细菌纤维素膜的制备及在锌碘电池中的应用

doi:10.11896/cldb.24120210

材料导报

2026, Vol. 40

Issue (4): 24120210-5 https://doi.org/10.11896/cldb.24120210

高分子与聚合物基复合材料

细菌纤维素膜的制备及在锌碘电池中的应用

刘增勇¹, 诸葛祥群¹, 李德贵², 刘文君¹, 罗鲲^1,*

1 常州大学材料科学与工程学院,江苏常州 213164
2 百色学院材料科学与工程学院,广西百色 533000

Preparation of Bacterial Cellulose Membrane and Its Application in Zinc-Iodine Batteries

LIU Zengyong¹, ZHUGE Xiangqun¹, LI Degui², LIU Wenjun¹, LUO Kun^1,*

1 School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China
2 School of Materials Science and Engineering, Baise University, Baise 533000, Guangxi, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 18309KB )
输出: BibTeX | EndNote (RIS)

摘要细菌纤维素(BC)膜作为一种天然高分子材料,具有独特的三维纤维网络结构和优异的机械强度。本工作将BC膜作为隔膜应用于锌碘电池,发现BC膜可以有效捕获碘物种,减少I₃^-的穿梭现象。使用BC膜的锌碘电池,其比容量可达177 mAh·g^-1,循环寿命超过1 500次,远优于使用玻璃纤维(GF)隔膜的锌碘电池的性能。该研究为生物质材料应用于电化学储能提供了新思路,具有广阔的应用前景。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	刘增勇
	诸葛祥群
	李德贵
	刘文君
	罗鲲

关键词: 锌碘电池细菌纤维素(BC)膜穿梭效应

Abstract: Bacterial cellulose (BC) membrane, a natural polymer material, possesses a unique three-dimensional fibrous network and excellent mechanical strength. In this study, BC membrane was employed as a separator in zinc-iodine batteries, effectively capturing iodine species and significantly suppressing the shuttling of triiodide ions (I₃^-). The zinc-iodine battery utilizing the BC membrane demonstrated a high specific capacity of 177 mAh·g^-1 and a long lifespan exceeding 1 500 cycles, markedly outperforming the counterpart using a conventional glass fiber (GF) separator. This work offers a promising strategy for the application of biomaterials in electrochemical energy storage systems, highlighting the broad potential of BC membranes in sustainable energy technologies.

Key words: zinc-iodine battery bacterial cellulose (BC) membrane shuttle effect

出版日期: 2026-02-25 发布日期: 2026-02-13

ZTFLH:

TM912

基金资助: 国家自然科学基金 (5247443)

通讯作者: * 罗鲲,博士,常州大学教授、博士研究生导师。主要从事新能源储能材料的研究。luokun@cczu.edu.cn

作者简介: 刘增勇,常州大学材料科学与工程专业硕士研究生,目前研究方向为锌空气电池和锌碘电池及其应用。

引用本文:

刘增勇, 诸葛祥群, 李德贵, 刘文君, 罗鲲. 细菌纤维素膜的制备及在锌碘电池中的应用[J]. 材料导报, 2026, 40(4): 24120210-5.
LIU Zengyong, ZHUGE Xiangqun, LI Degui, LIU Wenjun, LUO Kun. Preparation of Bacterial Cellulose Membrane and Its Application in Zinc-Iodine Batteries. Materials Reports, 2026, 40(4): 24120210-5.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24120210 或 https://www.mater-rep.com/CN/Y2026/V40/I4/24120210

1 He J, Mu Y, Wu B, et al. Energy & Environmental Science, 2024, 17(1), 323.
2 Yang J L, Xiao T, Xiao T, et al. Advanced Materials, 2024, 36(21), 2313610.
3 Hou Y, Kong F, Wang Z, et al. Journal of Colloid and Interface Science, 2023, 629, 279.
4 Mousavi M, Jiang G, Zhang J, et al. Energy Storage Materials, 2020, 32, 465.
5 Yan L, Liu T, Zeng X, et al. Carbon, 2022, 187, 145.
6 He J, Hong H, Hu S, et al. Nano Energy, 2024, 119, 109096.
7 Liu M, Chen Q, Cao X, et al. Journal of the American Chemical Society, 2022, 144(47), 21683.
8 Chen Q, Chen S, Ma J, et al. Nano Energy, 2023, 117, 108897.
9 Cui M, Zhao H, Yin D, et al. Energy Storage Materials, 2024, 69, 103372.
10 Zhang Y, Zhang Y Y, Li C E, et al. Coordination Chemistry Reviews, 2024, 519, 216103.
11 Zhang Y, Zhou C G, Yan X H, et al. Journal of Power Sources, 2023, 565, 232916.
12 Zhang Y, Hu S, Li C E, et al. Coordination Chemistry Reviews, 2025, 531, 216497.
13 Zhang Y, Jing X, Yan X H, et al. Coordination Chemistry Reviews, 2024, 499, 215494.
14 Zhang Y, Xue S C, Yan X H, et al. Electrochimica Acta, 2023, 442, 141822.
15 Yang P, Zhang K, Liu S, et al. Advanced Functional Materials, 2024, 34(52), 2410712.
16 Yang H, Qiao Y, Chang Z, et al. Advanced Materials, 2020, 32(38), 2004240.
17 Yang T Y, Su T T, Wang H L, et al. Journal of Energy Chemistry, 2025, 102, 454.
18 Lin P, Chen G, Kang Y, et al. ACS Nano, 2023, 17(16), 15492.
19 Takayama G, Kondo T. Carbohydrate Polymers, 2023, 321, 121311.
20 Zhang Z, Li Y, Cui X, et al. Advanced Materials Interfaces, 2023, 10(1), 2201730.
21 Cheng C, Yang R, Wang Y, et al. Carbohydrate Polymers, 2023, 304, 120489.
22 Xu Q, Wei C, Fan L, et al. Cellulose, 2017, 24(4), 1889.
23 Huang C, Ji H, Yang Y, et al. Carbohydrate Polymers, 2020, 230, 115570.
24 Rosa M F, Medeiros E S, Malmonge J A, et al. Carbohydrate Polymers, 2010, 81(1), 83.
25 Pan R, Wang Z, Sun R, et al. Cellulose, 2017, 24(7), 2903.
26 Yang P, Zhang K, Liu S, et al. Advanced Functional Materials, 2024, 2410712.
27 Xu H, Zhang R, Luo D, et al. ACS Nano, 2023, 17(24), 25291.
28 Xu P, Zhu J, Chen C, et al. ChemElectroChem, 2019, 6(15), 3885.

[1]	徐婉琳, 冯腾锐, 吴琪, 夏杰桢, 曹蓉. 二维碳基材料在锂硫电池中的研究进展[J]. 材料导报, 2025, 39(7): 23100229-10.
[2]	姜宇, 杨蓉, 张乾伟, 樊潮江, 董鑫, 蒋百铃, 燕映霖. 功能化MXene在锂硫电池中应用研究进展[J]. 材料导报, 2024, 38(12): 22100251-9.
[3]	宋丽红, 张敏刚, 曹翔宇, 郭锦, 闫晓燕. S-N掺杂聚乙二醇用于锂硫电池的第一性原理研究[J]. 材料导报, 2023, 37(3): 21030173-5.
[4]	赵文文, 王韵芳, 段东红, 刘世斌, 周娴娴, 陈良. 金属有机骨架衍生的层状Co₃O₄/C在锂硫电池中的应用[J]. 材料导报, 2022, 36(6): 20120257-7.
[5]	冯阳, 汪港, 陈君妍, 康卫民, 邓南平, 程博闻. 高性能锂硫电池研究进展与改进策略[J]. 材料导报, 2022, 36(11): 20080027-14.
[6]	李锐, 孙晓刚, 黄雅盼, 魏成成, 梁国东, 邹婧怡, 徐宇浩, 何强. 三维多孔碳纳米片PC/CNT夹层高性能锂硫电池[J]. 材料导报, 2020, 34(16): 16006-16010.
[7]	张腾, 唐天宇, 侯仰龙. 面向锂硫电池的高负载量碳硫复合正极材料研究进展[J]. 材料导报, 2019, 33(1): 90-102.
[8]	王杰, 孙晓刚, 陈珑, 邱治文, 蔡满园, 李旭, 陈玮. 利用二硫苏糖醇夹层抑制锂硫电池的穿梭效应[J]. 《材料导报》期刊社, 2018, 32(7): 1079-1083.

[1]	LI Chaolei. Study on Radial Pores Structure of Microporous Layer with High Mass Transportation in Proton Exchange Membrane Fuel Cells[J]. Materials Reports, 2026, 40(1): 25010096 -5 .
[2]	ZHAO Jiazheng. Metallic Heterostructured Materials: Classification,Toughening Mechanisms,and Development Trends[J]. Materials Reports, 2026, 40(1): 25020015 -16 .
[3]	ZHANG Xiaohang. Research Progress on Brazing Methods of Silicon Nitride Ceramics and Metals[J]. Materials Reports, 2026, 40(1): 25010049 -12 .
[4]	XU Chaoliang. Review of the Effect of Irradiation-Assisted Stress Corrosion Cracking on Stainless Steel in Light Water Reactor Environments[J]. Materials Reports, 2026, 40(1): 25010139 -11 .
[5]	FENG Kaibin, LIU Runcong, LI Silong, WU Yunfei, NA Xianzhao, WANG Xiaodong. Detection of the Oscillation Marks on Casting Slabs Using Magnetic Flux Variation and the Nonexcitation Method[J]. Materials Reports, 2026, 40(1): 25010165 -10 .
[6]	LI Bin. Research Progress of Abrasive Flow Machining in the Processing of Complex Microporous Structures Materials for Aeronautic Applications[J]. Materials Reports, 2026, 40(1): 25020122 -12 .
[7]	WAN Yuhui. Study on Room Temperature Deformation Behavior of Magnesium-Bismuth Binary Alloy[J]. Materials Reports, 2026, 40(1): 25010137 -6 .
[8]	YI Shifeng, CHEN Xiaomin. Prediction of High-temperature Tensile Fracture Behavior of GH4169 Alloy Based on the Oyane-Sato Criterion[J]. Materials Reports, 2026, 40(1): 25010099 -7 .
[9]	YIN Ziluo. Dielectric and Mechanical Properties of Polypropylene Fiber-reinforced Cross-linked Polystyrene[J]. Materials Reports, 2026, 40(1): 25010020 -6 .
[10]	HOU Kexin. Research Progress on the Preparation Strategies and Applications of Electrospun Nanofiber-based Hydrogel Wound Dressings[J]. Materials Reports, 2026, 40(1): 25010089 -9 .

Viewed

Full text

Abstract

Cited

Shared

Discussed