WO<sub>3</sub>基纳米材料的可控合成及其功能化应用<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.011.003

Abstract
Figure/Table
References
Related Citation (3)

Download:

Full Text ( PDF ) (2249KB)
Export: BibTeX | EndNote (RIS)

Abstract Nano-WO₃ based materials have many unique properties, such as photodegradation, water splitting, photochromism, electrochromism, etc. Therefore, nano-WO₃ based materials are potentially used in photocatalysis, new energy resources utilization, smart windows, sensing capabilities and flat-panel display. Research achievements of spray drying method, sol-gel method, hydrothermal method and template method, which are widely used in synthesis of nano-WO₃based materials, are introduced in detail. And the existing problems of these processes are analyzed. Furthermore, the progress of nano-WO₃based materials in photodegradation, pollutants adsorption, water splitting and electrochromism in recent years are reviewed in this paper.An outlook over application and development prospect of nano-WO₃ based materials is given at last.

Key words： WO₃ nano-materials controlled-synthesis template method

Published: 04 May 2018

CLC number:

TB321

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHANG Lina
	SU Qi
	YANG Gaoling
	LIU Baixiong
	YANG Bin

Cite this article:

ZHANG Lina,SU Qi,YANG Gaoling, et al. Review on Controlled-synthesis and Functional Application of Nano-WO₃ Based Materials[J]. Materials Reports, 2017, 31(11): 20-28.

URL:

http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.011.003 OR http://www.mater-rep.com/EN/Y2017/V31/I11/20

1 Masahiro S, Keisuke S, Hironobu K, et al. Preparation of 3-D ordered macroporous tungsten oxides and nano-crystalline particulate tungsten oxides using a colloidal crystal template method, and their structural characterization and application as photocatalysts under visible light irradiation [J]. J Mater Chem,2010,20:1811.
2 He H C, Berglund S P, Xiao P, et al. Nanostructured Bi₂S₃/WO₃ heterojunction films exhibiting enhanced photoelectrochemical performance [J]. J Mater Chem A,2013,1:12826.
3 White C M, Jang J S, Lee S H, et al. Photocatalytic activity and photoelectrochemical property of nano-WO₃ powders made by hot-wire chemical vapor deposition [J]. Electrochem Solid State Lett,2010,13:120.
4 Liu Y Y, Li W Z, Han S, et al. Photoelectrochemical properties and photocatalytic activity of nitrogen-doped nanoporous WO₃ photoelectrodes under visible light [J]. Appl Surf Sci,2012,258: 5038.
5 Liu B X, Wang J S, Wu J S, et al. Proton exchange growth to mesoporous WO₃·0.33H₂O structure with highly photochromic sensitivity [J]. Mater Lett,2013,91:334.
6 Lu Y Y, Liu G, Zhang J, et al. Fabrication of a monoclinic/hexagonal junction in WO₃ and its enhanced photocatalytic degradation of rhodamine B[J]. Chinese J Catal, 2016, 37(3):349(in Chinese).
卢圆圆, 刘果, 张静, 等. WO₃ 中单斜相/六方相异相结的构建及提高光催化降解罗丹明 B 活性[J]. 催化学报,2016,37(3):349.
7 Lv R J, Zhang F X, Li Y J, et al. Solvothermal synthesis of mesoporous tungsten oxide materials with special morphology and their adsorptive properties[J]. Appl Chem,2013, 30(11):1338(in Chinese).
吕仁江, 张福祥, 李英杰, 等. 溶剂热合成具有特殊形貌的介孔 WO₃ 材料及其吸附性能[J]. 应用化学,2013,30(11):1338.
8 Fang C, Wang H, Shi S Q. Research progresss of electrochromic performances of WO₃[J]. Acta Phys Sin,2016,65(16):168201(in Chinese).
方成, 汪洪, 施思齐. 氧化钨电致变色性能的研究进展[J]. 物理学报,2016,65(16):168201.
9 Feng Z P, Wei F, Zhao H B, et al. Electrochromic behavior of WO₃ thin films prepared by dadio frequency magnetron sputtering[J]. Rare Met,2016,40(9):902(in Chinese).
冯志鹏, 魏峰, 赵鸿滨, 等. 射频磁控溅射 WO₃ 薄膜电致变色性能研究[J]. 稀有金属,2016, 40(9):902.
10 Liu B X, Wang J S, Li H Y, et al. Hollow mesoporous WO₃ spheres: Preparation and photocatalytic activity [J]. Inorg Chem,2012,28:465.
11 Yang T S, Zhang Y, Li C. Large scale production of spherical WO₃ powder with ultrasonic spray pyrolysis assisted by sol-gel method for hydrogen detection [J]. Ceram Int,2014,40:1765.
12 Choi Y G, Sakai G, Shimanoe K, et al. Wet process-prepared thick films of WO₃ for NO₂ sensing [J]. Sensor Actuators B: Chem,2003,95:258.
13 Tong M, Dai G, Gao D. WO₃ Thin film sensor prepared by sol-gel technique and its low-temperature sensing properties to trimethy-lamine [J].Mater Chem Phys,2001,69:176.
14 Li C P, Lin F, Richards R M, et al. Ultrasonic spray deposition of high performance WO₃ films using template-assisted sol-gel chemistry [J]. Electrochem Commun,2012,25:62.
15 Deepa M, Sharma R, Basu A, et al. Effect of oxalic acid dihydrate on optical and electrochemical properties of sol-gel derived amorphous electrochromic WO₃ films [J].Electrochim Acta,2005,50:3545.
16 Feng W, Wu G M, Gao G H. Ordered mesoporous WO₃ film with outstanding gasochromic properties [J]. J Mater Chem A,2014,2:585.
17 Breedon M, Spizzirii P, Taylor M, et al. Synthesis of nanostructured tungsten oxide thin film: A simple, controllable, inexpensive, aqueous sol-gel method [J]. Cryst Growth Des,2010,10:430.
18 Wang H R, Gao G H, Wu G M.TiO₂-doped WO₃ gasochromic thin films produced by sol-gel technique with high hydrogen-sensing pro-perties[J].Rare Met Mater Eng,2016(S1):325(in Chinese).
王浩然, 高国华, 吴广明,等. 溶胶-凝胶法制备高氢气敏感性的TiO₂复合WO₃薄膜(英文)[J]. 稀有金属材料与工程,2016(S1):325.
19 Su X, Xiao F, Li Y, et al. Synthesis of uniform WO₃ square nanoplates via an organic acid-assisted hydrothermal process [J]. Mater Lett,2010,64:1232.
20 Patil V B, Adhyapak P V, Suryavanshi S S, et al. Oxalic acid induced hydrothermal synthesis of single crystalline tungsten oxied nanorods [J]. J Alloy Compd,2014,590:283.
21 Park S Y, Lee J M, Noh C, et al. Colloidal approach for tungsten oxide nanorod-based electrochromic systems with highly improved response times and color efficiencies [J]. J Mater Chem,2009,19:7959.
22 Phuruangrat A, Ham D J, Hong S J, et al. Synthesis of hexagonal WO₃ nanowires by microwave-assisted hydrothermal method and their electrocatalytic activities for hydrogen evolution reaction [J]. J Mater Chem,2009,20:1683.
23 Lee C Y, Kim S J, Hwang I S, et al. Glucose-mediated hydrothermal synthesis and gas sensing characteristics of WO₃ hollow microspheres[J].Sensor Actuators B: Chem,2009,142:236.
24 Xi G C, Ouyang S X, Li P, et al. Near-infrared adsorption, photoluminescence, and photochemical reduction of carbon dioxide [J]. Angew Chem Int Ed,2012,51:2395.
25 Guo C S, Yin S, Yan M, et al. Morphology-controlled synthesis of W₁₈O₄₉ nanostructures and their near-infrared absorption properties [J]. Inorg Chem,2012,51:4763.
26 Zhao Z G, Miyauchi M. Shape modulation of tungstic acid and tungsten oxide hollow structures [J]. J Phys Chem C,2009,113:6539.
27 Zhang H J. Study on hydrothermal synthesis of WO₃ nanostructures and their gas-sensing properties[D]. Chongqing:Chongqing University,2013(in Chinese).
张合静. 水热法制备纳米三氧化钨及其气敏性能研究[D]. 重庆:重庆大学,2013.
28 Li J, Li L J, Gao Y F, et al. Preparation of nanomaterials employing template method[J]. Mater Rev,2011,25(S2):5(in Chinese).
李静, 李利军, 高艳芳, 等. 模板法制备纳米材料[J]. 材料导报,2011,25(专辑18):5.
29 Zhao Z G, Miyauchi M. nanoporous-walled tungsten oxide nanotubes as highly active visible-light-driven photocatalysts [J]. Angew Chem Int Ed,2008,120:7159.
30 Zhang Y, Yuan J, Le J, et al. Structural and electrochromic properties of tungsten oxide prepared by surfactant-assisted process [J]. Sol Energ Mater Sol Cells,2009,93:1338.
31 Ozkan E, Lee S H, Liu P, et al. Electrochromic and optical properties of mesoporous tungsten oxide films [J]. Solid State Ion,2002,149:139.
32 Sun S, Wang W, Zeng S, et al. Preparation of ordered mesoporous Ag/WO₃ and its highly efficient degradation of acetaldehyde under visible-light irradiation[J]. J Hazard Mater,2010, 178:427.
33 Li H, Theriault J, Rousselle B, et al. Facile fabrication of crack free large-area 2D WO₃ inverse opal films by a ‘dynamic hard-template’ strategy on ITO substrates [J]. Chem Commun,2014, 50:2184.
34 Bi D Q, Xu Y M. Influence of iron oxide doping on the photocataly-tic degradation of organic dye X3B over tungsten oxide[J]. Acta Phys Chim Sin,2012,28(7):1777(in Chinese).
毕冬琴, 许宜铭. Fe₂O₃ 掺杂对 WO₃ 光催化降解有机染料 X3B 的影响[J]. 物理化学学报, 2012, 28(7):1777.
35 Zhong L Q, Liu Y J, Xu Y L, et al. Photocatalytic degradation of organic dye with H₃PW₁₂O₄₀/ZrO₂-WO₃ sensitized by H₂O₂[J]. Fine Chem,2013,30(12):1413 (in Chinese).
钟立群, 刘艳举, 徐玉林, 等. H₂O₂ 处理 H₃PW₁₂O₄₀/ZrO₂-WO₃ 光催化降解有机染料[J]. 精细化工,2013,30(12):1413.
36 Nandiyanto A B, Arutanti O, Ogi T, et al. Synthesis of spherical macroporous WO₃ particles and their high photocatalytic perfor-mance [J]. Chem Eng Sci,2013,101:523.
37 Liu B X, Wang J S, Li H Y, et al. Facile synthesis of hierarchical hollow mesoporous Ag/WO₃ spheres with high photocatalytic performance [J]. J Nanosci Nanotechnol,2013,13:4117.
38 Liu B X, Wang J S, Wu J S, et al. Controlled fabrication of hierarchical WO₃hydrates with excellent adsorption performance [J]. J Mater Chem A,2014,2:1947.
39 Shi J C, Hu G J, Cong R, et al. Controllable synthesis of WO₃·nH₂O microcrystals with various morphologies by a facile inorganic route and their photocatalytic activities [J]. New J Chem,2013, 37:1538.
40 Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode [J]. Nature,1972,238:37.
41 Hodes G, Cahen D, Manassen J. Tungsten trioxide as a photoanode for a photoelectrochemical cell (PEC) [J].Nature,1976,260:312.
42 Abe R, Shinmei K, Koumura N, et al. Visible-light induced water splitting based on two-step photoexcitation between dye-sensitized layered niobate and tungsten oxide photocatalysts in the presence of a triiodide/lodide shuttle redox mediator[J]. J Am Chem Soc,2013,135:16872.
43 Vito C, Stefano C, Roberto A. Efficient photoelectrochemical water splitting by anodically grown WO₃ electrodes [J]. Langmuir,2011,27:7276.
44 Su J Z, Guo L J, Bao N Z. Nanostructure WO₃/BiVO₄ heterojunction films for efficient photoelectronchemical water splitting [J]. Nano Lett,2011,11:1928.
45 Abe R, Higashi M, Domen K. Overall water splitting under visible light through a two-step photoexcitation between TaON and WO₃ in the presence of an iodate-iodide shuttle redox mediator [J]. Chem Sus Chem,2011,4:228.
46 Tanaka A, Hashimoto K, Kominami H. Visible-light-induced hydrogen and oxygen formation over Pt/Au/WO₃ photocatalyst utilizing two types of photoabsorption due to surface Plasmon resonance and band-gap excitation [J]. J Am Chem Soc,2014,136:586.
47 Xu N, Shen X D, Cui S. Progress and potential application of electrochromic materials[J]. Rare Earth,2010(4):610(in Chinese).
徐娜, 沈晓冬, 崔升. 电致变色材料的研究进展及发展前景[J]. 稀有金属,2010(4):610.
48 Jiao Z H, Wang X, Wang J M, et al. Efficient synthesis of plate-like crystalline hydrated tungsten trioxide thin films with highly improved electrochromic performance[J]. Chem Commun, 2012,48:365.
49 Chen H C, Jan D J, Chen C H, et al. Bond and electrochromic pro-perties of WO₃ films deposited with horizontal DC, pulsed DC, and RF sputtering [J]. Electrochim Acta,2013,93:307.