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材料导报  2026, Vol. 40 Issue (8): 25040190-8    https://doi.org/10.11896/cldb.25040190
  无机非金属及其复合材料 |
基于静电纺丝与水热技术制备ZnO/CuO分级结构及其光催化性能研究
谢芸瑛1, 范超2, 王小梅1, 孙发哲3,*
1 山东理工大学物理与光电工程学院,山东 淄博 255000
2 中国石化安全工程研究院有限公司化学安全国家重点实验室,山东 青岛 266104
3 山东理工大学分析测试中心,山东 淄博 255000
Preparation and Photocatalytic Performance Study of ZnO/CuO Hierarchical Structure Based on Electrospinning and Hydrothermal Technology
XIE Yunying1, FAN Chao2, WANG Xiaomei1, SUN Fazhe3,*
1 School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, Shandong, China
2 SINOPEC Research Institute of Safety Engineering Co., Ltd. State Key Laboratory of Chemical Safety, Qingdao 266104, Shandong, China
3 Analysis and Testing Center, Shandong University of Technology, Zibo 255000, Shandong, China
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摘要 通过静电纺丝与水热技术相结合的方法制备了ZnO/CuO分级结构,通过 X 射线衍射(XRD)、拉曼光谱(Raman)、扫描电子显微镜(SEM)、傅里叶变换红外光谱(FTIR)和紫外漫反射光谱(UV-Vis)对ZnO/CuO纳米纤维和分级结构进行了表征,对比研究了ZnO/CuO纳米纤维和分级结构的光催化性能。结果表明,ZnO/CuO分级结构的光催化性能高于 ZnO/CuO纳米纤维,且随着催化剂用量的增加,光催化效率越来越高。由紫外可见吸收光谱可知,当使用10 mg ZnO/CuO分级结构作为催化剂时,甲基橙(MO)在462 nm处的特征吸收峰在50 min后几乎消失,MO溶液颜色接近无色。分级结构不仅能够增加材料的比表面积、提供更多的催化位点,还能够缩短载流子的扩散路径,使得光生电子-空穴对更加高效地参与光催化反应。
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谢芸瑛
范超
王小梅
孙发哲
关键词:  ZnO/CuO分级结构  静电纺丝  水热法  光催化    
Abstract: ZnO/CuO hierarchical structure was fabricated with electrostatic spinning and hydrothermal method. The nanofiber of ZnO/CuO and hierarchical structure of ZnO/CuO were characterized by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and ultraviolet diffuse reflectance spectroscopy (UV-Vis). The photocatalytic properties of ZnO/CuO nanofiber and ZnO/CuO hierarchical structure were systematically investigated. The results displayed that the photocatalytic performances of ZnO/CuO hierarchical structure were higher than that of ZnO/CuO nanofiber. The efficiency of photocatalysis became better with the increase of catalyst dosage. According to the UV-Vis absorption spectra, the characteristic absorption peak of methyl orange (MO) at 462 nm almost disappeared after 50 min (the MO solution was nearly colorless) when 10 mg of ZnO/CuO hierarchical structure was used as the catalyst. This can be attributed to the fact that the hierarchical structure not only enhanced the specific surface area of the material and promoted the generation of more catalytic sites, but also shortened the diffusion path of charge carriers, thereby enabling photogenerated electron-hole pairs to participate more efficiently in the photocatalytic reaction.
Key words:  ZnO/CuO hierarchical structure    electrospinning    hydrothermal method    photocatalytic
出版日期:  2026-04-25      发布日期:  2026-05-06
ZTFLH:  O643.36  
基金资助: 山东省自然科学基金(ZR2022MF241;ZR2017BF025);教育部产学合作协同育人项目(202101256024);国家自然科学基金(2200207;61704098)
通讯作者:  * 孙发哲,博士,山东理工大学分析测试中心高级工程师,目前主要从事光催化材料、气敏材料和静电纺丝技术等方面的研究。sunfazhe@163.com   
作者简介:  谢芸瑛,山东理工大学硕士研究生,在王小梅副教授的指导下进行研究。目前主要研究领域为气体传感器、光催化。
引用本文:    
谢芸瑛, 范超, 王小梅, 孙发哲. 基于静电纺丝与水热技术制备ZnO/CuO分级结构及其光催化性能研究[J]. 材料导报, 2026, 40(8): 25040190-8.
XIE Yunying, FAN Chao, WANG Xiaomei, SUN Fazhe. Preparation and Photocatalytic Performance Study of ZnO/CuO Hierarchical Structure Based on Electrospinning and Hydrothermal Technology. Materials Reports, 2026, 40(8): 25040190-8.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25040190  或          https://www.mater-rep.com/CN/Y2026/V40/I8/25040190
1 Teng B, Zhao Z, Xia L, et al. Chemosphere, 2024, 369, 143844.
2 Restivo J, Orge C A, Soares O S G P, et al. Journal of Environmental Chemical Engineering, 2024, 12(3), 112859.
3 Chen X, Wang Y, Li W, et al. Environmental Research, 2020, 188, 109715.
4 Liu J, Zhu H, Qiang Z, et al. Separation and Purification Technology, 2025, 364, 132466.
5 Hsiao P H, Lin K H, Lee Y S, et al. The Journal of Alloys and Compounds, 2024, 1002, 175355.
6 Nangan S, MariaJoseph A, Pattananuwat P, et al. Journal of the Taiwan Institute of Chemical Engineers, 2025, 166, 105487.
7 Zhu J, Ling M, Ma R D, et al. Materials Reports, 2024, 38(11), 38(in Chinese).
朱杰, 凌敏, 马润东, 等. 材料导报, 2024, 38(11), 38.
8 Huang F, Zhang F, Wang Y, et al. Trends in Chemistry, 2024, 6(3), 115.
9 Liu S, Ma L, Liu Y, et al. Journal of Environmental Chemical Engineering, 2024, 12(4), 113136.
10 Chen S, Hu Y H. Catalysis Reviews, 2024, 66(5), 1951.
11 Butola D, Purohit L P. Materials Chemistry and Physics, 2024, 328, 130021.
12 Ramar M, Mariappan S M, Gunasekaran S, et al. ACS Applied Nano Materials, 2024, 7(7), 6935.
13 Rasheed H M, Aroosh K, Meng D, et al. Mater Today Energy, 2025, 48, 101774.
14 Rao M, Bibi I, Majid F, et al. Ceramics International, 2025, 51(7), 8231.
15 Mo R G J L, Bao M R G, Bai L, et al. Materials Reports, 2024, 38(21), 99 (in Chinese).
莫日格吉乐, 包莫日根, 白璐, 等. 材料导报, 2024, 38(21), 99.
16 Pandey S, Srivastava A, Rawat P, et al. ACS Omega, 2024, 9(45), 45169.
17 Thejaswini M, Lakshmi Ranganatha V, Vasanth Patil H B, et al. Ionics, 2024, 30(10), 6611.
18 Silva J M P, Julião R S, Nicácio T C N, et al. The Journal of Alloys and Compounds, 2024, 985, 173978.
19 Lu Q F, Hao X X, Feng Y, et al. Materials Reports, 2024, 38(13), 65 (in Chinese).
陆泉芳, 郝小霞, 冯妍, 等. 材料导报, 2024, 38(13), 65.
20 Jiad M M, Abbar A H. Chemical Engineering Research & Design, 2023, 200, 431.
21 Wang Q, Pornrungroj C, Linley S, et al. Nature Energy, 2022, 7(1), 13.
22 Zerouali M, Bouras D, Daïra R, et al. Optical Materials, 2024, 152, 115495.
23 Nguyen H T, Chan Y Y, Pham M T, et al. Journal of the Taiwan Institute of Chemical Engineers, 2024, 159, 105477.
24 Zerouali M, Bouras D, Daïra R, et al. Ceramics International, 2025, 51(1), 473.
25 Vaddar H, Jangannanavar V D, Basavanagoudra H, et al. Ceramics International, 2025, 51(6), 7001.
26 Upadhaya D, Dhar P D. Journal of the Taiwan Institute of Chemical Engineers, 2022, 132, 104216.
27 Kirkwood N, Singh B, Mulvaney P. Advanced Materials Interfaces, 2016, 3(22), 1600868.
28 Xing H, Lai E, Guo Z, et al. Chemical Engineering Journal, 2020, 394, 124907.
29 Magrin M R, di Bona A, Sygletou M, et al. Applied Surface Science, 2023, 624, 157133.
30 Sudrajat H, Lisovytskiy D, Colmenares J C. Catalysis Science & Technology, 2024, 14(23), 6893.
31 Naumann J, Müller M, Bohn N, et al. ACS Applied Energy Materials, 2024, 7(11), 4786.
32 Lin J, Yao C, Wu L, et al. The Journal of Physical Chemistry C, 2021, 125(17), 9119.
33 Vo N T T, You S J, Pham M T, et al. Environmental Technology & Innovation, 2023, 32, 103285.
34 Bharathi P, Harish S, Archana J, et al. Applied Surface Science, 2019, 484, 884.
35 Lu W, Gu T, Jing X, et al. The Journal of Alloys and Compounds, 2023, 968, 171864.
36 Bi F, Zhou B, Li R, et al. Materials Today Communications, 2024, 41, 111066.
37 Shao Q, Xing B, Du Z, et al. Polymers, 2024, 16(22), 103390.
38 Su W, Yang Q, Li T, et al. Small Methods, 2024, 8(9), 2301754.
39 Wang K, Liu W R, Jiang P, et al. Chinese Journal of Inorganic Chemistry, 2024, 40(7), 1270 (in Chinese).
王坤, 刘文蕊, 江鹏, 等. 无机化学学报, 2024, 40(7), 1270.
40 Kong Q, Sun J J, Ji Y Y, et al. Journal of Ceramics, 2023, 44(3), 509 (in Chinese).
孔琦, 孙家杰, 姬圆圆, 等. 陶瓷学报, 2023, 44(3), 509.
41 Shao Y, Luo Z, Bao M, et al. Chemical Engineering Journal, 2023, 474, 145634.
42 Shi Y, Zhang S, Xu J, et al. Journal of Analytical and Applied Pyrolysis, 2022, 165, 105566.
43 Sun C F, Hu G L, Cao J J, et al. CIESC Journal, DOI: 10.11949/0438-1157.20241498(in Chinese).
孙传付, 胡桂林, 曹俊杰, 等. 化工学报, DOI: 10.11949/0438-1157.20241498.
44 Saravanan R, Mansoob K M, Gupta V K, et al. Journal of Colloid and Interface Science, 2015, 452, 126.
45 Liu S L, Yang Q F, Qiu H Q, et al. Technology of Water Treatment, 2025, 51(2), 99 (in Chinese).
刘松麟, 杨庆峰, 邱辉强, 等. 水处理技术, 2025, 51(2), 99.
46 Alarcon-Llado E, Cusco R, Ibanez J, et al. MRS Online Proceedings Library, 2007, 957(1), 711.
47 Kahouli M, Tounsi N, Mzabi N, et al. Advanced Powder Technology, 2018, 29(2), 325.
48 Fedorov A V, Kukushkin R G, Yeletsky P M, et al. Journal of Alloys and Compounds, 2020, 844, 156135.
49 Kumar A, Sofi A H, Shah M A. Iranian Journal of Science, 2023, 47(5), 1883.
50 Khoshsang H, Abbasi K, Ghaffarinejad A. Inorganic Chemistry Communications, 2023, 155, 111083.
51 Yousefinia A, Khodadadi M, Mortazavi-Derazkola S. Environmental Technology & Innovation, 2023, 32, 103340.
52 Uma H B, Kumar M S V, Ananda S. Journal of Molecular Structure, 2022, 1264, 133110.
53 Jabessa M T, Thillai A P, Feyisa B R, et al. Results in Chemistry, 2024, 7, 101369.
54 Cao F, Wang T, Ji X. Applied Surface Science, 2019, 471, 417.
55 Wang X, Deng M, Zhao Z, et al. Materials Chemistry and Physics, 2022, 276, 125305.
56 Thien T D, Chung N D, Phong K X, et al. Ceramics International, 2024, 50(15), 27573.
57 Varsha G S, Pavithran R, Bose R J. Ceramics International, 2024, 50(20, Part B), 39262.
58 Kovalev I A, Petrov A A, Ibragimova O A, et al. Mendeleev Communications, 2018, 28(5), 541.
59 Huang X, Niu Y, Peng Z, et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 580, 123747.
60 Sun K, Qian Y, Li D, et al. Advanced Materials, 2024, 36(52), 2411118.
61 Tan J, Chen X R, Chen W B, et al. Materials Reports, 2024, 38(S1), 81 (in Chinese).
谭俊, 陈喜蓉, 陈文斌, 等. 材料导报, 2024, 38(S1), 81.
62 Mejia-Bernal J R, Gómez-Solís C, Juárez-Ramírez I, et al. Journal of Materials Science: Materials in Engineering, 2025, 20(1), 38.
63 Mansurov R R, Zverev V S, Safronov A P. Journal of Catalysis, 2022, 406, 9.
64 Wang L, Li T, Tao L, et al. Process Safety and Environmental Protection, 2022, 158, 79.
65 Xu H Z, Li G Z, Zhao G Z, et al. Materials Reports, 2022, 36(24), 223 (in Chinese).
许洪祝, 李长波, 赵国峥, 等. 材料导报, 2022, 36(24), 223.
66 Li Y Y, Pu H Z, Zeng H L, et al. Materials Reports, 2022, 36(10), 15 (in Chinese).
李园园, 蒲红争, 曾寒露, 等. 材料导报, 2022, 36(10), 15.
67 Slimani Y, Khan A, Sivakumar R, et al. Journal of Molecular Structure, 2025, 1322, 140366.
68 Mubeen K, Irshad A, Safeen A, et al. Journal of Saudi Chemical Society, 2023, 27(3), 101639.
69 Sarengan N, Salaeh S, Sagadevan S, et al. Journal of Materials Science: Materials in Electronics, 2024, 35(32), 2054.
70 Acedo-Mendoza A G, Infantes-Molina A, Vargas-Hernández D, et al. Materials Science in Semiconductor Processing, 2020, 119, 105257.
71 Yang N, Li R, Xu Y, et al. Environmental Research, 2025, 268, 120789.
72 Li K, Li M, Su C, et al. Inorganic Chemistry, 2025, 64(12), 6224.
73 Muthukumar R, Balaji G. Diamond and Related Materials, 2025, 152, 111941.
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