共价有机框架型锂单离子固态电解质研究进展

doi:10.11896/cldb.25030088

材料导报

2026, Vol. 40

Issue (4): 25030088-10 https://doi.org/10.11896/cldb.25030088

高分子与聚合物基复合材料

共价有机框架型锂单离子固态电解质研究进展

耿亚芸¹, 王英姑^2,*, 米森杰¹, 张重德¹, 郭鹏飞¹, 卢彧¹, 杨志伟¹, 付慧³, 赵付来^3,*, 李震^1,*

1 华东交通大学材料科学与工程学院,南昌 330013
2 南昌理工学院智能建筑工程学院,南昌 330044
3 山东理工大学材料科学与工程学院,山东淄博 255000

Research Progress of COF-based Single-lithium-ion Solid Electrolytes

GENG Yayun¹, WANG Yinggu^2,*, MI Senjie¹, ZHANG Chongde¹, GUO Pengfei¹, LU Yu¹, YANG Zhiwei¹, FU Hui³, ZHAO Fulai^3,*, LI Zhen^1,*

1 School of Materials Science and Engineering, East China Jiaotong University, Nanchang 330013, China
2 School of Intelligent Building Engineering, Nanchang Institute of Technology, Nanchang 330044, China
3 School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, Shandong, China

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摘要锂单离子型固态电解质的锂离子迁移数接近1,可减少阴离子在电极材料上的极化浓差和副反应的发生,在提升电池的循环性能和使用寿命上展现出极大潜力。共价有机框架(COF)具有有序孔道和良好的结构设计性,这使其成为固态电解质领域的研究热点。然而,目前已报道的COF型锂单离子固态电解质材料面临室温下锂离子传导率低、阴离子中心电荷离域程度低、锂离子解离难等挑战,实际应用与推广严重受限。本文综述了近年COF型锂单离子固态电解质的相关研究进展,探讨了阴离子中心的种类对锂离子传导率和锂离子迁移数的影响,归纳并总结了材料结构-性能之间的构效关系,并对COF型锂单离子固态电解质材料的未来发展趋势和挑战应对策略进行分析和展望,以期为高性能固态锂离子电池的发展提供一定参考。

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	耿亚芸
	王英姑
	米森杰
	张重德
	郭鹏飞
	卢彧
	杨志伟
	付慧
	赵付来
	李震

关键词: 共价有机框架锂单离子固态电解质阴离子中心锂离子传导率锂离子迁移数

Abstract: The lithium-ion transference number of single-lithium-ion solid electrolytes is close to unity, which can reduce the polarization concentration of anions on electrodes and the occurrence of side reactions, demonstrating great potential for improving the cycling performance and service life of batteries. Covalent organic framework (COF) possess ordered pore structures and highly designable architectures, making them excellent candidates in the field of solid electrolytes. However, currently reported COF-based single-lithium-ion solid electrolytes face challenges such as low lithium-ion conductivity at room temperature, limited delocalization of anionic center charges, and difficulty in ion dissociation, which have severely restricted their practical application and widespread adoption. This paper reviews recent developments in COF-based single-lithium-ion solid electrolytes and explores the influence of different types of anionic centers on lithium-ion conductivity and lithium-ion transference numbers, with particular emphasis on the relationship between material structures and electrochemical performance. It finally analyzes future development trends and strategies to address challenges in COF-based single-lithium-ion solid electrolytes, aiming to provide useful information and understanding for developing high-performance solid-state lithium-ion batteries.

Key words: covalent organic framework single-lithium-ion solid electrolyte anionic center lithium-ion conductivity lithium-ion transference number

出版日期: 2026-02-25 发布日期: 2026-02-13

ZTFLH:

TB34

基金资助: 国家自然科学基金(52103205;52103093);江西省自然科学基金(20232BAB214031;20242BAB25237);山东省泰山学者项目(tsqn202312187);山东省自然科学基金(ZR2024QE220);中国科协青年人才托举工程项目(2021QNRC001);南昌理工学院校级课题(NLZK-23-08)

通讯作者: * 王英姑,硕士,南昌理工学院建筑工程学院讲师,主要研究有机多孔材料功能应用。wyinggu@163.com
赵付来,博士,山东理工大学材料科学与工程学院教授、博士研究生导师。主要研究纳米复合材料及功能应用。ialufhz@163.com
李震,博士,华东交通大学材料科学与工程学院讲师,主要研究多孔材料及功能应用。zhenli9084@163.com

作者简介: 耿亚芸,华东交通大学材料科学与工程学院硕士研究生,在李震博士的指导下研究功能化COF的设计及其在固态电解质材料中的应用。

引用本文:

耿亚芸, 王英姑, 米森杰, 张重德, 郭鹏飞, 卢彧, 杨志伟, 付慧, 赵付来, 李震. 共价有机框架型锂单离子固态电解质研究进展[J]. 材料导报, 2026, 40(4): 25030088-10.
GENG Yayun, WANG Yinggu, MI Senjie, ZHANG Chongde, GUO Pengfei, LU Yu, YANG Zhiwei, FU Hui, ZHAO Fulai, LI Zhen. Research Progress of COF-based Single-lithium-ion Solid Electrolytes. Materials Reports, 2026, 40(4): 25030088-10.

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https://www.mater-rep.com/CN/10.11896/cldb.25030088 或 https://www.mater-rep.com/CN/Y2026/V40/I4/25030088

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