), 17.
50 Han Y, Xue X, Zhang T, et al. Materials Science and Engineering A, 2016, 667, 391.
51 Song X, Wang Y, Gong J, et al. Materials Characterization, 2023, 196, 112640.
52 Guo J T. Superalloy Materials(first book), Science Press, China, 2008, pp. 95(in Chinese).
郭建亭. 高温合金材料学(上册), 科学出版社, 2008, pp. 95.
53 Singh J B, Ravikanth K V. Journal of Phase Equilibria and Diffusion, 2024, 45(5), 824.
54 Yonemura M, Mitsuhara M. Philosophical Magazine, 2018, 98(36), 3247.
55 Schirra J J, Caless R H, Hatala R W. Superalloys, 1991, 718(625), 375.
56 Liu G, Liu L, Zhao X B, et al. Materials Reports, 2008(9), 38(in Chinese).
刘刚, 刘林, 赵新宝, 等. 材料导报, 2008(9), 38.
57 Pu S, Xie G, Wang L, et al. Acta Metallurgica Sinica, 2016, 52(5), 538(in Chinese).
濮晟, 谢光, 王莉, 等. 金属学报, 2016, 52(5), 538.
58 Pan Z Y, Hu X B, Xie G, et al. Journal of Chinese Electron Microscopy Society, 2014, 33(3), 197(in Chinese).
潘智毅, 胡肖兵, 谢光, 等. 电子显微学报, 2014, 33(3), 197.
59 Zhou S, Sheng N, Sun S, et al. Metals and Materials International, 2023, 29(1), 27.
60 Fan L H, Li J L, Sun J D, et al. Acta Metallurgica Sinica, 2024, 60(4), 453(in Chinese).
凡莉花, 李金临, 孙九栋, 等. 金属学报, 2024, 60(4), 453.
61 Hu P P, Chen J Y, Feng Q, et al. The Chinese Journal of Nonferrous Metals, 2011, 21(2), 332(in Chinese).
胡聘聘, 陈晶阳, 冯强, 等. 中国有色金属学报, 2011, 21(2), 332.
62 Ju Y, Wang H, Sang P, et al. Journal of Materials Science, 2023, 58(20), 8535.
63 MacKay R A, Nathal M V, Pearson D D. Metallurgical Transactions A, 1990, 21, 381.
64 Li X Y, Zhang H P, Bai J M, et al. Journal of Alloys and Compounds, 2023, 942, 168757.
65 Rodenkirchen C, Ackerman A K, Mignanelli P M, et al. Metallurgical and Materials Transactions A, 2023, 54(5), 1902.
66 Long F, Yoo Y S, Jo C Y, et al. Journal of Alloys and Compounds, 2009, 478(1-2), 181.
67 Shi Q, Huo J, Cao L, et al. MATEC Web of Conferences. EDP Sciences, 2014, 14, 01002.
68 Yang G, Tian G, Zhang X, et al. Journal of Alloys and Compounds, 2022, 906, 164297.
69 Cheng Y, Zhao X, Xia W, et al. Journal of Materials Research and Technology, 2022, 21, 2672.
70 Ma W Y, Han Y F, Li S S, et al. Acta Metallurgica Sinica, 2006(11), 1191(in Chinese).
马文有, 韩雅芳, 李树索, 等. 金属学报, 2006(11), 1191.
71 Cui J Y, Zhang J T, Yao J, et al. Rare Metal Materials and Engineering, 2023, 52(4), 1490(in Chinese).
崔金艳, 张建庭, 尧健, 等. 稀有金属材料与工程, 2023, 52(4), 1490.
72 Zhao M M, Zhang X N, Dong P, et al. Journal of Chinese Electron Microscopy Society, 2023, 42(2), 137(in Chinese).
赵蒙蒙, 张晓娜, 董鹏, 等. 电子显微学报, 2023, 42(2), 137.
73 Ai C, Zhao X B, Zhang C, et al. The Chinese Journal of Nonferrous Metals, 2023, 33 (4), 1074(in Chinese).
艾诚, 赵鑫博, 张传, 等. 中国有色金属学报, 2023, 33(4), 1074.
74 Yang D Y, Zhang X, Jin T, et al. Rare Metal Materials and Engineering, 2005(8), 1295(in Chinese).
阳大云, 张炫, 金涛, 等. 稀有金属材料与工程, 2005(8), 1295.
75 Zhang J, Lu F, Liu X, et al. Materials Characterization, 2024, 207, 113470.
76 Cui J Y, Zhang J T, Yao J, et al. Rare Metal Materials and Engineering, 2023, 52(4), 1490(in Chinese).
崔金艳, 张建庭, 尧健, 等. 稀有金属材料与工程, 2023, 52(4), 1490.
77 Cao K, Yang W, Liu C, et al. Journal of Alloys and Compounds, 2023, 942, 168951.
78 Wang B, Zhang J, Pan X J, et al. Acta Metallurgica Sinica, 2017, 53(3), 298 (in Chinese).
王博, 张军, 潘雪娇, 等. 金属学报, 2017, 53(3), 298.
79 Liu Z Y, Fang X, Guo S D. Transactions of Materials and Heat Treatment, 2023, 44(4), 112(in Chinese).
刘志远, 方向, 郭圣东. 材料热处理学报, 2023, 44(4), 112.
80 Tan L, Zhang Y, Jia J, et al. Journal of Iron and Steel Research International, 2016, 23(8), 851.
81 Chen J, Chen J, Wang Q, et al. Materials Letters, 2022, 312, 131656.
82 Luo R, Liu Q, Gao P, et al. Journal of Alloys and Compounds, 2023, 947, 169495.
83 Bai G, Li J, Hu R, et al. Materials Science and Engineering A, 2011, 528(6), 2339.
84 Jiang L, Lei T, Li C W, et al. Journal of Alloys and Compounds, 2023, 949, 169868.
85 Sun W, Qin X, Guo J, et al. Materials & Design, 2015, 69, 81.
86 Qin X Z, Guo J T, Yuan C, et al. Materials Letters, 2008, 62(15), 2275.
87 Chen J, Huo Q, Chen J, et al. Materials Science and Engineering A, 2021, 799, 140163.
88 Szczotok A, Rodak K. Conference Series:Materials Science and Engineering, 2012, 35(1), 012006.
89 Tsai Y L, Wang S F, Bor H Y, et al. Materials Science and Engineering A, 2013, 571, 155.
90 Sun W, Qin X Z, Guo J T, et al. Acta Metallurgica Sinica, 2015, 51(1), 67(in Chinese).
孙文, 秦学智, 郭建亭, 等. 金属学报, 2015, 51(1), 67.
91 Qin X Z, Wang J Q, Cheng S H, et al. Materials Science and Enginee-ring A, 2023, 881, 145416.
92 Quan Q, Sun S, Sheng N, et al. Materials, 2022, 15(21), 7509.
93 Zheng L, Zhang G, Lee T L, et al. Materials & Design, 2014, 61, 61.
94 Li H, Jiang B, Gao M, et al. Materials & Design, 2019, 181, 107983.
95 Matsuo T, Ueki M, Takeyama M, et al. Journal of Materials Science, 1987, 22, 1901.
96 Bai Y, Zhang R, Cui C, et al. Materials Letters, 2023, 335, 133798.
97 Liu X, Hu R, Zou H, et al. Journal of Alloys and Compounds, 2023, 938, 168532.
98 Chen N, Zheng D, Niu P, et al. Materials Characterization, 2023, 202, 113018.
99 He M R, Banerjee A, Marvel C J, et al. Metallurgical and Materials Transactions A, 2022, 53(8), 2926.
100 Han S, Choe B, Kim D, et al. Engineering Failure Analysis, 2024, 158, 107989.
101 Liu S, Wang C, Yan P, et al. Materials Science and Engineering A, 2022, 850, 143594.
102 Yu X X, Wang C Y. Philosophical Magazine, 2012, 92(32), 4028.
103 Liu F H, Wang C Y. RSC Advances, 2017, 7(31), 19124.
104 Song W, Tang C, Wang D, et al. Materials Science and Engineering A, 2022, 857, 143991.
105 Zhu H, Wang J, Chen Y, et al. Physical Review Materials, 2023, 7(4), 043602.
106 Feng R, Hung C Y, Antonov S, et al. Materials Advances, 2024, 5(22), 8847.
107 Eriş R, Akdeniz M V, Mekhrabov A O. Journal of Alloys and Compounds, 2023, 936, 167869.
108 Tawancy H M, Aboelfotoh M O. Scripta Materialia, 2008, 59(8), 846.
109 Li X, He Y, Liu L, et al. Scripta Materialia, 2022, 220, 114931.
110 Verma A, Singh J B. Metallurgical and Materials Transactions A, 2021, 52, 4317.
111 Song X, Wang Y, Zhao X, et al. Journal of Alloys and Compounds, 2022, 911, 164959.
112 Giese S, Bezold A, Pröbstle M, et al. Metallurgical and Materials Transactions A, 2020, 51, 6195.
113 Xia F, Sangid M D, Xiao Y, et al. Philosophical Magazine, 2020, 100(8), 998.
114 Yin H, Gao Y, Gu Y. Materials Characterization, 2017, 127, 288.
115 Rush M T, Colegrove P A, Zhang Z, et al. Journal of Materials Processing Technology, 2012, 212(1), 188.
116 Sidhu R K, Richards N L, Chaturvedi M C. Materials Science and Technology, 2007, 23(2), 203.
117 Kazempour-Liasi H, Tajally M, Abdollah-Pour H. Journal of Materials Engineering and Performance, 2020, 29, 1068.
118 Mehdizadeh M, Farhangi H. Metals and Materials International, 2022, 28(11), 2719.
119 Zhang L, Li Y, Zhang Q, et al. Materials Science and Engineering A, 2022, 844, 142947.
120 Francis A, Thirugnanasambantham K G, Ramesh R, et al. International Journal on Interactive Design and Manufacturing, 2022, 1.
121 Strunz P, Petrenec M, Polák J, et al. Metals, 2016, 6(2), 37.
122 Barbieri G, Cognini F, de Crescenzo C, et al. Metals, 2024, 14(1), 124.
123 Montanari R, Varone A, Barbieri G, et al. Surface and Interface Analysis, 2016, 48(7), 483.
124 Jahangiri M R, Arabi H, Boutorabi S M A. Transactions of Nonferrous Metals Society of China, 2014, 24(6), 1717.
125 Kazempour-Liasi H, Tajally M, Abdollah-Pour H. Engineering Research Express, 2019, 1(2), 025026.
126 Xie J, Shu D, Hou G, et al. Journal of Central South University, 2021, 28(9), 2628.
127 Li S, Wang B, Shi D, et al. Journal of Alloys and Compounds, 2019, 783, 565.
128 Zhou X Y. Research on laser micro-melting welding repair process and post-heat treatment of K417 nickel-based superalloy. Master's Thesis, Nanjing University of Aeronautics and Astronautics, China, 2022(in Chinese).
周心怡. K417镍基高温合金激光微熔焊接修复工艺及后热处理研究. 硕士学位论文, 南京航空航天大学, 2022.
129 Luo X J, Ma G J, Wang X F, et al. Journal of Aeronautical Materials, 2011, 31(4), 29(in Chinese).
罗学军, 马国君, 王晓峰, 等. 航空材料学报, 2011, 31(4), 29.
130 Lu Y, Zhao J, Shi L, et al. Ordnance Material Science and Engineering, DOI:10. 14024/j. cnki. 1004-244x. 20240819. 005(in Chinese).
陆煜, 赵健, 石磊, 等. 兵器材料科学与工程, DOI:10. 14024/j. cnki. 1004-244x. 20240819. 005.
131 Liao Z B, Guo W M, Zhao M H, et al. Journal of Mechanical Engineering, 2013, 49(20), 170(in Chinese).
廖宗博, 国为民, 赵明汉, 等. 机械工程学报, 2013, 49(20), 170.
132 Zheng Z, Zhou J Y, Zhao W X, et al. Materials Science Forum, 2019, 944, 411.
133 Yang J X, Wei W, Liu L, et al. Rare Metal Materials and Engineering, 2016, 45(4), 975(in Chinese).
杨金侠, 魏薇, 刘路, 等. 稀有金属材料与工程, 2016, 45(4), 975.
134 Xu Z H, Xie Z X, Kang M D, et al. Materials Reports, 2021, 35(22), 22115(in Chinese).
许章华, 谢志雄, 康茂东, 等. 材料导报, 2021, 35(22), 22115.
135 Zhang K, Xie F, Rui H U, et al. Transactions of Nonferrous Metals Society of China, 2016, 26(7), 1885.
136 Teng Y J, Ou M Q, Xing W W, et al. Rare Metal Materials and Engineering, 2019, 48(5), 1505(in Chinese).
滕雨均, 欧美琼, 邢炜伟, 等. 稀有金属材料与工程, 2019, 48(5), 1505.
137 Wang J M, Shao C, Zhao M H, et al. Modern Manufacturing Engineering, 2007(9), 91(in Chinese).
王建明, 邵冲, 赵明汉, 等. 现代制造工程, 2007(9), 91.
138 Wang P F, Hu R, Zhong H, et al. Special Casting & Nonferrous Alloys, 2012, 32(3), 223(in Chinese).
王鹏飞, 胡锐, 钟宏, 等. 特种铸造及有色合金, 2012, 32(3), 223.
139 Huang W P, Yu H C, Yin J, et al. Acta Metallurgica Sinica, 2016, 52(9), 1089(in Chinese).
黄文普, 喻寒琛, 殷杰, 等. 金属学报, 2016, 52(9), 1089.
140 Monajati H, Jahazi M, Bahrami R, et al. Materials Science and Engineering A, 2004, 373(1-2), 286.
141 Reed R C, Jackson M P, Na Y S. Metallurgical and Materials Transactions A, 1999, 30, 521.
142 Chen Y, Tian G F, Zhou L, et al. Materials Science Forum, 2017, 898, 430.
143 Cieslak M J, Headley T J, Romig A D. Metallurgical Transactions A, 1986, 17, 2035.
144 Ahmad M, Akhter J I, Akhtar M, et al. Journal of Alloys and Compounds, 2005, 390(1-2), 88.
145 Nematzadeh F, Akbarpour M R, Parvizi S, et al. Materials & Design (1980-2015), 2012, 36, 94.
146 Ojo O A, Wang Y L, Chaturvedi M C. Materials Science and Enginee-ring A, 2008, 476(1-2), 217.
147 Arulmurugan B, Agilan M, Jerome S, et al. Sādhanā, 2018, 43, 1.
148 Lopez-Galilea I, Koßmann J, Kostka A, et al. Journal of Materials Science, 2016, 51, 2653.
149 Liang T, Wang L, Liu Y, et al. Journal of Materials Science, 2020, 55(27), 13389.
150 Natesh M, Selvaraj S K, Arivazhagan N, et al. Silicon, 2023, 15(1), 365.
151 Ola O T, Ojo O A, Chaturvedi M C. Philosophical Magazine, 2014, 94(29), 3295.
152 Ojo O A, Richards N L, Chaturvedi M C. Metallurgical and Materials Transactions A, 2006, 37, 421.
153 Vishwakarma K R, Richards N L, Chaturvedi M C. Materials Science and Engineering A, 2008, 480(1-2), 517.
154 Gao Z. Journal of Physics: Conference Series, 2022, 2361(1), 012003.
155 Teng J, Gong X, Yang B, et al. Corrosion Science, 2022, 198, 110141.
156 Sun X, Zhang L, Pan Y, et al. Materials Today Communications, 2024, 38, 107826.
157 Li W, Zhao X, Cheng Y, et al. Corrosion Science, 2023, 223, 111458.
158 Shen Y, Ju Q, Xu G H, et al. Materials Letters, 2022, 328, 133226.
159 Volders C, Angelici V A, Waluyo I, et al. npj Materials Degradation, 2022, 6(1), 52.
160 Liu S, Ye X X, Ming C, et al. Journal of Alloys and Compounds, 2023, 933, 167725.
161 Yu S, Zhan X, Liu F, et al. Journal of Alloys and Compounds, 2022, 904, 164071.
162 Izzuddin H, Hayashi S, Yoneda S, et al. Materials and Corrosion, 2020, 71(9), 1488.
163 Ke H, Taylor C D. Journal of the Electrochemical Society, 2020, 167(11), 111502.
164 Li Q, Liu F, Li Y, et al. Crystals, 2024, 14(4), 307. |
|
|
|
渝公网安备50019002502923号 © Editorial Office of Materials Reports.
2026, Vol. 40 
