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《材料导报》期刊社  2017, Vol. 31 Issue (2): 55-59    https://doi.org/10.11896/j.issn.1005-023X.2017.02.012
  材料研究 |
脉冲激光沉积VN/Ag复合薄膜的组织及摩擦学性能研究*
国洪建1,2,3, 贾均红1, 张振宇3, 梁补女3, 陈文元1,2, 李博1, 汪建义1,2
1 中国科学院兰州化学物理研究所,固体润滑国家重点实验室, 兰州 730000;
2 中国科学院大学, 北京 100049;
3 兰州工业学院机电工程学院, 兰州 730050;
Microstructure and Tribological Properties of VN/Ag Films Fabricated by Pulsed Laser Deposition Technique
GUO Hongjian1,2,3, JIA Junhong1, ZHANG Zhenyu3, LIANG Bunu3, CHEN Wenyuan1,2, LI Bo1, WANG Jianyi1,2
1 State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
2 University of Chinese Academy of Sciences, Beijing 100049;
3 Department of Mechanical Engineering, Lanzhou Institute of Technology, Lanzhou 730050;
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摘要 利用脉冲激光沉积技术制备了不同Ag含量的VN/Ag复合薄膜,利用扫描电子显微镜、X射线衍射仪、纳米力学测试系统等设备表征薄膜的组织结构、成分、表面形貌及力学性能,利用UMT-3摩擦试验机考察薄膜在室温至900 ℃下的摩擦学性能。结果表明,随着Ag含量的增多,薄膜的组织形貌变差,硬度及弹性模量降低。当Ag含量为16%(原子分数)时薄膜在试验温度范围内的摩擦学性能最佳。由于Ag在低温的润滑特性及高温摩擦化学反应生成了新的润滑相,如V2O5、V6O11、V6O13、Ag3VO4、AgVO3等,使得摩擦系数随温度的升高而逐渐降低,在900 ℃下取得最低值0.08,实现了宽温域内的连续润滑。
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国洪建
贾均红
张振宇
梁补女
陈文元
李博
汪建义
关键词:  脉冲激光沉积  VN/Ag薄膜  摩擦学性能  润滑机理    
Abstract: A series of VN/Ag films varied in Ag-concentration were fabricated by pulsed laser deposition (PLD) technique and characterized by scanning electron microscope, X-ray diffraction technique, nanomechanical testing system and UMT-3 wear tester. The results showed that the deteriorating surface morphology and decreased mechanical properties of the films are attributed to the increased Ag content. The VN/Ag films with Ag-concentrations of 16% registered the enhanced tribological property compared to the others over the investigated temperatures, the friction coefficient decreased with the temperature increasing and hold the lowest value of 0.08 at 900℃. Combining with the lubricating Ag at low temperatures and the new lubrication phase generated by tribochemical reaction could be responsible to the excellent tribological performance of the VN/Ag films in a wide temperature range.
Key words:  pulsed laser deposition (PLD)    VN/Ag film    tribological property    lubrication mechanism
出版日期:  2017-01-25      发布日期:  2018-05-02
ZTFLH:  TH117.2  
基金资助: *国家自然科学基金(51471181);甘肃省青年科学基金(1506RJYA058);甘肃省陇原青年创新人才计划
作者简介:  国洪建:男,1984年生,博士,副教授,研究方向为高温润滑薄膜的制备及研究 E-mail:chinaghj2009@licp.cas.cn 贾均红:通讯作者,男,1974年生,博士,研究员,博士研究生导师,研究方向为高温润滑复合材料 E-mail:jhjia@licp.cas.cn
引用本文:    
国洪建, 贾均红, 张振宇, 梁补女, 陈文元, 李博, 汪建义. 脉冲激光沉积VN/Ag复合薄膜的组织及摩擦学性能研究*[J]. 《材料导报》期刊社, 2017, 31(2): 55-59.
GUO Hongjian, JIA Junhong, ZHANG Zhenyu, LIANG Bunu, CHEN Wenyuan, LI Bo, WANG Jianyi. Microstructure and Tribological Properties of VN/Ag Films Fabricated by Pulsed Laser Deposition Technique. Materials Reports, 2017, 31(2): 55-59.
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https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.02.012  或          https://www.mater-rep.com/CN/Y2017/V31/I2/55
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