| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Research Progress in Toughening Epoxy Resin Matrix by Insitu Technique |
| WEI Bo1, ZHOU Jintang1,2,3, YAO Zhengjun1,2,3, QIAN Yi1, QIAN Kun1
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1 College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106;
2 Key Laboratory of Materials Preparation and Protection for Harsh Environment, Ministry of Industry and Information Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106;
3 Jiangsu Key Laboratory of Advanced Metallic Materials, Nanjing 211189 |
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Abstract ince the invention of epoxy resin in the early 20th century, due to its great properties in adhesion, machinability and chemical resistance, the epoxy resin is widely used in coating, packaging, electronic products manufacturing and other industries. In recent years, people use epoxy resin as infiltration matrix in the aerospace, arms equipment and many other national frontier technology areas and has achieved lots of research production. When people use different new resin moulding transfer techniques to prepare and process composites with epoxy resin matrix, it is easy to make the final products have some advantages like small shrinkage, uniform integrity and excellent corrosion resistance, and make the materials meet requirements for electrical and mechanical properties at the same time. Up to now, epoxy resin is still in dominant position in aviation industry.
In order to promote the application of aviation industry, countries around the world have put forward higher requirements for epoxy resin, and the related advanced composite material preparation technology has been constantly enriched and improved. Epoxy resin forms a threedimensional network structure in curing process. In one hand, it improves the physical strength and hardness of the materials significantly. In the other hand, high crosslinking density also makes materials brittle and easy to crack. Therefore, it has always been the focus of research in the field of aeronautical composites about how to improve toughness of epoxy resin. Researchers have made great achievements after attempting in toughening epoxy resin for many years. Various toughening schemes and mechanisms have been established successively, which expands the application of epoxy resin greatly.
Most of the mature schemes for toughening epoxy resin belong to the category of insitu toughening at present. A new phase can be formed by adding reinforcing phase into the epoxy resin polyphase system, the uniform spatial distribution of different phases in the infiltrating matrix will improves toughness as the result. Some of the most effective toughening schemes are: (i) toughening epoxy resin by adding rubber particles, thermotropic liquid crystal polymer, hyperbranched polymer, coreshell polymer and so on; (ii) preparing a interpenetrating/semiinterpenetrating polymer networks with epoxy resin and another phase to toughen through predesign; (iii) adding nanoparticles with special functions to toughen epoxy resin matrix. The research on toughening modification of epoxy resin has important theoretical significance and practical value in general.
In this paper, the development of epoxy resin was briefly reviewed through two aspects: the mature macroscopic system and the rapid development of nanomodifiers in recent 30 years. Some insitu toughening technologies with great effect were described in detail, and enumerate the important results published in recent years to support. The paper also evaluated the advantages and disadvantages of different technologies objectively. At the end of this paper, the problems faced by the toughening technology of epoxy resin and the future development direction are analyzed to provide reference for the preparation of light and high performance epoxy resin composites.
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Published: 23 July 2019
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| Fund:This work was financially supported by the National Natural Science Foundation of China (51702158), the Fundamental Research Funds for the Central Universities (NS2017036), the Open Fund of Key Laboratory of Materials Preparation and Protection for Harsh Environment (Nanjing University of Aeronautics and Astronautics), Ministry of Industry and Information Technology (56XCA18159-3). |
About author:: Bo Wei received his B.E degree in Polymer materials and engineering from Nantong university in 2017. He is studying for a master's degree in chemistry at Nanjing University of Aeronautics and Astronautics at present. His research direction is the preparation of aerospace composite materials and the research of absorbing materials, and a paper has been published in Guangzhou Chemistry.
Jintang Zhou received his B.E., M.S., and Ph.D. degrees in material processing from Nanjing University of Aeronautics and Astronautics in 2005, 2010 and 2014, respectively. He is an associate professor and master tutor of Material Science and Technology College of Nanjing University of Aeronautics and Astronautics. His major research interest is structure/function integrated composite material. In recent years, he has achieved more than 20 authorized invention patents, and published more than 40 theses in some authorative journals, which are included in SCI and EI.
Zhengjun Yao received his B.E. degree from Southeast University in 1990, and received his M.S. degree from Xi'an Jiaotong University in 1993, then he received his Ph.D. degree from Nanjing University of Aeronautics and Astronautics and worked there till now. He is a professor, doctoral supervisor and the dean of material science and technology college of Nanjing University of Aeronautics and Astronautics at present. He is an expert in key consulting research projects team of the Chinese Academy of Engineering, the standing director of Jiangsu Institute of Compo sites, vice president of the Jiangsu Institute of Metals, the director of the Academic Committee of New Metal Materials of Jiangsu Institute of Metals, the deputy director of Heat Treatment and Surface Modification Engineering Technology Research Center of Jiangsu Province, a technical expert in strategic alliance of highperformance alloy industry in Jiangsu Province and vice chairman of Materials Engineering Committee of the Jiangsu Institute of Mechanical Engineering. His research interests include new metal materials and surface engineering and polymer composite materials. He has published more than 60 theses in some authorative journals included in SCI as the first author or corresponding author. |
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2019, Vol. 33 
