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材料导报  2020, Vol. 34 Issue (Z2): 63-66    
  无机非金属及其复合材料 |
碳纳米颗粒对碳纳米管复合材料电热-力学性能的影响
王效军1,2, 刘太奇1
1 北京石油化工学院航天材料研究所,北京 102617
2 北京化工大学材料科学与工程学院,北京 100029
Effect of Carbon Nanoparticles on Electrothermal-Mechanical Properties of Carbon Nanotubes Composites
WANG Xiaojun1,2, LIU Taiqi1
1 Institute of Aerospace Materials, Beijing Institute of Petrochemical Technology, Beijing 102617, China
2 College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
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摘要 以水性聚氨酯为基体,碳纳米管(CNT)为导电填料,制备了碳纳米管电热浆料,并使用纳米碳黑(CB)对其改性,研究了CB的添加量对浆料电热-力学性能的影响。实验结果表明,随着CNT含量的升高,未经CB改性的电热涂膜拉伸强度和断裂伸长率增大,电阻率下降;但当CNT含量达到19%时,在220 V电压下涂膜未出现表观发热现象。制备CNT含量为10%的电热浆料并使用CB改性后,其电热性能得到了很大的提高。对改性后的电热涂膜进行测试,SEM图像显示CB与CNT分布均匀并且CB包覆了CNT;力学性能测试显示,随着CB含量升高,电热涂膜的拉伸强度增大,断裂伸长率减小;电热性能测试显示CB含量为5%时,涂膜出现表观发热现象,当CB含量为7%时,220 V电压下涂膜发热温度达87.8 ℃。
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王效军
刘太奇
关键词:  碳纳米管  纳米碳黑  电热浆料  电热性能  力学性能    
Abstract: Apolyurethane based carbon nanotubes electro-thermal coatings were prepared by using carbon nanotubes (CNT) and polyurethane water solution. Nano carbon black (CB) was used as a modifier to investigate the effects of different CB loading on electrothermal-mechanical properties. The results show that, the tensile strength and elongation-at-break of the electrothermal coating films without CB modification increase and the resistivity decrease with increasing the content of CNT, however, the coating shows no temperature increasing, even the CNT content reaches to 19% under the condition of 220 V. The electrothermal properties of the electrothermal coating film has been greatly increased after introducing CB into the composites with the CNT in a content of 10%. The analytical results show that CB and CNT dispersed well in the composites. The tensile strength of the electrothermal coating films increase and elongation-at-break decrease with increasing the content of CB. The coating with a content of 5% CB shows an obviously temperature increasing, and the temperature reaches to 87.8 ℃ with a content of 7% CB under the condition of 220 V.
Key words:  carbon nanotubes    carbon nanoparticles    electro-thermal coatings    electro-thermal performance    mechanical performance
               出版日期:  2020-11-25      发布日期:  2021-01-08
ZTFLH:  TB34  
通讯作者:  liutaiqi@bipt.edu.cn   
作者简介:  王效军,毕业于青岛科技大学高分子材料工程专业,现为北京化工大学硕士研究生,在刘太奇教授指导下进行研究。目前主要研究方向为节能材料。刘太奇, 北京石油化工学院教授、博士研究生导师,研究中心主任,北京化工大学博导。毕业于北京理工大学(本科、硕士)与中国科学院长春应用化学研究所(博士)。主要从事纳米环境净化材料、航天材料及节能材料研究。主持和参与国家“863”子项目(主持)、国家“九五”规划、国家自然科学基金重点、国家攀登计划、航天某型号(主持)等多个科研项目。发表论文80余篇,其中SCI、EI收录60余篇,主编《纳米技术应用丛书》之《纳米空气净化技术》(化工出版社)。
引用本文:    
王效军, 刘太奇. 碳纳米颗粒对碳纳米管复合材料电热-力学性能的影响[J]. 材料导报, 2020, 34(Z2): 63-66.
WANG Xiaojun, LIU Taiqi. Effect of Carbon Nanoparticles on Electrothermal-Mechanical Properties of Carbon Nanotubes Composites. Materials Reports, 2020, 34(Z2): 63-66.
链接本文:  
http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2020/V34/IZ2/63
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