| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Research Progress in Optimizations of Polymer-matrix Membranes Using Two-dimensional Graphene-based Nanomaterials |
| XIE Quanling1, SHAO Wenyao2, MA Hanjun1,2, LIU Chenran1,2,HONG Zhuan1,3
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1 Third Institute of Oceanography, Ministry of Natural Resources, Xiamen 361005
2 College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
3 Fujian Collaborative Innovation Center for Exploitation and Utilization of Marine Biological Resources, Xiamen 361005 |
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Abstract To date, polymer membranes still encounter several challenges including the trade-off effect between permeability and selectivity, low resis-tance to fouling and chemical stability. Organic-inorganic hybrid membranes can make use of the advantages of organic materials and inorganic materials. In recent years, the rapid development of nanomaterials plays an important role in promoting the development of new composite membranes. Especially, the application of two-dimensional graphene nanomaterials has attracted more and more attentions.
However, graphene has high chemical stability, inert surface, weak interaction with other media, and strong van der Waals force between graphene nanosheets, which is easy to aggregate and difficult to disperse in water and solvents, seriously hindering its application in polymer membrane materials. Graphene oxide (GO) introduces a large number of oxygen-containing polar groups on its surface or edge, which alleviates the strong interaction between nanosheets. Therefore, GO demonstrates good dispersibility in water and polar solvents. A large number of oxygen-containing groups also provide rich reaction sites for preparing modified graphene. In addition, GO has the advantages of large-scale production and low cost, making GO widely used in polymer membrane materials.
Popular polymer membrane materials such as polyvinylidene fluoride, polysulfone and polyethersulfone were individually blended with GO, modified GO, or composite nanomaterials to prepare mixed matrix membranes via immersion precipitation phase inversion. Because the hydrophilicity, pore structure and surface roughness were improved effectively, the mixed matrix membranes showed the enhanced permeability and antifouling property, and even presented new functions such as antibacterial. An appropriate amount of GO or modified GO was introduced into the ultrathin active layer or porous sublayer of polyamide thin-film composite membranes. The permeaselectivity, antifouling and chlorine resistance of the nanocomposite membranes were improved due to the enhanced hydrophilicity and charge property of active layer and the optimal structure of active layer. In addition, high-flux GO laminated membranes can be fabricated by layer-by-layer assembly using non-covalent bond interactions such as electrostatic, hydrogen bonding, van der Waals force, or covalent bonding between GO active sites and crosslinking agent.
This review offers the research progress with respect to the application of two-dimensional graphene nanomaterials to improve the structure and properties of polymer membranes based on the methods of physical blending, interfacial polymerization and layer-by-layer assembly. In addition, the challenges and prospects of industrial applications of two-dimensional graphene-based nanomaterials in polymer membranes are prospected.
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Published: 23 July 2019
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| Fund:This work was financially supported by Xiamen Science and Technology Committee (3502Z20172008 ), the Scientific Research Foundation of Third Institute of Oceanography, SOA (2016036), Xiamen Southern Oceanographic Center (16PFW008SF15), Construction of Public Service Platform for Research and Test of Marine Pilot Technology (Bhsfs009), the Fundamental Research Funds for the Central Universities (20720170027). |
About author:: Quanling Xie, Ph. D, senior engineer. Research inte rests include R & D of membrane separation technology and membrane material, separation and purification technologies of natural products, pilot technology and engineering technology from laboratory into industrial production. Presided or participated in more than 10 research projects. Applied for 7 invention patents and 4 patents authorized. More than 20 papers have been published.
Wenyao Shao, Engineer, College of Chemistry and Chemical Engineering, Xiamen University. Mainly engaged in biochemical separation research, including preparation and application of membrane materials, foam separation technology. In recent years, he has chaired a number of projects in the field of biochemical separation, including the National Fund, the Youth Research Project of Fujian Province, and the Science and Technology Plan Project of Xiamen City, and published many articles in the field of biochemical separation. |
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2019, Vol. 33 
