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材料导报  2020, Vol. 34 Issue (Z2): 338-343    
  金属与金属基复合材料 |
Au-Pt-Ni三元催化剂体系纳米相图的研究进展
胡洁琼, 谢明, 陈永泰, 杨有才, 方继恒, 范小通, 李爱坤
昆明贵金属研究所,稀贵金属综合利用新技术国家重点实验室,昆明 650106
Research Progress on the Nanophase Diagram of Au-Pt-Ni Catalyst System
HU Jieqiong, XIE Ming, CHEN Yongtai, YANG Youcai, FANG Jiheng, FAN Xiaotong, LI Aikun
State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China
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摘要 Au-Pt-Ni体系在燃料电池催化剂领域具有较强的应用背景,体系纳米相图的研究及建立,将加深对纳米催化剂合成和稳定性以及纳米尺度的不同组元间相平衡关系的理解,并指导探索多金属间协同作用的纳米催化剂形成机理,为直接醇类燃料电池用新型贵金属合金纳米催化剂的设计与开发提供理论指导。目前关于纳米相图的研究还很有限,限制了兼具高活性、稳定性、抗中毒和廉价的新型贵金属合金催化剂的设计与开发。本文总结了Au-Pt-Ni体系块体和纳米相图的国内外研究进展,并对体系的热力学参数进行了整理与评估。
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胡洁琼
谢明
陈永泰
杨有才
方继恒
范小通
李爱坤
关键词:  Au-Pt-Ni体系  纳米相图  热力学参数  直接甲醇燃料电池  铂基催化剂  贵金属合金    
Abstract: Au-Pt-Ni system has a strong application background as a fuel cell catalyst. The research on the establishment of nanophase diagram of the Au-Pt-Ni system will provide deeper understanding of the synthesis procedure and stability pattern of the nanocatalyst, along with the diagram of phase equilibrium between the different components at nanoscale. Meanwhile, the synergistic effect of multi-metals on the formation mechanism of nanocatalyst will be illuminated, so as to provide the theoretical insight for design and development of the new types of precious metal based nanocatalyst for direct alcohol fuel cells. However, the research on nanophase diagram is still limited, which limits the design and development of new precious metal alloy catalysts with high activity, stability, anti poisoning and low cost. This manuscript summarizes the research progress of bulk and nanophase diagram of the Au-Pt-Ni system at home and abroad and evaluates the collected thermodynamic parameters of the system, in order to make better use of new types of precious metal based nanocatalyst for direct alcohol fuel cells.
Key words:  Au-Pt-Ni system    nanophase diagram    thermodynamic parameters    direct methanol fuel cell    platinum based catalyst    precious metal alloy
               出版日期:  2020-11-25      发布日期:  2021-01-08
ZTFLH:  TB33  
基金资助: 国家自然科学基金委地区基金(51961016);云南省重大科技专项(2019ZE001-1;202002AB080001-1);国家重点研发计划项目(2017YFB0305700);国家自然科学基金云南联合基金(U1602271;U1602275);云南省面上基金项目(2018FB088)
通讯作者:  joanr8210@163.com   
作者简介:  胡洁琼,高级工程师,2012年5月硕士毕业于昆明贵金属研究所材料学专业,主要研究方向是贵金属合金相图及热力学数据库的构建。以第一作者累计发表研究论文20余篇,申请和参与申请专利19件,以第一发明人授权专利1件,参与制定国军标3件,获得省部级奖励3项,承担和参与国家及省部级项目10项,其中主持和承担的项目有3项。谢明,博士研究生导师,研究员。获国务院政府“特殊津贴”、云南省“云岭学者”等称号。主持和参与完成国家“八五”科技攻关、863计划、国家科技支撑计划、国家基金重点项目(NSFC-云南联合基金)、国家重点军工、工信部强基工程、2017年国家重点研发计划等重大科技项目50余项。荣获国家、省部级科技进步奖20余项(其中一等奖3项),荣获云南省科技进步科技创新团队一等奖1项;获得国家授权发明专利40余件,在国内外有影响的学术刊物和会议上发表学术论文200余篇,其中被SCI、EI收录80余篇;编写国家军工、国家标准和企业标准10余项,参与撰写《粉末冶金手册》《材料大百科全书》《电工合金产品应用手册》等。
引用本文:    
胡洁琼, 谢明, 陈永泰, 杨有才, 方继恒, 范小通, 李爱坤. Au-Pt-Ni三元催化剂体系纳米相图的研究进展[J]. 材料导报, 2020, 34(Z2): 338-343.
HU Jieqiong, XIE Ming, CHEN Yongtai, YANG Youcai, FANG Jiheng, FAN Xiaotong, LI Aikun. Research Progress on the Nanophase Diagram of Au-Pt-Ni Catalyst System. Materials Reports, 2020, 34(Z2): 338-343.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2020/V34/IZ2/338
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