Preparation of Metal Spinel Oxides for Photocatalytic Degradation of Organic Pollutants:a Review
SUN Yujie1, LIU Yuqin1, XU Fen2, SUN Lixian2
1 School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, China 2 Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials, School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China
Abstract: Most organic dyes are difficult to be photo-degraded due to their light stability. And organic dyes have been considered as an important source of water pollution now. Therefore, it is imminent to use photocatalytic technology to solve the problem of water pollution. Fortunately, metal spinel oxides semiconductor materials have been demonstrated to be an effective catalyst for the degradation of organic pollutants by using sunlight. The spinel-type metal oxides have the characteristics of narrow band gap and absorption of visible light, and can generate electrons and holes under the irradiation of light to realize photocatalytic degradation of the organic dyes. How to regulate the photocatalytic performance of metal spinel oxides is the focus of current international and domestic research. Numerous studies have shown that the main factors affecting their catalytic performances include the following three aspects: i. Preparation method. Various preparation methods, such as heat treatment (including thermal decomposition), hydrothermal-solvent heat, sol-gel, microwave method, self-combustion method, coprecipitation method, solid state synthesis method, electrospinning method, etc. Diffe-rent preparation methods can affect the morphology, surface area, particle size and band gap of the prepared materials, thus affecting the photocatalytic properties of the materials. For example, the surface area of ZnAl2O4 prepared by coprecipitation method and microwave-hydrothermal method was 94.4 m2/g and 279.7 m2/g, respectively;the forbidden band width of spinel NiFe2O4 prepared by using metal nitrate and metal chloride corresponded to 2.7 eV, 1.6—1.8 eV. ⅱ.Doping the third metal. For spinel-type metal oxides with a wider band gap, the forbidden band width can be reduced by doping the third me-tal. For example, the doping of metal Mg can reduce the band gap of CoFe2O4 from 2.4 eV to 1.8 eV, and the doping of Ce3+ reduces the band gap of ZnAl2O4 from 3.8 eV to 2.8 eV. The doping of a small amount of Bi makes the band gap of CoFe2O4 drops from 1.4 eV to 1.3 eV. ⅲ.Effective separation of photoinduced electrons and holes. In order to improve the photocatalytic activity of the spinel photocatalyst, it can be realized by doping a conductive material (such as graphene) and a metal oxide with a suitable potential (such as ZnO). The photoinduced electrons and the holes can be effectively separated to reduce the recombination rate of electron-hole pairs and to improve the catalytic activity of the photocatalyst. There are many kinds of reported spinel-type metal oxides so far. This review classifies spinel-type metal oxides according to their metal acids. The preparation of spinel-type ferrites and aluminates, and the research progress of performance and mechanism of photocatalytic degradation of organic dyes are analyzed and summarized respectively, and the future development direction has also been prospected. It is expected that this review will play an important role in the development of a series of novel spinel photocatalysts with excellent catalytic performances.
作者简介: 孙宇杰,目前就读于中国地质大学(北京)材料科学与工程学院本科。在刘玉芹副教授的指导下,已完成了一项“硅藻土负载CaFe2O4的制备及其光催化性能测试”的大学生创新项目,并申请了一项发明专利。 徐芬,博士,桂林电子科技大学教授、博士研究生导师。1986年在湖南大学获理学学士学位,1989年在湖南大学获理学硕士学位,2005年在中国科学院大连化学物理研究所获理学博士学位。1995—2001先后在德国和日本进行学习及合作研究。目前,主要从事先进能源材料研究。近年来发表论文100余篇,获批发明专利6项,省部级成果奖4项。 孙立贤,博士,桂林电子科技大学二级教授、博士研究生导师。广西优秀八桂学者,广西优秀专家,中国科学院优秀百人计划、英国皇家化学会会士、德国洪堡学者(AvH fellow)、日本产业技术(NEDO)研究员、全国优秀科技工作者,享受国务院政府特殊津贴, 入选2014—2018 Else-vier高被引学者。1994年于湖南大学获理学博士学位,1995—2001先后在德国耶拿大学(洪堡学者)和日本产业技术综合研究所(客座教授)合作研究;2001—2012年在中国科学院大连化学物理研究所工作,任材料热化学课题组组长;2012年到桂林电子科技大学工作,先后任院长、重点实验室主任等。Journal of Thermal Analysis ＆ Calorimetry副主编,The Journal of Chemical Thermodynamics等期刊编委;中国仪表功能材料学会储能与动力电池专业委员会副主任等。目前,主要从事能源材料、热化学与传感器研究。近年来发表SCI论文400余篇,获批发明专利25项,获省部级成果奖8项。
引用本文:
孙宇杰, 刘玉芹, 徐芬, 孙立贤. 尖晶石型金属氧化物的制备及光催化有机污染物降解:综述[J]. 材料导报, 2020, 34(15): 15021-15032.
SUN Yujie, LIU Yuqin, XU Fen, SUN Lixian. Preparation of Metal Spinel Oxides for Photocatalytic Degradation of Organic Pollutants:a Review. Materials Reports, 2020, 34(15): 15021-15032.
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2020, Vol. 34 
