无卤素离子辅助合成纳米银线及其在柔性透明导电薄膜中的应用

材料导报

2019, Vol. 33

Issue (z1): 300-302

金属与金属基复合材料

无卤素离子辅助合成纳米银线及其在柔性透明导电薄膜中的应用

原禧敏, 杨宏伟, 李郁秀, 巢云秀, 李耀, 陈家林, 陈力

昆明贵金属研究所稀贵金属综合利用新技术国家重点实验室,昆明 650106

Synthesis of Silver Nanowires Without the Aid of Halogen Ion and Their Application in the Flexible Transparent Conductive Film

YUAN Ximin, YANG Hongwei, LI Yuxiu, CHAO Yunxiu, LI Yao, CHEN Jialin, CHEN Li

State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106

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摘要本研究未采用传统的卤素离子作为助剂,而直接以硝酸银、三水合硝酸铜和聚乙烯吡咯烷酮作为反应物,并对反应条件进行深入探索,最终成功合成出线径在200～300 nm,线长在10～120 μm,长径比在50～500范围内的银纳米线。其中,Cu²⁺的添加有助于银十面双晶结构的稳定,从而促进纳米银线的形成。采用该类型的银纳米线制成的透明导电电极展现出良好的透明度及导电性能,在柔性透明导电薄膜中具有较好的潜在应用价值。

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关键词: 银纳米线硝酸铜硝酸银聚乙烯吡咯烷酮透明导电薄膜

Abstract: In this work, silver nitrate, copper nitrate trihydrate and polyvinylpyrrolidone (PVP) were directly applied as the reactants but without the aid of halogen ion and the reaction conditions were explored in details. Eventually, silver nanowires with the diameter of 200—300 nm, the length of 10—120 μm, and the aspect ratio of 50—500 were successfully synthesized. The addition of Cu²⁺contributes to the stabilization of decahedral twin structure and the formation of silver nanowires.The transparent conductive electrode fabricated by using this type of silver nanowires exhibited favorable transparency and conductivity; indicating their potential applications in flexible transparent conductive film.

Key words: silver nanowires copper nitrate silver nitrate polyvinylpyrrolidone transparent conductive film

出版日期: 2019-05-25 发布日期: 2019-07-05

ZTFLH:

TM241

作者简介: 原禧敏,2017年7月毕业于辽宁工业大学大学,获得工程学士学位。于2017年9月至2020年7月在昆明贵金属研究所学习,主要从事纳米材料领域的研究。杨宏伟,昆明贵金属研究所,副研究员。2012年7月毕业于厦门大学,物理化学专业博士学位。同年加入昆明贵金属研究所工作至今,重点研究贵金属纳米材料的制备、表征以及应用研究。nanolab@ipm.com.cn

引用本文:

原禧敏, 杨宏伟, 李郁秀, 巢云秀, 李耀, 陈家林, 陈力. 无卤素离子辅助合成纳米银线及其在柔性透明导电薄膜中的应用[J]. 材料导报, 2019, 33(z1): 300-302.
YUAN Ximin, YANG Hongwei, LI Yuxiu, CHAO Yunxiu, LI Yao, CHEN Jialin, CHEN Li. Synthesis of Silver Nanowires Without the Aid of Halogen Ion and Their Application in the Flexible Transparent Conductive Film. Materials Reports, 2019, 33(z1): 300-302.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2019/V33/Iz1/300

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