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材料导报  2018, Vol. 32 Issue (22): 3845-3847    https://doi.org/10.11896/j.issn.1005-023X.2018.22.002
  无机非金属及其复合材料 |
SrI2∶Eu∶Cs晶体生长及闪烁性能
张鲁龄, 魏钦华, 秦来顺, 史宏声
中国计量大学材料科学与工程学院,杭州 310018
Crystal Growth and Scintillation Properties of SrI2∶Eu∶Cs
ZHANG Luling, WEI Qinhua, QIN Laishun, SHI Hongsheng
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018
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摘要 采用垂直布里奇曼法成功制备出尺寸为Φ25 mm×70 mm的SrI2∶Eu∶Cs晶体,经加工后封装得到尺寸为10 mm×10 mm×10 mm的透明单晶,这是迄今为止Eu2+和Cs+双掺杂的最大尺寸SrI2单晶,所用原料为国产原料。XRD测试结果表明,所得晶体为SrI2正交相,空间群为Pbca。荧光光谱显示晶体的发射峰和激发峰分别位于440 nm和419 nm,属于典型Eu2+的5d→4f跃迁发射。X射线激发发射光谱显示该晶体只有一个位于440 nm的发射峰,与荧光光谱的结果一致。采用单指数拟合后得到晶体在370 nm激发波长下的荧光寿命约为1.3 μs。在137Cs射线源激发下的γ能谱测试显示晶体的能量分辨率为5.5%,已基本满足实际使用的要求。
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张鲁龄
魏钦华
秦来顺
史宏声
关键词:  垂直布里奇曼法  SrI2∶Eu∶Cs  衰减时间  能量分辨率  闪烁晶体    
Abstract: Single crystals of SrI2∶Eu∶Cs with sizes up to Φ25 mm×70 mm were successfully grew in evacuated quartz ampoules via the Bridgman technique using the domestic raw materials. A transparent and crackless 10 mm×10 mm×10 mm SrI2∶Eu∶Cs single crystal was machined.The XRD results proved that the crystal was SrI2 orthogonal phase and the space group was Pbca. Fluorescence spectra showed that the emission and excitation peaks of the crystals were at 440 nm and 419 nm, respectively, ascribed to 5d→4f transition of Eu2+. The X-ray excited emission spectra showed that SrI2∶Eu∶Cs presented one peak at 440 nm. The decay time, under 370 nm excitation, was found to be about 1.3 μs. The energy resolutions was 5.5% under 137Cs gamma rays. This crystal already satisfies some application needs.
Key words:  vertical Bridgman method    SrI2∶Eu∶Cs    decay time    energy resolutions    scintillator
               出版日期:  2018-11-25      发布日期:  2018-12-21
ZTFLH:  O78  
基金资助: 国家自然科学基金(11575170;11605194)
通讯作者:  史宏声:通信作者,男,1975年生,博士,教授,硕士研究生导师,研究方向为闪烁晶体、大尺寸晶体生长 E-mail:shihongsheng@cjlu.edu.cn   
作者简介:  张鲁龄:男,1993年生,硕士研究生,研究方向为卤化物闪烁晶体 E-mail:jayu7879@126.com
引用本文:    
张鲁龄, 魏钦华, 秦来顺, 史宏声. SrI2∶Eu∶Cs晶体生长及闪烁性能[J]. 材料导报, 2018, 32(22): 3845-3847.
ZHANG Luling, WEI Qinhua, QIN Laishun, SHI Hongsheng. Crystal Growth and Scintillation Properties of SrI2∶Eu∶Cs. Materials Reports, 2018, 32(22): 3845-3847.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.22.002  或          http://www.mater-rep.com/CN/Y2018/V32/I22/3845
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