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材料导报  2026, Vol. 40 Issue (7): 24120160-6    https://doi.org/10.11896/cldb.24120160
  高分子与聚合物基复合材料 |
羧甲基纤维素钠改性的BF/EPDM复合材料的性能研究
张泽明1,2,3, 黄存盛1,2,3, 党东营1,2,3, 张德伟1,2,3,*, 汪传生1,2,3
1 青岛科技大学机电工程学院,山东 青岛 266061
2 山东省高分子材料先进制造技术重点实验室,山东 青岛 266061
3 轮胎先进装备与关键材料国家工程研究中心,山东 青岛 266061
Study on the Properties of BF/EPDM Composites Modified with Sodium Carboxymethyl Cellulose
ZHANG Zeming1,2,3, HUANG Cunsheng1,2,3, DANG Dongying1,2,3, ZHANG Dewei1,2,3,*, WANG Chuansheng1,2,3
1 College of Electrical and Mechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong, China
2 Shandong Key Laboratory of Advanced Manufacturing Technology for Polymer Materials, Qingdao 266061, Shandong, China
3 National Engineering Research Center for Advanced Equipment and Key Materials for Tires, Qingdao 266061, Shandong, China
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摘要 通过羧甲基纤维素钠(CMC)溶液对玄武岩纤维(BF)进行表面改性处理,探究不同浓度CMC溶液处理后的BF及BF取向对三元乙丙橡胶(EPDM)/BF复合材料性能的影响。结果表明:随着CMC溶液浓度的增大,BF/EPDM复合材料的断裂伸长率、抗撕裂强度及拉伸强度均先增大后减小,而复合材料的储能模量与损耗因子(tanδ)峰值先下降后上升,当CMC溶液浓度为0.5%(质量分数,余同)时,复合材料综合性能达到最佳,与未经CMC处理的复合材料相比抗撕裂强度提高2.7%,拉伸强度提高10.9%,DIN磨耗量降低4.8%;当CMC溶液浓度为0.5%时,三种取向中BF径向取向后复合材料的储能模量最低,与BF轴向取向相比拉伸强度提高4.8%,抗撕裂强度提高4.2%,DIN磨耗降低3.8%;SEM测试表明0.5%浓度CMC溶液处理后的BF完全被CMC包覆。
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张泽明
黄存盛
党东营
张德伟
汪传生
关键词:  玄武岩纤维  羧甲基纤维素钠  纤维取向  三元乙丙橡胶  复合材料    
Abstract: The surface modification of basalt fiber (BF) using a sodium carboxymethyl cellulose (CMC) solution was investigated, focusing on the impact of different CMC solution concentrations and BF orientation on the performance of BF/ethylene propylene diene monomer (EPDM) composites. The results demonstrated that as the CMC solution concentration increased, the elongation at break, tear strength, and tensile strength of the BF/EPDM composites initially increased and then decreased. The energy storage modulus and loss factor (tanδ) of the compo-sites first decreased and then increased. Notably, when the CMC solution concentration reached 0.5wt%, the composite material exhibited optimal overall performance. Compared to the blank specimen, its tear strength, tensile strength, and DIN abrasion resistance increased by 2.7%, 10.9%, and 4.8%, respectively. Furthermore, when a CMC solution concentration of 0.5% (mass fraction), the energy storage modulus of the composite material after BF radial orientation is the lowest amongst the three types of orientation, while its tensile strength, tear strength, and DIN abrasion resistance were improved by 4.8%, 4.2%, and 3.8%, respectively, compared with the mixed orientation. SEM analysis revealed that the BF treated with 0.5wt% CMC solution was uniformly and completely coated with CMC.
Key words:  basalt fiber    sodium carboxymethyl cellulose    fiber orientation    EPDM rubber    composites
发布日期:  2026-04-16
ZTFLH:  TQ336  
基金资助: 国家自然科学基金(50775116);山东省重点研发计划(2019JMRH00205);山东省自然科学基金(ZR2016XJ003);山东省自主创新及成果转化专项(2014CGZH0405)
通讯作者:  *张德伟,博士,青岛科技大学机电工程学院副教授、硕士研究生导师。目前主要从事高分子材料先进制造技术等方面的研究。zhangdewei1421@163.com   
作者简介:  张泽明,青岛科技大学机电工程学院硕士研究生,在张德伟副教授的指导下研究橡胶高分子材料先进制造技术。
引用本文:    
张泽明, 黄存盛, 党东营, 张德伟, 汪传生. 羧甲基纤维素钠改性的BF/EPDM复合材料的性能研究[J]. 材料导报, 2026, 40(7): 24120160-6.
ZHANG Zeming, HUANG Cunsheng, DANG Dongying, ZHANG Dewei, WANG Chuansheng. Study on the Properties of BF/EPDM Composites Modified with Sodium Carboxymethyl Cellulose. Materials Reports, 2026, 40(7): 24120160-6.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24120160  或          https://www.mater-rep.com/CN/Y2026/V40/I7/24120160
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