| REVIEW PAPER |
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| Progress of the Mechanism of Sulfate Attack on Cement-based Materials |
| ZHANG Xiaojia, ZHANG Gaozhan, SUN Daosheng, LIU Kaiwei
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| Advanced Building Materials Key Laboratory of Anhui Province, Anhui Jianzhu University, Hefei 230022 |
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Abstract Sulfate attack is an important factor that affects the durability of cement-based materials. The effects of sulfate hydrate on the aluminum phase hydration products and C-S-H gel of cement-based material are analyzed, and the mechanism of sulfate attack on cement-based materials are summarized in this paper. Finally the deficiencies and future prospect on the study of microstructure of cement-based materials under sulfate attack are discussed.
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Published: 11 May 2018
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1 Li Hua. Testing and analysis on microstructure evolution of cement-based materials under sulfate attack[D].Nanjing:Southeast University,2012(in Chinese).
李华.硫酸盐侵蚀下水泥基材料微结构演变的测试与分析研究[D].南京:东南大学,2012.
2 Li H, Sun W, Zuo X B. Effect of mineral admixtures on sulfate attack resistance of cement-based materials[J].Journal of the Chinese Ceramic Society,2012,40(8):1119(in Chinese).
李华,孙伟,左晓宝.矿物掺合料改善水泥基材料抗硫酸盐侵蚀性能的微观分析[J].硅酸盐学报,2012,40(8):1119.
3 Mehta P K, Wang S. Expansion of ettringite by water adsorption[J].Cement & Concrete Research,1982,12(1):121.
4 Skalny J, Marchand J, Odler I. Sulfate attack on concrete[M].London:Spon Press,2002.
5 Yu C, Sun W, Scrivener K. Mechanism of expansion of mortars immersed in sodium sulfate solutions[J].Cement & Concrete Research,2013,43:105.
6 Müllauer W, Beddoe R E, Heinz D. Sulfate attack expansion mechanisms[J].Cement & Concrete Research,2013,52:208.
7 Whittaker M, Zajac M, Haha M B, et al. The role of the alumina content of slag, plus the presence of additional sulfate on the hydration and microstructure of Portland cement-slag blends[J].Cement & Concrete Research,2014,66(12):91.
8 Lee S T, Moon H Y, Swamy R N. Sulfate attack and role of silica fume in resisting strength loss[J].Cement & Concrete Composites,2005,27(1):65.
9 Hekal E E, Kishar E, Mostafa H. Magnesium sulfate attack on hardened blended cement pastes under different circumstances[J].Cement & Concrete Research,2002,32(9):1421.
10Liu K W, Deng M, Mo L W, et al. Deterioration mechanism of Portland cement paste subjected to sodium sulfate attack[J].Advances in Cement Research,2015,27(8):477.
11丁庆军,弓子成,朱玉雪,等.温度对高掺量矿渣的水泥浆体抗硫酸盐侵蚀性能的影响[C]∥混凝土与水泥制品学术讨论会.北京,2013:314.
12Zhang Gaozhan. The Microstructure formation and evolution mechanism of C-S-H gel in portland cement pastes with granulated blast furnace slag under the attack of corrosive ions[D].Wuhan:Wuhan University of Technology,2016(in Chinese).
张高展.侵蚀性离子作用下矿渣-水泥复合浆体C-S-H微结构形成与演变机理[D].武汉:武汉理工大学,2016.
13 Hu Chenguang. Effect of temperature and sulfate attack on microstructure of C-S-H in portland cement pastes with fly ash[D].Wuhan:Wuhan University of Technology,2014(in Chinese).
胡晨光.温度和硫酸盐侵蚀对粉煤灰水泥浆体C-S-H微结构的影响研究[D].武汉:武汉理工大学,2014.
14 袁润章.胶凝材料学[M].武汉:武汉理工大学出版社,1996.
15 Zhang L, Yang D Y. Progress of sulfate attack process of concrete and its main products[J].China Concrere and Cement Products,2006(6):19(in Chinese).
张磊,杨鼎宜.混凝土硫酸盐侵蚀过程及主要产物研究进展[J].混凝土与水泥制品,2006(6):19.
16 Ding Q J, He Z. Advances in research on the formation mechanism of cementitious paste microstructure in current concrete[J].Materials China,2009,28(11):8(in Chinese).
丁庆军,何真.现代混凝土胶凝浆体微结构形成机理研究进展[J].中国材料进展,2009,28(11):8.
17 Gollop R S, Taylor H F W. Microstructural and microanalytical studies of sulfate attack. Ⅰ. Ordinary portland cement paste[J].Cement & Concrete Research,1992,22(6):1027.
18 Kunther W, Lothenbach B, Skibsted J. Influence of the Ca/Si ratio of the C-S-H phase on the interaction with sulfate ions and its impact on the ettringite crystallization pressure[J].Cement & Concrete Research,2015,69(1):37.
19 Feng X X, Li X J, Wei Q M. Investigation of sulphate attack on C-S-H gel[J].China Concrete and Cement Products,2007(3):1(in Chinese).
封孝信,李秀娟,魏庆敏.硫酸盐对C-S-H凝胶的侵蚀探讨[J].混凝土与水泥制品,2007(3):1.
20Li X J. Study on the mechanism of magnesium sulfate to cement and C-S-H gel[J].Advanced Materials Research,2011,243-249:4687.
21Ding Q J, Wang H, Hu C G, et al. Effect of corrosive solutions on C-S-H microstructure in portland cement paste with fly ash[J].Journal of Wuhan University of Technology(Materials Science),2016,31(5):1002.
22Ding Q J, Zhang G Z, Hu C G. Effect of sulfate attack on C-S-H microstructure in hardened portland cement pastes[C]∥The 14th International Congress on the Chemistry of Cement.Beijing,2015.
23 Li Y, Wang P, Guan Z Z, et al. Micro-mechanical properties of individual phases in cement pastes under brine solution using nanoindentation and scaning electron microscopy[J].Journal of Nano Research,2017,46:31.
24 Jackson M D, Moon J, Gotti E, et al. Material and elastic properties of Al-Tobermorite in ancient roman seawater concrete[J].Journal of the American Ceramic Society,2013,96(8):2598.
25 Jackson M D, Chae S R, Mulcahy S R, et al. Unlocking the secrets of Al-tobermorite in roman seawater concrete[J].American Minera-logist,2013,98(10):1669.
26 Chen D, Yu X T, Yu Y D, et al. Progress of study on sulfate attack on concrete materials[J].Journal of Chongqing Jiaotong University(Natural Science),2016,35(2):24(in Chinese).
陈达,俞小彤,廖迎娣,等.混凝土硫酸盐侵蚀研究进展[J].重庆交通大学学报:自然科学版,2016,35(2):24.
27 Yang N R, Zhong B Q, Dong P, et al. Ettringite formation and conditions for its stability[J].Journal of the Chinese Ceramic Society,1984(2):27(in Chinese).
杨南如,钟白茜,董攀,等.钙矾石的形成和稳定条件[J].硅酸盐学报,1984(2):27.
28 Xi Y Z. Recent progress in cement chemistry-notes on the 9th international congress on the chemistry of cement[J].Journal of the Chinese Ceramic Society,1993(6):577(in Chinese).
席耀忠.近年来水泥化学的新进展:记第九届国际水泥化学会议[J].硅酸盐学报,1993(6):577.
29 Álvarez-Ayuso E, Nugteren H W. Synthesis of ettringite: A way to deal with the acid wastewaters of aluminium anodising industry[J].Water Research,2005,39(1):65.
30Kishar E A. Hydration reaction of tricalciumaluminate in different systems[J].Cement & Concrete Research,2005,35(8):1638.
31Hu C G, Ding Q J, Hu S G, et al. Effect of sulfate ions on distribution of Al3+ coordination in hardened cement pastes at variable temperature[J].Journal of Function Materials,2014,45(2):2142(in Chinese).
胡晨光,丁庆军,胡曙光,等.变温下硫酸根离子对水泥浆体中Al3+配位分布的影响[J].功能材料,2014,45(2):2142.
32Ding Q J, Liu K, Zhang G Z, et al. The composition and Al-bearing phases transition of cement paste subjected to MgSO4 attack[J].Journal of Wuhan University of Technology,2016,38(5):1(in Chinese).
丁庆军,刘凯,张高展,等.MgSO4侵蚀条件下水泥浆体相组成及Al相转变[J].武汉理工大学学报,2016,38(5):1.
33 Yu C. Dedradation process and mechanism of cementitious materials subject to sulfate attack[D].Nanjing:Southeast University,2013(in Chinese).
于诚.水泥基材料在硫酸盐侵蚀作用下的劣化过程和机理[D].南京:东南大学,2013.
34 Tian B, Cohen M D. Does gypsum formation during sulfate attack on concrete lead to expansion?[J].Cement & Concrete Research,2000,30(1):117.
35 Xi Y Z. Secondary ettringite formation and durability of expansive concrete[J].China Concerete and Cement Products,2003(2):5(in Chinese).
席耀忠.二次钙矾石形成和膨胀混凝土的耐久性[J].混凝土与水泥制品,2003(2):5.
36 黄士元,蒋家奋,杨南如,等.近代混凝土技术[M].西安:陕西科技出版社,1998.
37 Janković K, Milicić L, Stanković S J, et al. Investigation of the mortar and concrete resistance in aggressive solutions[J].Tehniki Vjesnik,2014,21(1):173.
38 Ma B G, He X Y, Su Y, et al. Investigation of sulfate deterioration of concrete in the environment of inland salt lake[J].Concrete,2001(4):11(in Chinese).
马保国,贺行洋,苏英,等.内盐湖环境中混凝土硫酸盐侵蚀破坏研究[J].混凝土,2001(4):11.
39 Hansen W. A discussion of the paper “scanning electron micrographic studies of ettringite formation” by PK Mehta[J].Cement & Concrete Research,1976,6(4):595.
40Evju C, Hansen S. The kinetics of ettringite formation and dilatation in a blended cement with β-hemihydrate and anhydrite as calcium sulfate[J].Cement & Concrete Research,2005,35(12):2310.
41Mehta P K. Mechanism of expansion associated with ettringite formation[J].Cement & Concrete Research,1973,3(1):1.
42Mehta P K. Scanning electron micrographic studies of ettringite formation[J].Cement & Concrete Research,1976,6(2):169.
43 Scherer G W. Crystallization in pores[J].Cement & Concrete Research,1999,29(8):1347.
44 Scherer G W. Stress from crystallization of salt[J].Cement & Concrete Research,2004,34(9):1613.
45 Chen J K, Jiang M Q. Long-term evolution of delayed ettringite and gypsum in Portland cement mortars under sulfate erosion[J].Construction & Building Materials,2009,23(2):812.
46 Chen S S, Mehta P K. Zeta potential and surface area measurements on ettringite[J].Cement & Concrete Research,1982,12(2):257.
47 Mehta P K, Faichung H U. Further evidence for expansion of ettringite by water adsorption[J].Journal of the American Ceramic Society,1978,61(3-4):179.
48 Mehta P K, Klein A. Formation of ettringite by hydration of a system containing an anhydrous calcium sulfoaluminate[J].Journal of the American Ceramic Society,1965,48(8):435.
49 Liu K W. Damage process and deterioration mechanism of cement-based subjected to sodium sulfate attack[D].Nangjing:Nanjing Tech University,2014(in Chinese).
刘开伟.硫酸钠侵蚀下水泥基材料的劣化过程及机理[D].南京:南京工业大学,2014.
50Hansen W. Attack on Portland cement concrete by alkali soils and waters-a Critical review. Symposium on effects of aggressive fluids on concrete[C]∥Highway Research Record.Transportation Research Board.Washington,1966:1.
51Bonen D, Sarkar S L. Replacement of portlandite by gypsum in the interfacial zone and cracking related to crystallisation pressure[J].Ceramic Transactions,1993,37:49.
52Biczok I. Concret corrosion and concrete protection[M].New York:Chemical Publishing Company,1967.
53 Turchin V, Yudina L, Sattarova A. Research sulfate resistance of cement containing composition[J].Procedia Engineering,2013,57:1166.
54 Ismail I, Bernal S A, Provis J L, et al. Microstructural changes in alkali activated fly ash/slag geopolymers with sulfate exposure[J].Materials and Structures,2013,46(3):361.
55 Bellmann F, Erfurt W, Ludwig H M. Field performance of concrete exposed to sulphate and low pH conditions from natural and indust-rial sources[J].Cement and Concrete Composites,2012,34(1):86.
56 Santhanam M, Cohen M D, Olek J. Sulfate attack research—whit-her now?[J].Cement and Concrete Research,2001,31(6):845.
57 Schmidt T, Lothenbach B, Romer M, et al. Physical and microstructural aspects of sulfate attack on ordinary and limestone blended Portland cements[J].Cement and Concrete Research,2009,39(12):1111.
58 Bellmann F, Möser B, Stark J. Influence of sulfate solution concentration on the formation of gypsum in sulfate resistance test specimen[J].Cement & Concrete Research,2006,36(2):358.
59 Xiao J, Deng D H, Zhang W E, et al. Formation of gypsum leading to the destruction of cement paste under the external sulfate attacking[J].Journal of Building Materials,2006,9(1):19(in Chinese).
肖佳,邓德华,张文恩,等.硫酸盐侵蚀下石膏形成引起的水泥净浆破坏[J].建筑材料学报,2006,9(1):19.
60Crammond N J. Thausamine in failed cement mortars and renders from exposed brickwork[J].Cement & Concrete Research,1985,15(6):1039.
61Hartshorn S A, Sharp J H, Swamy R N. Thaumasite formation in Portland-limestone cement pastes[J].Cement & Concrete Research,1999,29(8):1331.
62Sahu S, Badger S, Thaulow N. Evidence of thaumasite formation in Southern California concrete[J].Cement & Concrete Composites,2002,24(3-4):379.
63 Crammond N J. The thaumasite form of sulfate attack in the UK[J].Cement & Concrete Composites,2003,25(8):809.
64 Bensted J. Thaumasite—direct, woodfordite and other possible formation routes[J].Cement & Concrete Composites,2003,25(8):873.
65 Gaze M E, Crammond N J. The formation of thaumasite in a cement∶lime∶sand mortar exposed to cold magnesium and potassium sulfate solutions[J].Cement & Concrete Composites,2000,22(3):209.
66 Hobbs D W, Taylor M G. Nature of the thaumasite sulfate attack mechanism in field concrete[J].Cement & Concrete Research,2000,30(4):529.
67 Abubaker F, Lynsdale C, Cripps J C. Investigation of concrete-clay interaction with regards to the thaumasite form of sulfate attack[J].Construction and Building Materials,2014,67:88.
68 Collepardi M. Thaumasite formation and deterioration in historic buildings[J].Cement & Concrete Composites,1999,21(2):147.
69 Hees R V, Wijffels T J, Klugt L V D. Thaumasite swelling in historic mortars: Field observations and laboratory research[J].Cement & Concrete Composites,2003,25(8):1165.
70Deloye F, Louarn N, Loos F. Examples of masonry analysis: The case of the Puberg Tunnel[J].Bull de Liaison Lab des Ponts et Chaussees,1989,163(1):17.
71Sahu S, Badger S, Thaulow N. Mechanism of thaumasite formation in concrete slabs on grade in Southern California[J].Cement & Concrete Composites,2003,25(8):889.
72Crammond N.The occurrence of thaumasite in modern construction—A review[J].Cement & Concrete Composites,2002,24(3-4):393.
73 Sylla H M. Reactions in hardened cement paste under heat treatment[J].Beton,1988,38:449.
74 Sibbick R G, Crammond N J. Microscopical investigations into recent field examples of the thaumasite form of sulfate attack(TSA)[C]∥Proceedings of the 8th Euroseminar on Microscopy Applied to Buil-ding Materials.Athens,2001:261.
75 Diamond S. Thaumasite in Orange County, Southern California: An inquiry into the effect of low temperature[J].Cement & Concrete Composites,2003,25(8):1161.
76 He Z, Wang L,Shao Y X, et al. Effect of decalcification on C-S-H gel microstructure in cement paste[J].Journal of Building Materials,2011,14(3):293(in Chinese).
何真,王磊,邵一心,等.脱钙对水泥浆体中C-S-H凝胶结构的影响[J].建筑材料学报,2011,14(3):293.
77 He Y, Lu L, Struble L J, et al. Effect of calcium-silicon ratio on microstructure and nanostructure of calcium silicate hydrate synthesized by reaction of fumed silica and calcium oxide at room temperature[J].Materials & Structures,2014,47(1-2):311.
78 Richardson I G. Tobermorite/jennite- and tobermorite/calcium hydroxide-based models for the structure of C-S-H: Applicability to hardened pastes of tricalcium silicate, β-dicalcium silicate, Portland cement, and blends of Portland cement with blast-furnace slag, metakaol[J].Cement & Concrete Research,2004,34(9):1733.
79 Sun G K, Young J F, Kirkpatrick R J. The role of Al in C-S-H: NMR, XRD, and compositional results for precipitated samples[J].Cement & Concrete Research,2006,36(1):18.
80Bonen D. Composition and appearance of magnesium silicate hydrate and its relation to deterioration of cement-based materials[J].Journal of the American Ceramic Society,2005,75(10):2904.
81Weerdt K D, Justnes H. The effect of sea water on the phase assemblage of hydrated cement paste[J].Cement & Concrete Composites,2015,55:215. |
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2018, Vol. 32 
