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材料导报  2026, Vol. 40 Issue (7): 25010110-7    https://doi.org/10.11896/cldb.25010110
  无机非金属及其复合材料 |
粉煤灰与矿渣改性油井水泥体系抗高温衰退性能及机理
庞学玉1,2, 程国东2, 黄贤斌1,2, 白英睿1,2, 高志2, 郝伯荣2, 吕开河1,2, 孙金声1,2,*
1 深层油气全国重点实验室(中国石油大学(华东)),山东 青岛 266580
2 中国石油大学(华东)石油工程学院,山东 青岛 266580
The Performance and Mechanisms of High-temperature Retrogression Resistance in Fly Ash and Slag-Modified Well Cementing Systems
PANG Xueyu1,2, CHENG Guodong2, HUANG Xianbin1,2, BAI Yingrui1,2, GAO Zhi2, HAO Borong2, LYU Kaihe1,2, SUN Jinsheng1,2,*
1 State Key Laboratory of Deep Oil and Gas, China University of Petroleum (East China), Qingdao 266580, Shandong, China
2 School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, Shandong, China
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摘要 传统加砂油井水泥体系在超深井超高温工况下长期服役过程中通常会产生严重的强度衰退,因此,亟需开发新型抗高温防衰退油井水泥体系以支持超深井井筒环空的长效封隔。本工作对传统加砂油井水泥体系,粉煤灰改性体系,以及矿渣改性体系的抗高温性能进行了综合对比。研究表明,在长期(≥30 d)养护过程中,相对于传统硅砂油井水泥体系和矿渣改性体系,粉煤灰改性体系在宏观物理力学性能、微观结构及水泥石成分稳定性等方面均表现最优。当调整硅砂和粉煤灰加量使得体系钙硅比(CaO/SiO2摩尔比)接近0.83时,粉煤灰掺量变化对水泥石抗衰退性能的影响不大。
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庞学玉
程国东
黄贤斌
白英睿
高志
郝伯荣
吕开河
孙金声
关键词:  粉煤灰  矿渣  加砂油井水泥  高温高压  长期强度衰退    
Abstract: Traditional silica-enriched oil well cement systems often experience severe strength retrogression during long-term service under ultra-high temperature conditions in ultra-deep wells. There is thus an urgent need to develop novel high-temperature-resistant cement systems with enhanced strength-retrogression resistance to ensure long-term zonal isolation in wellbore annuli. This work presents a comprehensive comparative analysis of high-temperature performance among three cement systems: traditional silica-enriched cement, fly ash-modified cement, and slag-modified cement. The results demonstrate that during extended curing periods (≥30 days), the fly ash-modified system exhibits superior performance in terms of macroscopic physico-mechanical properties as well as microstructural and compositional stability, compared to both conventional silica-enriched and slag-modified systems. Furthermore, when the CaO/SiO2 molar ratio is adjusted to approximately 0.83 by optimizing the contents of silica sand and fly ash, variations in fly ash dosage show negligible effects on the strength-retrogression resistance of the cement matrix.
Key words:  fly ash    granulated blast furnace slag    silica-enriched oil well cement    high temperature and high pressure    long-term strength retrogression
发布日期:  2026-04-16
ZTFLH:  N34  
基金资助: 国家自然科学基金基础科学中心项目“超深特深层油气钻采流动调控”(52288101);中央高校基本科研业务费专项资金(23CX05001A)
通讯作者:  *孙金声,博士,中国工程院院士,主要从事钻完井工作液、储层保护、防漏堵漏理论与技术等方面的研究。sunjsdri@cnpc.com.cn   
作者简介:  庞学玉,博士,中国石油大学(华东)石油工程学院教授,主要从事固井水泥材料科学与应用、井筒水泥环封隔完整性领域研究工作。
引用本文:    
庞学玉, 程国东, 黄贤斌, 白英睿, 高志, 郝伯荣, 吕开河, 孙金声. 粉煤灰与矿渣改性油井水泥体系抗高温衰退性能及机理[J]. 材料导报, 2026, 40(7): 25010110-7.
PANG Xueyu, CHENG Guodong, HUANG Xianbin, BAI Yingrui, GAO Zhi, HAO Borong, LYU Kaihe, SUN Jinsheng. The Performance and Mechanisms of High-temperature Retrogression Resistance in Fly Ash and Slag-Modified Well Cementing Systems. Materials Reports, 2026, 40(7): 25010110-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25010110  或          https://www.mater-rep.com/CN/Y2026/V40/I7/25010110
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