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材料导报  2024, Vol. 38 Issue (4): 22040345-6    https://doi.org/10.11896/cldb.22040345
  高分子与聚合物基复合材料 |
三维碳纤维基复合材料及其在海水溶解氧电池中的应用性能
王金涛1,2, 段体岗2,*, 郭建章1, 马力2, 余聚鑫2, 张海兵2
1 青岛科技大学机电工程学院,山东 青岛 266237
2 中国船舶集团有限公司第七二五研究所海洋腐蚀与防护重点实验室,山东 青岛 266237
Three-dimensional Carbon Fiber Matrix Composites and Their Application Performance in Seawater Dissolved Oxygen Batteries
WANG Jintao1,2, DUAN Tigang2,*, GUO Jianzhang1, MA Li2, YU Juxin2, ZHANG Haibing2
1 College of Electromehanical Engineering, Qingdao University of Science & Technology, Qingdao 266237, Shandong, China
2 State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266237, Shandong, China
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摘要 以三维碳纤维刷为基体通过一步水热还原法制备了石墨烯/铂复合电极(Pt-G/CFB),分析结果表明碳纤维丝束上均匀生长和包覆了大量Pt纳米微粒和石墨烯,Pt晶粒尺寸约3.1 nm;复合电极具有较大比表面积和丰富的介孔结构。Pt-G催化剂在氧还原反应(ORR)中表现出良好的催化性能和稳定性。将复合电极与Al合金阳极组成海水溶解氧电池进行放电测试,电池在低温、贫氧及小电流密度条件下放电性能良好,最大功率密度达到197 mW/L。
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王金涛
段体岗
郭建章
马力
余聚鑫
张海兵
关键词:  海水溶解氧电池  改性碳纤维  石墨烯-铂复合催化剂  氧还原反应  恒电流放电    
Abstract: Graphene/platinum composite electrode (Pt-G/CFB) was prepared by one-step hydrothermal reduction method with three-dimensional carbon fiber brush as matrix. The analysis results showed that a large number of Pt nanoparticles and graphene were uniformly grown and coated on carbon fiber tow, and the grain size of Pt was about 3.1 nm; the composite electrode had large specific surface area and abundant mesoporous structure. Pt-G catalyst exhibited good catalytic performance and stability in oxygen reduction reaction (ORR). Seawater dissolved oxygen battery composed of composite electrode and Al alloy anode was tested for discharge. The battery has good discharge performance under low temperature, deficient oxygen and low current density conditions, and the maximum specific power reaches 197 mW/L.
Key words:  seawater dissolved oxygen battery    modified carbon fiber    graphene-platinum composite catalyst    oxygen reduction reaction    constant current discharge
出版日期:  2024-02-25      发布日期:  2024-03-01
ZTFLH:  TG172  
通讯作者:  *段体岗,博士,高级工程师,2016年哈尔滨工程大学材料科学与工程专业毕业,同年进入中国船舶集团有限公司第七二五研究所工作,主要从事电极材料、电催化、化学电源、腐蚀防护等方面的研究。获得中国腐蚀防护学会科技进步一等奖1项。发表学术论文30余篇,参与编写专著2项,申请国家发明专利10余项。duantigang@sunrui.net   
作者简介:  王金涛,青岛科技大学机电工程学院在读硕士研究生,导师为郭建章教授。在中国船舶集团有限公司第七二五研究所联合培养。主要从事氧还原催化剂及其在海水溶解氧电池中的应用性能的研究。
引用本文:    
王金涛, 段体岗, 郭建章, 马力, 余聚鑫, 张海兵. 三维碳纤维基复合材料及其在海水溶解氧电池中的应用性能[J]. 材料导报, 2024, 38(4): 22040345-6.
WANG Jintao, DUAN Tigang, GUO Jianzhang, MA Li, YU Juxin, ZHANG Haibing. Three-dimensional Carbon Fiber Matrix Composites and Their Application Performance in Seawater Dissolved Oxygen Batteries. Materials Reports, 2024, 38(4): 22040345-6.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.22040345  或          https://www.mater-rep.com/CN/Y2024/V38/I4/22040345
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