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材料导报  2026, Vol. 40 Issue (9): 25040063-7    https://doi.org/10.11896/cldb.25040063
  高分子与聚合物基复合材料 |
碳纤维化学接枝MXene:碳纤维/环氧树脂复合材料的界面强化与力学性能提升
杨至高, 谢小林*, 江洪流, 叶亮亮, 许旺达
南昌航空大学材料科学与工程学院,南昌 330063
Chemical Grafting of MXene onto Carbon Fiber: Interfacial Reinforcement andMechanical Performance Enhancement of Carbon Fiber/Epoxy Composites
YANG Zhigao, XIE Xiaolin*, JIANG Hongliu, YE Liangliang, XU Wangda
School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China
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摘要 本工作通过制备新型二维纳米材料MXene以及将不同浓度的MXene接枝在碳纤维(CF)表面,有效提高了CF复合材料界面强度,增强了CF/环氧树脂(CF/EP)复合材料的力学性能。表征分析了MXene接枝CF的表面化学状态和形貌,对CF/EP复合材料进行了弯曲强度测试和层间剪切强度测试。实验结果表明,CF化学接枝MXene有效提高了CF表面粗糙度和化学活性,得益于纤维-基体界面机械互锁和化学结合的协同效应,使用经不同浓度MXene溶液处理的CF制备的复合材料力学性能均有不同程度的提升。其中,用1.0 mg/mL MXene溶液处理CF时所得CF/EP复合材料性能最好,弯曲强度达568.13 MPa,层间剪切强度达55.58 MPa,较未改性CF/EP复合材料分别提升了26.04%和38.6%。
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杨至高
谢小林
江洪流
叶亮亮
许旺达
关键词:  碳纤维  MXene  化学接枝  复合材料  界面强度  力学性能    
Abstract: The interfacial reinforcement of carbon fiber/epoxy (CF/EP) composites through surface grafting of MXene, a novel two-dimensional nanomaterial, were investigated in this study. By immobilizing MXene at varying concentrations onto CF surfaces, the interfacial strength of composites was significantly enhanced, leading to improved mechanical performance of the composites. The surface chemical states and morphology of MXene-grafted CFs were systematically characterized, and the flexural strength and interlaminar shear strength (ILSS) of the composites were tested. Results demonstrated that the surface roughness and chemical reactivity of CFs were effectively increased because of MXene grafting. The mechanical properties of the CF/EP composites in which the CFs were treated by MXene solutions with different concentrations were improved in varying degrees, owing to the synergistic effects of mechanical interlocking and chemical bonding at the fiber-matrix interface. Among all samples, the CF/EP composite treated with 1.0 mg/mL MXene solution exhibited the optimal performance, with a bending strength of 568.13 MPa and ILSS of 55.58 MPa, representing increases of 26.04% and 38.6%, respectively, compared to the unmodified CF/EP composite.
Key words:  carbon fiber    MXene    chemical grafting    composites    interfacial strength    mechanical property
收稿日期:  2026-05-10      出版日期:  2026-05-10      发布日期:  2026-05-18
ZTFLH:  TB332  
基金资助: 江西省重点研发计划(20224BBE51049)
通讯作者:  *谢小林,博士,南昌航空大学材料学院副教授、硕士研究生导师,主要研究聚合物基复合材料性能及成型工艺。xxl0810@nchu.edu.cn   
作者简介:  杨至高,南昌航空大学材料科学与工程学院硕士研究生,在谢小林副教授的指导下研究碳纤维及树脂基复合材料。
引用本文:    
杨至高, 谢小林, 江洪流, 叶亮亮, 许旺达. 碳纤维化学接枝MXene:碳纤维/环氧树脂复合材料的界面强化与力学性能提升[J]. 材料导报, 2026, 40(9): 25040063-7.
YANG Zhigao, XIE Xiaolin, JIANG Hongliu, YE Liangliang, XU Wangda. Chemical Grafting of MXene onto Carbon Fiber: Interfacial Reinforcement andMechanical Performance Enhancement of Carbon Fiber/Epoxy Composites. Materials Reports, 2026, 40(9): 25040063-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25040063  或          https://www.mater-rep.com/CN/Y2026/V40/I9/25040063
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