石墨烯基储能材料的增材制造研究进展

doi:10.11896/j.issn.1005-023X.2017.013.016

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1503KB)
Export: BibTeX | EndNote (RIS)

Abstract Graphene is a two-dimensional material that offers a combination of large specific surface area,excellent electrical conductivity and exceptional mechanical properties,thus can be broadly applied to fabricate high capacity and power energy storage devices. However, current fabrication schemes of graphene electrodes are unsatisfactory for industrial applications from the perspectives of technics, productivity and property. The additive manufacturing of graphene (three-dimensional printing of graphene) possesses outstanding advantages and potential on fabricating complicated three dimensional graphene micro-lattice.Furthermore, this method is characterized by its low cost and excellent structural properties through manipulating the structure from nanometer up to centimeter scale. In recent two years, the additive manufacturing of graphene and its applications have developed rapidly.This paper introduces the mechanism and advantages of the fabrication scheme of graphene based on a typical additive manufacturing technique—direct ink writing (DIW),describes DIW′s application attempts to manufacture graphene-based materials for energy storage systems (lithium-ion batteries, supercapacitors). It also discusses the challenges and future trend of the additive manufacturing of graphene-based electrodes.

Key words： graphene additive manufacturing electrode materials direct ink writing

Published: 04 May 2018

CLC number:

TB34

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	HE Bo
	PAN Yufei
	LU Min

Cite this article:

HE Bo,PAN Yufei,LU Min. Additive Manufacturing of Graphene-based Energy Storage Materials:A State-of-the-art Review[J]. Materials Reports, 2017, 31(13): 126-130.

URL:

http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.013.016 OR http://www.mater-rep.com/EN/Y2017/V31/I13/126

1 Stein A. Energy storage: Batteries take charge[J]. Nat Nanotech-nol,2011,6(5):262.
2 Zhu J, Yang D, Yin Z, et al. Graphene and graphene-based mate-rials for energy storage applications[J]. Small,2014,10(17):3480.
3 Bruce P G, Freunberger S A, Hardwick L J, et al. Li-O₂ and Li-S batteries with high energy storage[J]. Nat Mater,2012,11(1):19.
4 Peigney A, et al. Specific surface area of carbon nanotubes and bundles of carbon nanotubes[J]. Carbon,2001,39(4):507.
5 Lee C, Wei X, Kysar J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science,2008,321(5887):385.
6 Geim A K. Graphene: Status and prospects[J]. Science,2009,324(5934):1530.
7 Balandin A A, Ghosh S, Bao W, et al. Superior thermal conductivity of single-layer graphene[J]. Nano Lett,2008,8(3):902.
8 Li X, Zhang G, Bai X, et al. Highly conducting graphene sheets and Langmuir-Blodgett films[J]. Nature Nanotechnol,2008,3(9):538.
9 Zhu C, Liu T, Qian F, et al. Supercapacitors based on three-dimensional hierarchical graphene aerogels with periodic macropores[J]. Nano Lett,2016,16(6):3448.
10 García-Tuñon E, Barg S, Franco J, et al. Printing in three dimensions with graphene[J]. Adv Mater,2015,27(10):1688.
11 Cesarano J. A review of robocastingtechnology[M]. Cambridge: Cambridge University Press,1998: 542.
12 Lewis J A. Direct ink writing of 3D functional materials[J]. Adv Funct Mater,2006, 16(17):2193.
13 Smay J E, Gratson G M, et al. Directed colloidal assembly of 3D periodic structures[J]. Adv Mater,2002,14(18):1279.
14 Zhu C, Smay J E. Thixotropic rheology of concentrated alumina colloidal gels for solid freeform fabrication[J]. J Rheol,2011,55(3):655.
15 Xu Y, Sheng K, Li C, et al. Self-assembled graphene hydrogel via a one-step hydrothermal process[J]. ACS Nano,2010,4(7):4324.
16 Le L T, Ervin M H, Qiu H, et al. Graphene supercapacitor electrodes fabricated by inkjet printing and thermal reduction of graphene oxide[J]. Electrochem Commun,2011,13(4):355.
17 Bagri A, et al. Structural evolution during the reduction of chemically derived graphene oxide[J]. Nat Chem,2010,2(7):581.
18 Pei S, Cheng H. The reduction of graphene oxide[J]. Carbon,2012,50(9):3210.
19 Barg S, et al. Mesoscale assembly of chemically modified graphene into complex cellular networks[J]. Nat Commun,2014,5:4328.
20 Qiu L, Liu J Z, Chang S L Y, et al. Biomimetic superelastic graphene-based cellular monoliths[J]. Nat Commun,2012,3:1241.
21 Hu H, Zhao Z, Wan W, et al. Ultralight and highly compressible graphene aerogels[J]. Adv Mater, 2013,25(15):2219.
22 Jakus A E, Secor E B, Rutz A L, et al. Three-dimensional printing of high-content graphene scaffolds for electronic and biomedical applications[J]. ACS Nano,2015,9(4):4636.
23 Zhu C, Han T Y, Duoss E B, et al. Highly compressible 3D periodic graphene aerogel microlattices[J]. Nat Commun, DOI:10.1038/ncomms7962.
24 Sun H, Xu Z, Gao C. Multifunctional, ultra-flyweight, synergistically assembled carbon aerogels[J]. Adv Mater,2013,25(18):2554.
25 Zhang Q, Zhang F, Medarametla S P, et al. 3D printing of grapheneaerogels[J]. Small,2016, 12(13):1702.
26 Lin Y, Liu F, Casano G, et al. Pristine graphene aerogels by room-temperature freeze gelation.[J]. Adv Mater,2016,28(36):7993.
27 吕勇. 石墨烯及石墨烯/碳纳米管的制备与储能应用[D]. 成都: 西南交通大学,2015:81.
28 Miller J R, Simon P. Electrochemical capacitors for energy management[J]. Science,2008, 321(5889):651.
29 An K H, Kim W S, Park Y S, et al. Supercapacitors using single-walled carbon nanotube electrodes[J]. Adv Mater,2001,13(7):497.
30 Kim S, Koo H, Lee A, et al. Selective wetting-induced micro-electrode patterning for flexible micro-supercapacitors[J]. Adv Mater,2014,26(30):5108.
31 Gamby J, Taberna P L, Simon P, et al. Studies and characterisa-tions of various activated carbons used for carbon/carbon supercapa-citors[J]. J Power Sources,2001,101(1):109.
32 Chmiola J, Largeot C, Taberna P, et al. Monolithic carbide-derived carbon films for micro-supercapacitors[J]. Science,2010,328(5977):480.
33 Pech D, Brunet M, Durou H, et al. Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon[J]. Nat Nanotech-nol,2010,5(9):651.
34 Zhou Y, Candelaria S L, Liu Q, et al. Sulfur-rich carbon cryogels for supercapacitors with improved conductivity and wettability[J]. J Mater Chem A,2014,2(22):8472.
35 Huang Y,et al. An overview of the applications of graphene-based materials in supercapacitors[J]. Small,2012,8(12):1805.
36 Liu C, Yu Z, Neff D, et al. Graphene-based supercapacitor with an ultrahigh energy density[J]. Nano Lett,2010,10(12):4863.
37 Yan J, Wang Q, Wei T, et al. Recent advances in design and fabrication of electrochemical supercapacitors with high energy densities[J]. Adv Energy Mater, DOI: 10.1002/aenm.201300816.
38 Jiang X, Wang X, Dai P, et al. High-throughput fabrication of strutted graphene by ammonium-assisted chemical blowing for high-performance supercapacitors[J]. Nano Energy,2015, 16:81.
39 Chen Z, Ren W, Gao L, et al. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J]. Nat Mater,2011,10(6):424.
40 Wang Y, Tang J, Kong B, et al. Freestanding 3D graphene/cobalt sulfide composites for supercapacitors and hydrogen evolution reaction[J]. RSC Adv,2015,5(9):6886.
41 Bi H, Yin K, Xie X, et al. Low temperature casting of graphene with high compressive strength[J]. Adv Mater,2012,24(37):5124.
42 Worsley M A, Olson T Y, Lee J R I, et al. High surface area, sp²-cross-linked three-dimensional graphene monoliths[J]. J Phys Chem Lett,2011,2(8):921.
43 Qiu L, Liu J Z, Chang S L Y, et al. Biomimetic superelastic graphene-based cellular monoliths[J]. Not Commun,2012,3:1241.
44 Kim J H, Chang W S, Kim D, et al. 3D printing of reduced graphene oxide nanowires[J]. Adv Mater, 2015,27(1):157.
45 Gryglewicz G, Šliwak A, Béguin F. Carbon nanofibers grafted on activated carbon as an electrode in high-power supercapacitors[J]. ChemSusChem,2013,6(8):1516.
46 Yu J K A H. All-solid-state flexible supercapacitors based on papers coated with carbon nanotubes and ionic-liquid-based gel electrolytes[J]. Nanotechnology,2012,23(6):65401.
47 Wang G, Wang H, Lu X, et al. Solid-state supercapacitor based on activated carbon cloths exhibits excellent rate capability[J]. Adv Mater,2014,26(17):2676.
48 Yoo E, Kim J, Hosono E, et al. Large reversible Li storage of graphenenanosheet families for use in rechargeable lithium ion batteries[J]. Nano Lett,2008,8(8):2277.
49 Cai Dandan. Study on graphene-based high-performance anode material for lithium-ion batteries [D]. Guangzhou: South China University of Technology,2014:136.
蔡丹丹. 基于石墨烯的高性能锂离子电池负极材料的研究[D]. 广州: 华南理工大学,2014:136.
50 Sun K, Wei T, Ahn B Y, et al. 3D printing of interdigitated li-ion microbatteryarchitectures[J]. Adv Mater,2013,25(33):4539.
51 Fu K, Wang Y, et al. Graphene oxide-based electrode inks for 3D-printed lithium-ion batteries[J]. Adv Mater,2016,28(13):2587.