MULTI SCALE RARE EARTH CRYSTAL MATERIALS AND THEIR APPLICATIONS |
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Recent Research on Luminescent Materials Derived from Layered Rare-earth Hydroxides |
CHEN Lu, ZHU Qi*, SUN Xudong*
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Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education),School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China |
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Abstract Layered rare-earth hydroxides (LRHs), having a unique combination of a layered structure and the functional properties of rare-earth elements, are a new family of functional materials. The compounds have potential applications in electro-optic, catalytic, biomedical fields and so forth. This review summarizes the recent research on LRHs, including controlled synthesis, structural features, anion exchange, nanosheet exfoliation, and application in the field of luminescence for both the Ln2(OH)5(Ax-)1/x·nH2O (251-LRHs) and Ln2(OH)4SO4·nH2O (241-LRHs). Particular attention is paid to the size and morphology control and nano sheets exfoliation in 251-LRHs. The luminescent behaviors of LRHs themselves and calcined derivatives of the oxide, oxysulfate, and oxysulfide for phosphors, highly oriented transparent films, and optical temperature sensors are the main content. Finally, the prospects of LRHs on novel functional materials are proposed, which provides a new way for future functional design.
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Published: 10 February 2023
Online: 2023-02-23
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Fund:The National Natural Science Foundation of China (51302032) and the Natural Science Foundation of Liaoning Province (2020-MS-081). |
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