3D打印聚乳酸的改性研究与应用进展

doi:10.11896/cldb.22100107

材料导报

2024, Vol. 38

Issue (8): 22100107-10 https://doi.org/10.11896/cldb.22100107

高分子与聚合物基复合材料

3D打印聚乳酸的改性研究与应用进展

郑思铭¹, 李蔚^1,*, 杨函瑞¹, 陈松², 魏取福^1,*

1 江南大学纺织科学与工程学院,江苏无锡 214122
2 江苏苏丝丝绸股份有限公司,江苏宿迁 223800

Research Progress in the Modification and Applications of 3D Printed Polylactic Acid

ZHENG Siming¹, LI Wei^1,*, YANG Hanrui¹, CHEN Song², WEI Qufu^1,*

1 College of Textile Science and Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China
2 Jiangsu Susi Silk Joint Stock Co., Suqian 223800, Jiangsu, China

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摘要聚乳酸(PLA)是一种生物可降解热塑性聚酯,是极有前景的生物基可降解材料之一。PLA具有优异的力学性能、良好的可塑性及生物相容性,是理想的3D打印材料。3D打印PLA材料在多个领域尤其是医用方面有巨大的潜力。然而,PLA固有的脆性和较差的耐热、耐水解性限制了它的应用范围。近年来,学者对3D打印PLA的改性进行了大量研究。本文归纳了3D打印PLA的研究进展,分别从共混改性、复合改性、立构复合、涂层法和化学改性这几方面讨论了提高材料性能的原理与方法,并对相关性能进行了分析对比。共混法虽然简单易操作,但不利于材料的均匀化,且有时改性效果不够明显。复合改性向PLA中加入碳基添加剂、金属添加剂、植物纤维等填料,改性同时可赋予3D打印PLA更多功能,但易出现界面不相容等问题。此外,还有立构复合、涂层法、化学改性等新方法具有重要的研究价值。在此基础上,结合目前3D打印PLA在实际应用中的发展情况,分析了3D打印PLA仍存在的问题,对3D打印PLA未来的研究方向进行了展望。

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	郑思铭
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关键词: 聚乳酸 3D打印力学性能热性能耐水解性

Abstract: Polylactic acid (PLA) is a biodegradable thermoplastic polyester, which is one of the most promising biodegradable materials. PLA is an ideal 3D printing material with excellent mechanical properties, good plasticity, and biocompatibility. 3D printed PLA materials exhibit high potential in various fields, particularly in biomedical and tissue engineering. However, the inherent brittleness, poor heat-resistance, and inferior hydrolysis resistance limit the applications of PLA materials. Recently, scholars have conducted a number of studies to improve properties of 3D printed PLA. This article summarizes the research progress of 3D printing of PLA materials, including blending, composite preparation, stereo-comple-xation, coating and chemical modification. Major principles and protocols of these methods to improve properties of PLA are discussed, with detailed analysis and comparison of relevant properties. Although blending is easy to operate, it is not conducive to the homogenization of PLA materials, sometimes with limited improvement in properties. Carbon based additives, metal additives, plant fibers, and other fillers provide 3D printed PLA multiple functions. However, interfacial incompatibility remains a problem in composite preparation. Furthermore, new methods, such as stereo-complexation, coating, and chemical modification are also valuable methods to be discovered. Considering the development requirements of 3D printed PLA in practical applications, existing problems in current PLA materials are systematically analyzed to serve as an access threshold for quality 3D printed PLA to be considered in real applications.

Key words: polylactic acid 3D printing mechanical property thermal property hydrolysis resistance

出版日期: 2024-04-25 发布日期: 2024-04-28

ZTFLH:

TQ323.41

基金资助: 中央高校基本科研业务费专项资金资助(JUSRP51907A); 无锡市科技发展资金基础研究项目(K20221014); 江南大学基本科研计划-青年基金(JUSRP12030); 江苏苏丝丝绸股份有限公司产学研

通讯作者: *李蔚,江南大学纺织科学与工程学院副教授、硕士研究生导师。2008年东华大学高分子材料科学与工程专业本科毕业,2011年获美国内布拉斯加大学林肯分校生物系统工程硕士学位,2019年获美国内布拉斯加大学林肯分校纺织科学博士学位,同年赴江南大学纺织科学与工程学院任教,兼江苏格罗瑞节能科技有限公司科技副总。目前主要从事绿色高分子的资源化再生及其在纺织和其他领域应用的研究工作。发表论文15余篇,包括Bioresource Technology、ACS Sustainable Chemistry & Engineering、Journal of Cleaner Production、Journal of Materials Chemistry A、Industrial Crops and Products等。wli31@jiangnan.edu.cn
魏取福,江南大学纺织科学与工程学院博士、教授、博士研究生导师。2004年毕业于英国Heriot-Watt大学,获得博士学位,2010年美国哈佛大学访问学者。发表学术论文300篇以上,其中SCI检索论文200多篇,EI检索论文20多篇,CSCD论文100多篇,获国家发明专利10余项。主持和承担国家重点研发计划、国家863计划项目、国家自然科学基金、教育部重点项目、江苏省产学研等项目10余项,获教育部自然科学二等奖、江苏省教学成果一等奖、纺织工业协会教学成果一等奖等科研教学奖励。主编英文专著Surface Modification of Textiles、Functional Nanofibres and Their Applications,参编国家“十一五”规划教材《纤维材料改性》。qfwei@jiangnan.edu.cn

作者简介: 郑思铭,2021年6月于江南大学获得工学学士学位。现为江南大学纺织科学与工程学院硕士研究生,在魏取福教授与李蔚副教授的指导下进行研究。目前主要研究领域为聚乳酸及其相关材料。

引用本文:

郑思铭, 李蔚, 杨函瑞, 陈松, 魏取福. 3D打印聚乳酸的改性研究与应用进展[J]. 材料导报, 2024, 38(8): 22100107-10.
ZHENG Siming, LI Wei, YANG Hanrui, CHEN Song, WEI Qufu. Research Progress in the Modification and Applications of 3D Printed Polylactic Acid. Materials Reports, 2024, 38(8): 22100107-10.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.22100107 或 https://www.mater-rep.com/CN/Y2024/V38/I8/22100107

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