正渗透膜材料及其制备方法的研究进展

doi:10.11896/cldb.18070088

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Abstract As a novel membrane separation technique with high potential, forward osmosis technique has attracted extensive attention in recent years. However, the lack of high performance forward osmosis membranes has been a key factor impeding the advancement of forward osmosis technique. To date, a great many researches have been devoted to membrane structure optimization and the search for new membrane materials. Several common forward osmosis membranes, such as cellulose acetate (CA) membranes, aromatic polyamide (PA) membranes and polybenzimidazole (PBI) membranes have been widely applied in forward osmosis process. However, the disadvantages of these membrane materials are also prominent. For example, cellulose acetate membrane is easy to be hydrolyzed, poor in acid and alkali resistance; polyamide composite membrane has higher fouling tendency and poor chlorine resistance and PBI membrane has poor toughness with high price. Therefore, the deve-lopment of new types of forward osmosis membrane materials is of great significance for the improvement of membrane properties.
As we all known, FO technique is developing rapidly, so FO membrane performance needs to be improved as well. The optimization of membrane structure is crucial to improve the performance of FO membrane, and the optimization of separation layer and support layer structure is the key. In recent years, nanoparticles with the advantages of anti-fouling and hydrophilicity have been widely used in forward osmosis process. The membrane surface hydrophilicity is improved by adding nanoparticles such as zeolite, TiO₂ nanoparticles and graphene oxide into the separation layer of the membrane to improve the FO membrane performance. In addition, layer-by-layer (LBL) assembly and double-layer structures are also used to optimize the separation layer of the membrane. The internal concentration polarization (ICP) occurring in support layer is the main factor affecting the FO performance. Therefore, optimizing the support layer of the membrane is important to improve the membrane performance. Researchers have optimized the membrane support layer by increasing the hydrophilicity, reducing the thickness, and improving the pore structure. The hydrophilicity of the support layer can be improved by selecting a hydrophilic support layer material and modifying the support layer surface. Furthermore, the support layer with small thickness, high porosity, small tortuosity, high mechanical strength and good anti-fouling perfor-mance is indispensable for a high-performance FO membrane.
In this paper, recent advancementon forward osmosis membrane fabrication methods are reviewed. Several common forward osmosis membranes and fresh forward osmosis membrane as well as their fabrication methods are summarized. Taking into account the aspects of optimizing the separation layer and support layer structure, reducing the internal concentration polarization, optimizing the pore structure, improving the mechanical strength of the membrane and reducing the difficulty of post-cleaning, the recent research progress and development trend of the fabrication methods and structure control of forward osmosis membranes are analyzed under the criterion of a high water flux, high salt rejection, strong mechanical properties and anti-pollution properties.

Key words： forward osmosis membrane structure optimization membrane fouling

Published: 23 July 2019

CLC number:

TQ028

Fund:This work was financially supported by the National Natural Science Foundation of China (21576249).

About author:: Na Sun received her B.E. degree from Shandong University of Science and Technology in 2016. Currently she is pursuing her M.E. at Ocean University of China. Her research is focused on the preparation of forward osmosis membranes and water treatment technology.
Duo Wang is currently an associate professor of the Ocean University of China. His research interest includes membrane fabrication and characterization, membrane separation and water treatment technology. In recent years, his research mainly focuses on preparation of reverse osmosis and forward osmosis membranes and seawater desalination.

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Cite this article:

SUN Na,WANG Duo,WANG Meng. Research Progress of Forward Osmosis Membrane Materials and Their Preparation Methods[J]. Materials Reports, 2019, 33(17): 2966-2975.

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http://www.mater-rep.com/EN/10.11896/cldb.18070088 OR http://www.mater-rep.com/EN/Y2019/V33/I17/2966

1	Dova M I, Petrotos K B, Lazarides H N.<i>Journal of Food Engineering</i>, 2007, 78(2), 422.<br />
2	Babu B R, Rastogi N K, Raghavarao K. <i>Journal of Membrane Science</i>, 2006, 280(1), 185.<br />
3	Garg A, Gupta M, Bhargava H N. <i>European Journal of Pharmaceutics and Biopharmaceutics</i>, 2007, 67(3), 725.<br />
4	Lavan D A, Mcguire T, Langer R. <i>Nature Biotechnology</i>, 2003, 21(10), 1184.<br />
5	Loeb S. <i>Desalination</i>, 1998, 120, 247.<br />
6	Mcginnis R L, Mccutcheon J R, Elimelech M. <i>Journal of Membrane Science</i>, 2007, 305(1-2), 13.<br />
7	Mcginnis R L,Elimelech M. <i>Desalinatio</i>n, 2007, 207(1-3), 370.<br />
8	Cath T Y, Childress A E, Elimelech M.<i>Journal of Membrane Science</i>, 2006, 281, 70.<br />
9	Li L L, Wang D.<i>Journal of functional materials</i>, 2012, 43(5), 595(in Chinese).<br />
	李丽丽, 王铎. 功能材料, 2012, 43(5), 595.<br />
10	Wang M, Wang Z, Li Z X. <i>Membrane materials and their preparation, </i>Chemical Industry Press, China, 2003, pp.49(in Chinese).<br />
	汪锰, 王湛, 李政雄. 膜材料及其制备, 化学工业出版社, 2003,pp.49.<br />
11	Mccutcheon J R, Mcginnis R L, Elimelech M. <i>Desalination</i>, 2005, 174, 1.<br />
12	Herron J. U.S. patent application, WO2006110497, 2006.<br />
13	Liu L L, Wang D, Wang M, et al. <i>Membrane Science and Technology</i>, 2011, 31(1), 77(in Chinese).<br />
	刘蕾蕾, 王铎, 汪锰, 等. 膜科学与技术, 2011, 31(1), 77.<br />
14	Guan P P, Wang D.<i>Desalination and Water Treatment</i>, 2016, 57, 27505.<br />
15	Li G, Li X M, He T, et al. <i>Desalination and Water Treatment</i>, 2013, 51(13-15), 2656.<br />
16	Zhao S, Zou L.<i>Desalination</i>, 2011, 278(1), 157.<br />
17	Yip N Y, Tiraferri A, Phillip W A, et al.<i>Environmental Science & Technology</i>, 2011, 45(10), 4360.<br />
18	Yip N Y, Tiraferri A, Phillip W A, et al.<i>Environmental Science & Technology</i>, 2010, 44(10), 3812.<br />
19	Huang Y. Studies on preparation and performance of polyamide composite forward osmosis membrane. 's Thesis, Ocean University of China, China, 2011(in Chinese).<br />
	黄燕. 聚酰胺复合正渗透膜的制备及其性能研究. 硕士学位论文, 中国海洋大学, 2011.<br />
20	Wang R, Shi L, Tang C Y, et al.<i>Journal of Membrane Science,</i> 2010, 355(1), 158.<br />
21	Wei J, Qiu C, Tang C Y, et al.<i>Journal of Membrane Science</i>, 2011, 372(1), 292.<br />
22	Shen L, Wang F Q, Tian L, et al. <i>Journal of Membrane Science</i>, 2018, 563, 284.<br />
23	Li X S, Loh C H, Wang R, et al. <i>Journal of Membrane Science</i>, 2017, 525, 257.<br />
24	Wang K Y, Chung T S, Qin J J. <i>Journal of Membrane Science</i>, 2007, 300, 6.<br />
25	Yang Q, Wang K Y, Chung T S.<i>Environmental Science and Technology</i>, 2009, 43, 2800.<br />
26	Flanagan M F, Escobar I C.<i>Journal of Membrane Science</i>, 2013, 434(5), 85.<br />
27	Han J, Cho Y H, Kong H, et al. <i>Journal of Membrane Science</i>, 2013, 428, 533.<br />
28	Shaffer D L, Werbe J R, Jaramillo H, et al. <i>Desalination</i>, 2015, 356, 271.<br />
29	You S J, Tang C Y, Yu C, et al. <i>Environmental Science and Technology</i>, 2013, 47, 8733.<br />
30	Zhong Y J, Zhang J C, Wu Z Y,et al. <i>Journal of Chemical Industry and Engineering</i>, 2015, 66(1), 386(in Chinese).<br />
	钟溢键, 张济辞, 吴子焱, 等. 化工学报, 2015, 66(1), 386.<br />
31	Liu P, Zhang S H, Wang T. <i>Membrane Science and Technology</i>, 2016, 36(4), 7(in Chinese)<br />
	刘鹏, 张守海, 王涛. 膜科学与技术, 2016, 36(4), 7.<br />
32	Kanagaraj P, Nagendran A, Rana D, et al.<i>Applied Surface Science</i>, 2015, 329, 165.<br />
33	Waheed S, Ahmad A, Khan S M,et al. <i>Desalination</i>, 2014, 351, 59.<br />
34	Bilongo T G, Remigy J C, Clifton M J.<i>Journal of Membrane Science</i>, 2010, 364, 304.<br />
35	Li X S, Wang R, Tang C Y, et al. <i>Colloids and Surfaces B: Biointerfa-ces</i>, 2012, 94, 333.<br />
36	Wang H, Chung T S, Tong Y W, et al. <i>Soft Matter</i>, 2011, 7, 7274.<br />
37	Zhang Y, Qiu C, Li X, et al. <i>Journal of Membrane Science</i>, 2012, 423-424, 422.<br />
38	Sun G, Chung T S, Jeyaseelan K, et al. <i>RAC Advances</i>, 2013, 3, 473.<br />
39	Wang H L, Chung T S, Tang Y W, et al. <i>Journal of Membrane Science</i>, 2013, 434, 130.<br />
40	Wang H L, Chung T S, Tang Y W. <i>Journal of Membrane Science</i>, 2013, 445, 47.<br />
41	Ma N, Wei J, Liao R H,et al. <i>Journal of Membrane Science</i>, 2012, 405-406, 149.<br />
42	Niksefat N, Jahanshahi M, Rahimpour A.<i>Desalination</i>, 2014, 343, 140.<br />
43	Rajaeian B, Rahimpour A, Tade M O, et al.<i>Desalination</i>, 2013, 313, 176.<br />
44	Amini M, Jahanshahi M, Rahimpour A.<i>Journal of Membrane Science</i>, 2013, 435, 233.<br />
45	Ghanbari M, Emadzadeh D, Lau W J, et al. <i>Desalination</i>, 2015, 358, 33.<br />
46	Nguyena T P N, Yuan E T, Kim I C, et al. <i>Journal of Membrane Science</i>, 2013, 433, 49.<br />
47	Zirehpour A, Rahimpour A, Seyedpour F, et al. <i>Desalination</i>, 2015, 371, 46.<br />
48	Jin L M, Wang Z Y, Zheng S X,et al. <i>Journal of Membrane Science</i>, 2018, 545, 11.<br />
49	Liu C, Fang W X, Chou S R, et al. <i>Desalination</i>, 2013, 308, 147.<br />
50	Qiu C Q, Qi S, Tang C Y. <i>Journal of Membrane Science</i>, 2011, 381, 74.<br />
51	Li M N, Sun X F, Wang L, et al.<i>Desalination</i>. 2018, 436, 107.<br />
52	王铎, 许春玲, 苏燕, 等. 中国专利, CN103055713A, 2013.<br />
53	Su J, Chung T S, Helmer B J, et al. <i>Journal of Membrane Science</i>, 2012, 396, 92.<br />
54	Qi S, Qiu C Q, Zhao Y, et al. <i>Journal of Membrane Science</i>, 2012, 405, 20.<br />
55	姜莹, 邹昊, 彭博, 等. 中国专利, CN103432913A, 2013.<br />
56	Fang W X, Wang R, Chou S R, et al. <i>Journal of Membrane Science</i>, 2012, 394-395, 140.<br />
57	Loeb S, Titelman L, Korngold E, et al. <i>Journal of Membrane Science</i>, 1997, 129(2), 243.<br />
58	Ma N, Wei J, Qi S, et al. <i>Journal of Membrane Science</i>, 2013, 441, 54.<br />
59	Tian E L, Zhou H, Ren Y W, et al. <i>Desalination</i>, 2014, 347, 207.<br />
60	Zhou Z Z, Lee J Y, Chung T S. <i>Chemical Engineering Journal</i>, 2014, 249, 236.<br />
61	Vilakati G D, Wong M C Y, Hoek E M V,et al. <i>Journal of Membrane Science</i>, 2014, 469, 216.<br />
62	Widjojo N, Chung T S, Weber M, et al. <i>Chemical Engineering Journal</i>, 2013, 220, 15.<br />
63	Han G, Chung T S, Toriida M, et al. <i>Journal of Membrane Science</i>, 2012, 423-424, 543.<br />
64	Wang Y Q, Xu T W.<i>Journal of Membrane Science</i>, 2015, 476, 330.<br />
65	Yasukawa M, Mishima S, Shibuya M, et al. <i>Journal of Membrane Science</i>, 2015, 487, 51.<br />
66	Ong R C, Chung T S, Wit J S, et al.<i>Journal of Membrane Science</i>, 2015, 473, 63.<br />
67	Huang L W, Bui N N, Meyering M T, et al.<i>Journal of Membrane Science</i>, 2013, 437, 141.<br />
68	Emadzadeh D,Lau W J, Matsuura T, et al. <i>Journal of Membrane Science</i>, 2014, 449, 74.<br />
69	Emadzadeh D, Lau W J, Matsuura T,et al. <i>Desalination</i>, 2014, 348, 82.<br />
70	Darabi R R, Jahanshah M, Peyravi M. <i>Chemical Engineering Research and Design</i>, 2018, 133, 11.<br />
71	Liu X, Ng H Y.<i>Journal of Membrane Science</i>, 2015, 481, 148.<br />
72	Wu X, Field R W, Wu J J, et al.<i>Journal of Membrane Science</i>. 2017, 540, 251.<br />
73	Arena J T, Manickam S S, Reimund K K, et al. <i>Desalination</i>. 2014, 343, 8.<br />
74	Yu Y, Seo S, Kim I C,et al. <i>Journal of Membrane Science</i>, 2011, 375(1-2), 63.<br />
75	Herron J R, Beaudry E G, Jochums C E, et al.U.S. patent, US5281230, 1994.<br />
76	Stillman D, Krupp L, La Y H.<i>Journal of Membrane Science</i>, 2014, 468, 308.<br />
77	Wang K Y, Yang Q, Chung T S, et al. <i>Chemical Engineering Science</i>, 2009, 64, 1577.<br />
78	Tian M, Qiu C Q, Liao Y, et al. <i>Separation and Purification Technology</i>, 2013, 118, 727.<br />
79	Puguan J M C, Kim H S, Lee K J,et al. <i>Desalination</i>, 2014, 336, 24.<br />
80	靳焘, 姜婷婷, 胡继文, 等. 中国专利, CN104492283A,2015.<br />
81	张捍民, 李海军, 杨凤林. 中国专利, CN103212309A, 2013.<br />
82	徐佳, 李明明, 冯晨晨, 等. 中国专利, CN104001434A, 2014.<br />
83	Mulder M.<i>Basic principles of membrane technology. 2nd ed, </i>Kluwer Academic Publishers, US, 1998.<br />
84	Xiao P P, Nghiem L D, Yin Y, et al. <i>Journal of Membrane Science</i>, 2015, 481, 106.<br />
85	Wang Y Q, Ou R W, Wang H T, et al. <i>Journal of Membrane Science</i>, 2015, 475, 281.<br />
86	Zhao X Z, Li J, Liu C K. <i>Desalination</i>, 2017, 408, 102.<br />
87	Hu L L, Wang D, Wang M.<i>Membrane Science and Technology</i>, 2017, 37(2), 19(in Chinese).<br />
	胡乐乐, 王铎, 汪锰. 膜科学与技术, 2017, 37(2), 19.<br />
88	Liang H Q, Hung W S, Yu H H, et al. <i>Journal of Membrane Science</i>, 2017, 529, 47.<br />
89	胡继文, 姜婷婷, 靳焘, 等. 中国专利, CN104524992A. 2015.<br />
90	Sukipaneenit P, Chung T S.<i>Environment Science and Technology</i>, 2012, (46), 7358.<br />
91	Luo L, Wang P, Zhang S, et al.<i>Journal of Membrane Science</i>, 2014, 461, 28.<br />
92	Wang K Y, Chung T S, Qin J J.<i>Journal of Membrane Science</i>, 2007, 300, 6.<br />
93	Fu F J, Zhang S, Sun S P, et al. <i>Journal of Membrane Science</i>, 2013, 443, 144.<br />
94	Yu H Y, Kang Y, Liu Y L, et al. <i>Journal of Membrane Science</i> 2014, 449, 50.<br />
95	Gary G T, Mccutcheon J R, Elimelech M. <i>Desalination</i>, 2006, 197, 1.<br />
96	Song X J, Wang L, Tang C Y, et al.<i>Desalination</i>, 2015, 369, 1.<br />
97	Nguyen A, Zou L, Priest C.<i>Journal of Membrane Scienc</i>e, 2014, 454, 264.<br />
98	Zhang S, Wang K Y, Chung T S, et al.<i>Journal of Membrane Science</i>, 2010, 360, 522.<br />
99	Yasuda H, Lamaze C E. <i>Journal of Membrane Science</i>, 1971, 5, 111.<br />
10	0 Madsen H T, Bajraktari N B, Claus H N, et al.<i>Journal of Membrane Science</i>, 2015, 476, 469.<br />
	1 Guo H, Yao Z K, Wang J Q, et al.<i>Journal of Membrane Science</i>, 2018, 551, 234.<br />
	2 Wang J, Xiao T T, Bao R Y, et al.<i>Process Safety and Environmental Protection</i>, 2018, 116, 632.<br />
	3 Xu W X, Ge Q C.<i>Journal of Membrane Science</i>, 2018, 555, 507.