锌阳极氮掺杂多孔碳表面功能层设计及可逆性研究

doi:10.11896/cldb. 23040217

材料导报

2024, Vol. 38

Issue (6): 23040217-6 https://doi.org/10.11896/cldb. 23040217

电化学能源材料与器件

锌阳极氮掺杂多孔碳表面功能层设计及可逆性研究

陈京健, 徐能能^*, 芦拓, 魏群山^*

东华大学环境科学与工程学院,上海 201600

Design and Reversibility Study of Nitrogen-doped Porous Carbon Surface Functional Layer for Zinc Anodes

CHEN Jingjian, XU Nengneng^*, LU Tuo, WEI Qunshan^*

College of Environmental Science and Engineering, Donghua University, Shanghai 201600, China

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摘要锌阳极因枝晶生长、析氢、形变和钝化等挑战,成为限制锌空气电池充放电循环性能的关键因素。本工作以聚季铵盐为碳源和氮源,通过硬模板法制备出具有丰富介孔结构的碳材料,并将其作为锌阳极的表面功能层(N-MC@Zn)。其中,N-MC@Zn的比表面积高达590.06 m²·g^-1,平均孔径为22 nm。研究表明,锌阳极表面构建氮掺杂的多孔碳功能层,在一定程度上有效缓解了上述寄生反应带来的负面影响。特别是多孔碳涂层丰富的孔隙为锌沉积/剥离提供了缓冲区,极大提高了锌离子的沉积动力学,稳定了其沉积/剥离过程,缓解了锌阳极的析氢腐蚀;此外,多孔碳涂层内的各向异性避免了尖端效应,抑制了枝晶生长。基于上述优势,N-MC@Zn表现出优异的充放电稳定性(140 h,700次循环)、倍率充放电特性(0.5C～10C)以及放电容量。以上结果表明,多孔碳材料可作为高性能锌阳极功能层材料,为锌阳极涂层设计领域提供了新的视角。

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	陈京健
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关键词: 锌阳极介孔碳表面改性锌枝晶锌空气电池

Abstract: Zinc anode has become a key factor limiting the cycling performance of zinc-air batteries due to challenges such as dendrite growth, hydrogen evolution, deformation, and passivation. In this study, carbon materials with abundant mesoporous structures were prepared using quaternary ammonium salts as carbon and nitrogen sources through a hard template method, and they were used as a surface functional layer for the zinc anode (N-MC@Zn). The N-MC@Zn material had a high specific surface area of 590.06 m²·g^-1 and an average pore size of 22 nm. The research showed that constructing a nitrogen-doped porous carbon functional layer on the surface of the zinc anode effectively mitigated the negative effects caused by the aforementioned challenges. In particular, the abundant pores in the porous carbon coating provided a buffer zone for zinc deposition/stripping, greatly accelerating the deposition kinetics and stabilizing the deposition/stripping process of zinc ions, thus alleviating hydrogen evolution corrosion of the zinc anode. Furthermore, the anisotropy within the porous carbon coating prevented the growth of dendrites by avoiding the tip effect. Based on these advantages, N-MC@Zn exhibited excellent discharge and charge stability (140 h, 700 cycles), rate capability (from 0.5C to 10C), and discharge capacity. These results demonstrate that porous carbon materials can serve as high-performance functional layer materials for zinc anodes and provide a new perspective for the design of zinc anode coatings.

Key words: zinc anode mesoporous carbon surface modification zinc dendrite zinc-air batteries

出版日期: 2024-03-25 发布日期: 2024-04-07

ZTFLH:

TM911

基金资助: 中央高校基本科研业务费专项项目(2232022D-18);上海市扬帆计划(22YF1400700); 国家自然科学基金面上项目(21972017);上海市“科技创新行动计划”港澳台科技合作项目(19160760600);上海市“科技创新行动计划”基础重点项目(19JC1410500)

通讯作者: ^*徐能能,东华大学副研究员、硕士研究生导师。2019年获东华大学环境科学与工程工学博士学位,并在美国University of Louisiana at Lafayatee开展联合培养、博士后以及助理教授等研究工作,长期致力于能源环境材料的开发、设计及应用,包括小分子电催化电极材料结构优化、电极表界面调控及高比能锌空气电池/燃料电池等;发表期刊论文40余篇,授权发明/实用新型专利16项;先后主持/参与了美国能源部/国家自然科学基金项目、上海市启明星计划扬帆专项以及中央高校基础研究项目等项目。
魏群山,东华大学副教授、硕士研究生导师,莫伊大学孔子学院中方院长。2007年于中国科学院生态环境研究中心获环境科学与工程理学博士学位。长期致力于环境水质学、水污染控制理论与工程技术、混凝机理及环境微界面过程等多个领域。主持国家自然科学基金面上项目、青年科学基金项目多项;发表论文数十篇,申请国家专利多项,与国内外学者合作著作一部。

作者简介: 陈京健,2021年6月于南京理工大学泰州科技学院获得工学学士学位,于2023年6月在东华大学获得工学硕士学位。主要研究领域为锌空气电池锌负极。

引用本文:

陈京健, 徐能能, 芦拓, 魏群山. 锌阳极氮掺杂多孔碳表面功能层设计及可逆性研究[J]. 材料导报, 2024, 38(6): 23040217-6.
CHEN Jingjian, XU Nengneng, LU Tuo, WEI Qunshan. Design and Reversibility Study of Nitrogen-doped Porous Carbon Surface Functional Layer for Zinc Anodes. Materials Reports, 2024, 38(6): 23040217-6.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb. 23040217 或 https://www.mater-rep.com/CN/Y2024/V38/I6/23040217

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