Abstract: The front surface (FS) specimen and side surface (SS) specimen of CF8611/AC531 composite and the polarization test of them in the electrolyte with 3.5% NaCl+12.5% Cu2SO4 were designed. By means of the electrochemical workstation, scanning electron microscope, energy spectrometer and other devices, the potentiodynamic polarization curves and galvanic corrosion parameters of the composite and 7B04-T74 aluminum alloy in different electrolytes were measured, meanwhile the microstructure and component were observed and analyzed. Based on the steady corrosion field and the parametric scanning technology, a dynamic model for galvanic corrosion under the wear status of composite was established by Comsol software. The results show that, the perfor-mance of the composite is stable, but there are some carbon fiber exposed defects on the original surface. The cathodic reaction rate is closely related to the area of exposed carbon fiber, and the surface of the composite is divided into the active cathode region and inert cathode region. The main corrosion form of the aluminum alloy is pitting when coupled with composite, and no failure of composite. The galvanic corrosion model established here is valid and available. There is a positive linear correlation between the total galvanic current and the exposed area of carbon fiber, the formula is Ig=(2.794 1S+62.994)×10-7. When the area ratio of FS to SS is about 5.53∶1, the galvanic effect of them to the aluminum alloy is the same. Three reasons which will reduce the failure risk of the composite in galvanic corrosion are gave out.
1 Chen Y L, Wang D D, Zhang Y, et al. Research for galvanic corrosion between T700 CFRP and 2A12 aluminum alloy[J]. Equipment Environmental Engineering,2014,15(6):40(in Chinese). 陈跃良,王冬冬,张勇,等.T700碳纤维环氧树脂复合材料与2A12铝合金电偶腐蚀研究[J].装备环境工程,2014,15(6):40. 2 Lu F. Effect of composites on the contacting corrosion of aluminum alloy[J]. Surface Technology,1992,12(3):139. 3 Alias M N, Brown R. Corrosion behavior of carbon fiber composites in the marine environment[J]. Corrosion Science,1993,35(4):395. 4 Ireland R, Arronche L, La Saponara V. Electrochemical investigation of galvanic corrosion between aluminum 7075 and glass fiber/epoxy composites modified with carbon nanotubes[J]. Composites Part B: Engineering,2012,43(2):183. 5 Ireland R, Arronche L, La Saponara V. Electrochemical investigation of galvanic corrosion between aluminum 7075 and multiscale glass fiber/epoxy composites[J]. Composites Part B: Engineering,2012,56(5):171. 6 Pan J Q, Li P Y. Experimental study on galvanic corrosion of aluminum alloy and carbon/epoxy composite[J]. Aerospace Materials Technology,1993,12(5):19. 7 Gao M T, Xu C G, Du Z Y, et al. Contact corrosion between carbon fiber reinforce composite and high-strength materials[J]. Acta Aeronautica et Astronautica Sinica,1993,14(12):662. 8 Hu Y L, Li D. Galvanic corrosion behavior between graphite/epoxy composite material (GECM) and metal[J]. Corrosion Science and Protection Technology,1998,16(2):93(in Chinese). 胡艳玲,李荻.碳纤维/环氧树脂复合材料与金属的电偶腐蚀行为[J].腐蚀科学与防护技术,1998,16(2):93. 9 Fovet Y, Pourreyron L, Gal J Y. Corrosion by galvanic coupling between carbon fiber posts and different alloys[J]. Dental Materials,2000,16(5):364. 10 Chen L, Wu X H, Jiang Z H. Galvanic corrosion behavior of antirust aluminum and carbon fiber composite[J]. Corrosion & Protection,2008,29(2):59(in Chinese). 陈龙,吴晓宏,姜兆华.防锈铝与碳纤维复合材料电偶腐蚀行为[J].腐蚀与防护,2008,29(2):59. 11 Ma Z Y, Xie F Q. Corrosion behavior of aluminum alloy and composite T700 in artificial seawater[J]. Materials Protection,2009,42(3):27(in Chinese). 马宗耀,谢发勤.人工海水中铝合金与复合材料T700电偶的腐蚀性能[J].材料保护,2009,42(3):27. 12 Su P B, Wu X H, Jiang Z H, et al. Galvanic corrosion of carbon fiber composite and LY12 aluminum alloy[J]. Corrosion & Protection,2014,35(1):37(in Chinese). 苏培博,吴晓宏,姜兆华,等.碳纤维复合材料与LY12铝合金的电偶腐蚀[J].腐蚀与防护,2014,35(1):37. 13 Lu F, Zhong Q P, Cao C X. Galvanic corrosion and controlling of GECM and metals in atmospheric environment[J]. Materials Protection,2002,35(12):19(in Chinese). 陆峰,钟群鹏,曹春晓.大气环境条件下复合材料与金属电偶腐蚀及控制方法研究[J].材料保护,2002,35(12):19. 14 Lu F, Zhang X Y, Tang Z H, et al. Galvanic corrosion behavior between carbon fiber reinforced plastic materials and aluminum alloys[J]. Journal of Chinese Society for Corrosion and Protection,2005,25(1):39. 15 Srinivasan R, Nelson J A, Hihara L H. Development of guidelines to attenuate galvanic corrosion between mechanically-coupled aluminum and carbon-fiber reinforced epoxy composites using insulation layers[J]. Journal of the Electrochemical Society,2015,162(10):545. 16 Srinivasan R, Hihara L H. Utilization of hydrophobic coatings on insulative skirts to attenuate galvanic corrosion between mechanically-fastened aluminum alloy and carbon-fiber reinforced polymer-matrix composites[J]. Electrochemistry Communications,2016,72(12):96. 17 Chen L. The research of galvanic corrosion rule and protection between carbon fiber composite material and metal[D]. Harbin: Harbin Institute of Technology,2007(in Chinese). 陈龙.碳纤维复合材料与金属电偶腐蚀规律及防护研究[D].哈尔滨:哈尔滨工业大学,2007. 18 Lu F, Zhong Q P, Cao C X. Progress of galvanic corrosion between the graphite epoxy composite materials and metals[J]. Material Engineering,2003,21(4):39(in Chinese). 陆峰,钟群鹏,曹春晓.碳纤维环氧复合材料与金属电偶腐蚀的研究进展[J].材料工程,2003,21(4):39. 19 Hihara L H, Latanision R M. Suppressing galvanic corrosion in graphite/aluminum metal-matrix composites[J]. Corrosion Science,1993,34(4):655. 20 Hihara L H, Latanision R M. Galvanic corrosion of aluminum-matrix composites[J]. Corrosion-Houston Tx-,1992,48(7):33. 21 Chen S J. Large aircraft and composites[J]. Aeronautical Manufacturing Technology,2008,22(15):32(in Chinese). 陈绍杰.大型飞机与复合材料[J].航空制造技术,2008,22(15):32. 22 Li Z H, Xiong B Q, Zhang Y A, et al. Microstructural evolution of aluminum alloy 7B04 thick plate by various thermal treatments[J]. Chinese Journal of Nonferrous Metals,2008,18(1):40. 23 Chen Y L, Wang Z F, Bian G X, et al. Study on equivalent conversion of galvanic corrosion between dissimilar metals of airplane in NaCl solution with different concentrations[J]. Acta Aeronautica et Astronautica Sinica,2017,38(3):260(in Chinese). 陈跃良,王哲夫,卞贵学,等.不同浓度NaCl溶液下典型铝/钛合金电偶腐蚀当量折算关系[J].航空学报,2017,38(3):260. 24 Yin L, Jin Y, Leygraf C, et al. Numerical simulation of micro-galvanic corrosion in al alloys: Effect of geometric factors[J]. Journal of the Electrochemical Society,2017,164(2):75. 25 Jia J X, Atrens A, Song G, et al. Simulation of galvanic corrosion of magnesium coupled to a steel fastener in NaCl solution[J]. Materials and Corrosion,2005,56(7):468. 26 Jia J X, Song G, Atrens A. Influence of geometry on galvanic corrosion of AZ91D coupled to steel[J]. Corrosion Science,2006,48(8):2133. 27 Mandel M, Krüger L. Determination of pitting sensitivity of the aluminium alloy EN AW-6060-T6 in a carbon-fiber reinforced plastic/aluminium rivet joint by finite element simulation of the galvanic corrosion process[J]. Corrosion Science,2013,73:172. 28 Wang C G, Chen Y L, Zhang Y, et al. Simulation study on filiform corrosion of aircraft aluminum alloy/coating system[J]. Material Development and Application,2017,31(1):80(in Chinese). 王晨光,陈跃良,张勇,等.飞机铝合金/涂层体系丝状腐蚀的仿真研究[J].材料开发与应用,2017,31(1):80. 29 Udonatus D, Gethompson E T, Jaomotoyinbo A O, et al. Corrosion pathways in aluminium alloys[J]. Transactions of Nonferrous Me-tals Society of China,2017,27(1):55. 30 Ma Y, Li L B, Gao G X, et al. Effect of montmorillonite on the io-nic conductivity and electrochemical properties of a composite solid polymer electrolyte based on polyvinylidenedifluoride/polyvinyl alcohol matrix for lithium ion batteries[J]. Electrochimica Acta,2016,187(4):535. 31 Tavakkolizadeh M, Saadatmanesh H. Galvanic corrosion of carbon and steel in aggressive environments[J]. Journal of Composites for Construction,2001,5(3):200. 32 Yang S H B, Babu P, Chua S F S, et al. Carbon dioxide hydrate kinetics in porous media with and without salts[J]. Applied Energy,2016,162(5):1131. 33 Mueller Y, Tognini R, Mayer J, et al. Anodized titanium and stainless steel in contact with CFRP: An electrochemical approach consi-dering galvanic corrosion[J]. Journal of Biomedical Materials Research Part A,2007,82(4):936. 34 Bala H, Dymek M. Determination of corrosion rate of porous, liquid permeable materials on the example of hydride powder composite[J]. Ochrona przed Korozja,2017,6(4):79. 35 Hihara L H, Panquites I V P. Method of electrochemical machining (ECM) of particulate metal-matrix composites (MMcs): US,110,351[P]. 2000-08-29.