Please wait a minute...
《材料导报》期刊社  2018, Vol. 32 Issue (4): 559-562    https://doi.org/10.11896/j.issn.1005-023X.2018.04.010
  材料研究 |
低摩擦长寿命类富勒烯碳基薄膜的制备及其摩擦学特性
吴坤尧1, 孟志新1, 李兆1, 丁旭1, 张斌2, 张俊彦2
1 西安航空学院材料工程学院,西安 710077;
2 中国科学院兰州化学物理研究所,先进润滑与防护材料研究发展中心,兰州 730000
Synthesis of Low-friction Long-life Fullerene-like Carbon Film and Its Frictional Characteristics
WU Kunyao1, MENG Zhixin1, LI Zhao1, DING Xu1, ZHANG Bin2, ZHANG Junyan2
1 School of Materials Engineering, Xi'an Aeronautical University, Xi'an 710077;
2 R&D Center of Lubricating and Protecting Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
下载:  全 文 ( PDF ) ( 2002KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 以甲烷(CH4)为前躯体,利用等离子体增强化学气相沉积(PECVD)技术,在单晶硅<n-100>基底表面制备含氢类富勒烯碳基薄膜(FL-C∶H)。 采用高分辨透射电镜(HRTEM)、拉曼光谱仪(LABRAM)和多功能X射线光电子能谱仪(XPS)对薄膜及磨屑结构进行表征;利用摩擦磨损试验机、扫描电子显微镜(SEM)分别测试薄膜的摩擦学性能和观察磨屑的微观形貌。结果表明,所制备的碳基薄膜具有类富勒烯纳米结构,且磨屑的显微结构亦呈现类富勒烯结构的特征。同时,类富勒烯纳米结构的碳基薄膜具有优异的摩擦学性能,与传统非晶类金刚石薄膜相比,其磨损寿命显著提高,在载荷为30 N、摩擦速率为0.1 m/s下薄膜的磨损寿命为3 538.2 m,摩擦系数低至0.012左右,显示出长寿命低摩擦特性。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
吴坤尧
孟志新
李兆
丁旭
张斌
张俊彦
关键词:  类富勒烯碳基薄膜  长寿命  低摩擦    
Abstract: Fullerene-like hydrogenated carbon films (FL-C∶H) were grown by pulse plasma enhanced chemical vapor deposition (PECVD) technique on silicon (n-100) substrate using CH4 as feed stock at ambient temperature. The microstructure of the films and wear debris were characterized by high resolution transmission electron microscopy (HRTEM), Raman spectra(LABRAM) and X-ray photoelectron spectra (XPS). The tribological behaviors were investigated by friction-abrasion testing machine and scanning electron microscope. It was found that the films could be described as fullerene-like nanostructures. The tribological properties of the films were improved significantly. In addition, the FL-C∶H films demonstrate long wear life about 3 538.2 m and ultra-low friction coefficient (0.012) under the 30 N contact load and the 0.1 m/s friction velocity in contrast with the typical hydrogenated carbon films (α-C∶H).
Key words:  fullerene-like carbon film    long-life    low-friction
               出版日期:  2018-02-25      发布日期:  2018-02-25
ZTFLH:  TG174.444  
基金资助: 国家自然科学基金(51275508); 西安航空学院大创项目(DCX2017075)
作者简介:  吴坤尧:男,1988年生,硕士,讲师,研究方向为纳米润滑材料 E-mail:wky_frank@126.com
引用本文:    
吴坤尧, 孟志新, 李兆, 丁旭, 张斌, 张俊彦. 低摩擦长寿命类富勒烯碳基薄膜的制备及其摩擦学特性[J]. 《材料导报》期刊社, 2018, 32(4): 559-562.
WU Kunyao, MENG Zhixin, LI Zhao, DING Xu, ZHANG Bin, ZHANG Junyan. Synthesis of Low-friction Long-life Fullerene-like Carbon Film and Its Frictional Characteristics. Materials Reports, 2018, 32(4): 559-562.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.04.010  或          http://www.mater-rep.com/CN/Y2018/V32/I4/559
1 Robertson J. Diamond-like amorphous carbon[J].Materials Science and Engineering:R:Reports,2002,37(4):129.
2 Nalwa H S. Handbook of thin film materials[M].New York:Academic Press,2002:12.
3 Lettington A H. Applications of diamond-like carbon thin films[J].Carbon,1998,36(5):555.
4 Grill A. Diamond-like carbon: State of the art[J].Diamond and Related Materials,1999,8(2):428.
5 Sj?str?m H, Stafstr?m S, Boman M, et al. Superhard and elastic carbon nitride thin films having fullerenelike microstructure[J].Physical Review Letters,1995,75(7):1336.
6 Amaratunga G A J, Chhowalla M, Kiely C J, et al. Hard elastic carbon thin films from linking of carbon nanoparticles[J].Nature,1996,383(6598):321.
7 Chhowalla M, Munindradasa A I, Amaratunga G A J. Fullerene and nanoparticle formation in carbon cathodic arc deposition[J].Applied Physics Letters,1997,70(24):3233.
8 Alexandrou I, Scheibe H J, Kiely C J, et al. Carbon films with an sp2 network structure[J].Physical Review B:Condensed Matter,1999,60(15):10903.
9 Hultman L, Stafstr?m S, Czigány Z, et al. Cross-linked nano-onions of carbon nitride in the solid phase: Existence of a novel C48N12 aza-fullerene[J].Physical Review Letters,2001,87(22):225503.
10 Erdemir A, Meletis E. A study of the wear mechanism of diamond-like carbon films[J].Surface and Coatings Technology,1996,82(1):48.
11 Donnet C, Le Mogne T, Ponsonnet L, et al. The respective role of oxygen and water vapor on the tribology of hydrogenated diamond-like carbon coatings[J].Tribology Letters,1998,4(3-4):259.
12 Wang C, Yang S, Wang Q, et al. Super-low friction and super-elastic hydrogenated carbon films originated from a unique fullerene-like nanostructure[J].Nanotechnology,2008,19(22):225709.
13 Neidhardt J, Hultman L, Czigány Z. Correlated high resolution transmission electron microscopy and X-ray photoelectron spectroscopy studies of structured CNx(014 Blank V D, Buga S G, Dubitsky G A, et al. High-pressure polyme-rized phases of C60[J].Carbon,1998,36(4):319.
15 Guo J, Liu G, Wang X, et al. High-pressure Raman spectroscopy of carbon onions and nanocapsules[J].Applied Physics Letters,2009,95(5):051920.
16 Blank V, Denisov V, Kirichenko A, et al. High pressure transformation of single-crystal graphite to form molecular carbononions[J].Nanotechnology,2007,18(34):345601.
17 Díaz J, Paolicelli G, Ferrer S, et al. Separation of the sp3 and sp2 components in the C1s photoemission spectra of amorphous carbon films[J].Physical Review B,1996,54(11):8064.
18 Ronkainon H, Likonen J, Koskinen J, et al. Effect of tribofilm formation on the tribological performance of hydrogenated carbon coa-tings[J].Surface and Coatings Technology,1996,79(1-3):87.
19 Voevodin A A, Jones J G, Back T C, et al. Comparative study of wear-resistant DLC and fullerene-like CNx coatings produced by pulsed laser and filtered cathodic arc depositions[J].Surface and Coatings Technology,2005,197(1):116.
20 Ji L, Li H, Zhao F, et al. Effects of pulse bias duty cycle on fullerenelike nanostructure and mechanical properties of hydrogenated carbon films prepared by plasma enhanced chemical vapor deposition method[J].Journal of Applied Physics,2009,105(10):106.
21 Zhang W, AkihiroT , Koichiro W, et al. Mechanical and tribological properties of Ar incorporated diamond-like carbon films[J].Thin Solid Films,2002,416(1):145.
22 Filik J, May P, Pearce S, et al. XPS and laser Raman analysis of hydrogenated amorphous carbon films[J].Diamond and Related Materials,2003,12(3):974.
23 Singha A, Ghosh A, Roy A,et al. Quantitative analysis of hydrogenated diamondlike carbon films by visible Raman spectroscopy[J].Journal of Applied Physics,2006,100(4):044910.
[1] 杨鸿泰, 代明江, 李洪, 林松盛, 侯慧君, 石倩, 韦春贝. Al含量对TiAlN涂层组织结构和性能的影响[J]. 材料导报, 2018, 32(20): 3573-3578.
[2] 杜伟, 石倩, 代明江, 易健宏, 林松盛, 侯惠君. 电弧离子镀NiCrAlY和NiCoCrAlYHfSi涂层抗高温氧化性能[J]. 《材料导报》期刊社, 2018, 32(13): 2267-2271.
[3] 唐明, 代明江, 韦春贝, 邱万奇, 林松盛, 侯惠君, 李洪. 基体偏压对AlCrSiN涂层结构及力学性能的影响[J]. 材料导报, 2018, 32(18): 3099-3103.
[1] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[2] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[3] Siyuan ZHOU,Jianfeng JIN,Lu WANG,Jingyi CAO,Peijun YANG. Multiscale Simulation of Geometric Effect on Onset Plasticity of Nano-scale Asperities[J]. Materials Reports, 2018, 32(2): 316 -321 .
[4] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[5] Ninghui LIANG,Peng YANG,Xinrong LIU,Yang ZHONG,Zheqi GUO. A Study on Dynamic Compressive Mechanical Properties of Multi-size Polypropylene Fiber Concrete Under High Strain Rate[J]. Materials Reports, 2018, 32(2): 288 -294 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] ZHOU Rui, LI Lulu, XIE Dong, ZHANG Jianguo, WU Mengli. A Determining Method of Constitutive Parameters for Metal Powder Compaction Based on Modified Drucker-Prager Cap Model[J]. Materials Reports, 2018, 32(6): 1020 -1025 .
[8] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[9] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[10] YUAN Xinjian, LI Ci, WANG Haodong, LIANG Xuebo, ZENG Dingding, XIE Chaojie. Effects of Micro-alloying of Chromium and Vanadium on Microstructure and Mechanical Properties of High Carbon Steel[J]. Materials Reports, 2017, 31(8): 76 -81 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed