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材料导报  2021, Vol. 35 Issue (6): 6060-6064    https://doi.org/10.11896/cldb.19120090
  无机非金属及其复合材料 |
玻璃粉对聚硅氮烷陶瓷涂层厚度及孔隙的影响
杨小军1, 池作和2, 王进卿2, 潜培豪2, 王广鑫2, 王杰2
1 衢州学院机械工程学院,衢州 324000
2 中国计量大学计量测试工程学院,杭州 310018
Effect of Glass Powder on the Thickness and Porosity of Polysilazane Ceramic Coating
YANG Xiaojun1, CHI Zuohe2, WANG Jinqing2, QIAN Peihao2, WANG Guangxin2, WANG Jie2
1 College of Mechanical Engineering, Quzhou College, Quzhou 324000, China
2 College of Metrology and Measurement Engineering, China Jiliang University, Hangzhou 310018, China
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摘要 为研究玻璃粉对聚硅氮烷陶瓷涂层结构的影响,采用热重、傅里叶红外光谱等方法对聚硅氮烷及聚硅氮烷/玻璃粉混合物的热解转化过程进行研究,结果表明,添加玻璃粉前后样品的热解趋势基本一致。聚硅氮烷在整个热解过程中均会释放出气体,其中在500 ℃以下时发生转氨作用析出氨气,在500~700 ℃时主要析出甲烷。利用提拉涂膜法在TP 347基材上制备玻璃/陶瓷复合涂层,并利用扫描电子显微镜对其微观形貌进行表征,结果表明玻璃粉能显著提高涂层临界厚度。由于涂层在烧结过程中会析出大量气体,为了防止复合涂层在烧结后形成较大的孔隙,可在基材许用温度下尽量提高烧结温度。
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杨小军
池作和
王进卿
潜培豪
王广鑫
王杰
关键词:  涂层  聚硅氮烷  热解  临界厚度  孔隙    
Abstract: In order to study the effect of glass powder on the structure of polysilazane ceramic coating, the pyrolysis processes of polysilazane and polysilazane/glass powder mixture were studied by TGA and FTIR. The results show that the pyrolysis trend of the samples before and after adding glass powder is basically the same. In the whole pyrolysis process, the polysilazane will release gas, in which ammonia will be produced when the temperature is below 500 ℃ and methane will be mainly released at 500—700 ℃. Glass/ceramic composite coating was prepared on TP 347 substrate by dip coating, and its micro morphology was characterized by SEM. The results show that glass powder can significantly improve the critical thickness of the coating. In order to prevent the composite coating from forming large pores after sintering, the sintering temperature can be increased as high as possible under the allowable substrate temperature.
Key words:  coating    polysilazane    pyrolysis    critical thickness    pore
               出版日期:  2021-03-25      发布日期:  2021-03-23
ZTFLH:  TQ630  
基金资助: 浙江省自然科学基金(LQ20E060017)
通讯作者:  chizh@cjlu.edu.cn   
作者简介:  杨小军,高级工程师,1989年毕业于郑州大学,现任职于衢州学院机械工程学院,主要从事锅炉防腐涂层的研究、生物质发电技术研究及相关教学工作。获得国家科技部创新基金、浙江省科技厅公益项目及多项专利。
池作和,教授,1987年硕士毕业于西安交通大学热能工程专业,1996年博士毕业于浙江大学工程热物理专业。现为中国计量大学教授,能源工程研究所所长。主要从事大型电站锅炉低污染燃烧、SNCR脱硝、锅炉防腐涂层、工程气固多相流动、生物质气化和液化等方面的教学科研工作。发表论文25篇,著作6部,发明8项。
引用本文:    
杨小军, 池作和, 王进卿, 潜培豪, 王广鑫, 王杰. 玻璃粉对聚硅氮烷陶瓷涂层厚度及孔隙的影响[J]. 材料导报, 2021, 35(6): 6060-6064.
YANG Xiaojun, CHI Zuohe, WANG Jinqing, QIAN Peihao, WANG Guangxin, WANG Jie. Effect of Glass Powder on the Thickness and Porosity of Polysilazane Ceramic Coating. Materials Reports, 2021, 35(6): 6060-6064.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19120090  或          http://www.mater-rep.com/CN/Y2021/V35/I6/6060
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