热处理对Bi2O3-B2O3-SiO2凝胶玻璃粉体结构与性能的影响

doi:10.11896/j.issn.1005-023X.2018.22.029

材料导报

2018, Vol. 32

Issue (22): 4006-4010 https://doi.org/10.11896/j.issn.1005-023X.2018.22.029

中国材料大会——生态环境材料

热处理对Bi₂O₃-B₂O₃-SiO₂凝胶玻璃粉体结构与性能的影响

厉佩贤¹, 袁鸽成¹, 陆正华¹, 李倩¹, 乐迎锋¹, 吴其光²

1 广东工业大学材料与能源学院,广州 510006;
2 广东工业大学分析测试中心,广州 510006

Effect of Heat Treatment on Structure and Properties of Sol-Gel Bi₂O₃-B₂O₃-SiO₂ Glassy Powder

LI Peixian¹, YUAN Gecheng¹, LU Zhenghua¹, LI Qian¹,LE Yingfeng¹, WU Qiguang²

1 School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006 ;
2 Analysis and Test Center, Guangdong University of Technology, Guangzhou 510006

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摘要采用溶胶-凝胶法制备了一种Bi₂O₃-B₂O₃-SiO₂系玻璃粉体,在200 ℃、400 ℃、600 ℃和800 ℃温度下分别对凝胶玻璃粉体进行热处理,借助SEM、TEM、XRD、FT-IR、Raman、XPS、DSC、热膨胀仪及“纽扣”烧结实验分别测定了经不同温度热处理后玻璃粉体的结构与性能,分析了其结构变化对玻璃粉体转变温度T_g和烧结特性的影响。结果显示,在实验温度范围内,随热处理温度升高,Bi³⁺逐渐进入玻璃网络中,[BiO₆]八面体和[BiO₃]三角体、[BO₄]四面体和[BO₃]三角体分别与[SiO₄]四面体以顶角相连的方式构建玻璃网络结构。O1s和Bi4f的电子结合能逐渐增大,B1s的电子结合能减小,玻璃网络结构稳定性增强,导致玻璃转变温度T_g及玻璃膨胀软化点温度T_d升高、润湿性降低且热膨胀系数略有降低。经600 ℃热处理后,玻璃粉体具有较优的烧结性能,T_g、T_d分别约为485 ℃及542 ℃,热膨胀系数α约为7.067×10^-6/℃。

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关键词: 溶胶-凝胶热处理 Bi₂O₃-B₂O₃-SiO₂玻璃粉体结构性能

Abstract: The glassy powder of Bi₂O₃-B₂O₃-SiO₂ was prepared by sol-gel method. In order to study the effect of heat-treated temperature on structure and properties of the powder, it was heated at temperature of 200 ℃,400 ℃,600 ℃,800 ℃,respectively. The structure and properties of the glassy powder under various heat-treated temperature were tested by means of SEM, TEM, XRD, FT-IR, Raman, XPS, DSC, thermal dilatometer and ‘button-sintering’, respectively. The effect of the powder structure change on its transition temperature T_g and sintering properties was analyzed. The results show that Bi³⁺get into the network structure with the rising of heat-treated temperature,[BiO₆] octahedral and [BiO₃] triangle, [BO₄] tetrahedron and [BO₃] triangle connect with [SiO₄] tetrahedron separately in the way of vertex connecting to build the network structures. The O1s and Bi4f binding energies increase gradually while the B1s binding energies decrease which strengthen the stability of glass structure. All of these structure changes cause the increase of transition temperature T_g and softening temperature T_d, the decrease of wettability and slight increase of thermal expansion coefficient of the glass powder. The glass powder treated at 600 ℃has better sintering characteristics, the T_g, T_d is approximately 485 ℃and 542 ℃,respectively, and the thermal expansion coefficient is close to 7.067×10^-6/℃.

Key words: sol-gel heat-treating Bi₂O₃-B₂O₃-SiO₂ glass powder structure properties

出版日期: 2018-11-25 发布日期: 2018-12-21

ZTFLH:

TQ174

基金资助: 广东省自然科学基金(2006B14701003);广州市科技计划项目(2015110010034)

通讯作者: 袁鸽成:通信作者,男,1963年生,博士,教授,主要从事超细金属及玻璃陶瓷粉体材料及先进轻金属材料的研究 E-mail:gchyuan@gdut.edu.cn

作者简介: 厉佩贤:女,1994年生,硕士研究生,主要从事超细粉体材料制备及结构与性能研究 E-mail:lipeixianxx@163.com

引用本文:

厉佩贤, 袁鸽成, 陆正华, 李倩, 乐迎锋, 吴其光. 热处理对Bi₂O₃-B₂O₃-SiO₂凝胶玻璃粉体结构与性能的影响[J]. 材料导报, 2018, 32(22): 4006-4010.
LI Peixian, YUAN Gecheng, LU Zhenghua, LI Qian, LE Yingfeng, WU Qiguang. Effect of Heat Treatment on Structure and Properties of Sol-Gel Bi₂O₃-B₂O₃-SiO₂ Glassy Powder. Materials Reports, 2018, 32(22): 4006-4010.

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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.22.029 或 http://www.mater-rep.com/CN/Y2018/V32/I22/4006

1 Yu Xiaojun, Zhu Lihui, Huang Qingwei, et al. Effects of Bi₂O₃ on structure and properties of Al₂O₃-ZnO-Bi₂O₃-B₂O₃ low-melting glasses[J]. Electronic Components and Materials,2013,32(9):12(in Chinese).
于小军,朱丽慧,黄清伟,等. Bi₂O₃对Al₂O₃-ZnO-Bi₂O₃-B₂O₃低熔玻璃结构和性能的影响[J].电子元件与材料,2013,32(9):12.
2 He Feng, Deng Dawei, Wang Jun. Effect of Bi₂O₃ contents on sintering property of Bi₂O₃-ZnO-B₂O₃ system low-melting electronic sea-ling glass[J]. Journal of Wuhan University of Technology,2009,31(22):1(in Chinese).
何峰,邓大伟,王俊.Bi₂O₃对铋锌硼低熔封接玻璃烧结性能影响[J].武汉理工大学学报,2009,31(22):1.
3 Zhou Hongping, Zeng Renjie. Effects of CuO on structure and heat treatment of Bi₂O₃-B₂O₃-ZnO glasses[J]. Journal of Ceramics,2010,31(4):568(in Chinese).
周洪萍,曾人杰.CuO对ZnO-Bi₂O₃-B₂O₃系玻璃结构及热处理结果影响[J].陶瓷学报,2010,31(4):568.
4 Cheng Junwen,Chen Feifei,Dai Shixun, et al. Vitreous network formation and optical characteristics of glasses within Bi₂O₃-B₂O₃ binary system[J]. Journal of the Chinese Ceramic Society,2013,41(4):475(in Chinese).
成俊雯,陈飞飞,戴世勋,等. Bi₂O₃-B₂O₃二元系统玻璃的网络结构形成与光学性能研究[J].硅酸盐学报,2013,41(4):475.
5 Huang Yourong, Li Yaohui, Wang Jinzhen, et al. Network structures and characteristics of Bi₂O₃-ZnO-B₂O₃ ternary system glasses[J]. Journal of the Chinese Ceramic Society,2015,43(7):998(in Chinese).
黄幼榕,李要辉,王晋珍,等.Bi₂O₃-ZnO-B₂O₃三元系统玻璃结构与性能[J].硅酸盐学报,2015,43(7):998.
6 Shruti S, Salinas A J, Malavasi G, et al. Structural and in vitro study of cerium, gallium and zinc containing sol-gel bioactive glasses[J]. Journal of Materials Chemistry,2012,22(27):13698.
7 Chen J, Que W, Xing Y, et al. Molecular level-based bioactive glass-poly (caprolactone) hybrids monoliths with porous structure for bone tissue repair[J]. Ceramics International,2015,41(2):3330.
8 Gao Yuan, Hou Yonggai, Li Wenfeng, et al. Development of ZnO-B₂O₃-SiO₂ system glass prepared by sol-gel method[J]. Guangzhou Chemical Industry,2016,44(17):14(in Chinese).
高元,侯永改,李文凤,等.溶胶-凝胶法制备ZnO-B₂O₃-SiO₂系玻璃料的研究进展[J].广州化工,2016,44(17):14.
9 Ming Wang. Investigation of the structure evolution process in sol-gel derived CaO-B₂O₃-SiO₂ glass ceramics[J].Journal of Non-Crystalline Solids,2011,357:1160.
10 Zhu X, Mai C, Li M. Effects of B₂O₃ content variation on the Bi ions in Bi₂O₃-B₂O₃-SiO₂ glass structure[J]. Journal of Non-Crystalline Solids,2014,388:55.
11 Liu Junfang, Su Liangbi, Xu Jun. Near-infrared luminescence pro-perties of Bi₂O₃-SiO₂ glasses and glass ceramics[J]. Journal of Inorganic Materials,2014(8):859(in Chinese).
刘军芳,苏良碧,徐军.Bi₂O₃-SiO₂玻璃及玻璃陶瓷近红外发光性能的研究[J].无机材料学报.2014(8):859.
12 Fan H. Infrared, Raman and XPS spectroscopic studies of Bi₂O₃-B₂O₃-GeO₂ glasses[J]. Solid State Sciences,2010,12(4):541.
13 Deng D W. Study on structure and melt properties of Bi₂O₃-B₂O₃-ZnO low-melting lead-free sealing glass[D]. Wuhan:Wuhan University of Technology,2011(in Chinese).
邓大伟.Bi₂O₃-B₂O₃-ZnO系低熔点无铅封接玻璃结构与熔点性质研究[D].武汉:武汉理工大学,2011.
14 Ardelean I, Cora S. FTIR and Raman investigations of MnO-B₂O₃-Bi₂O₃[J]. Journal of Optoelectronics and Advanced Materials,2010,12(2):239.
15 Gao G J,Wang G N,Hu L.Effect of SiO₂ on thermal stability, optical properties and structural characteristic of Bi₂O₃-B₂O₃ binary glasses[J].Acta Photonica Sinica,2008(s1):50(in Chinese).
高国军,汪国年,胡丽.SiO₂对Bi₂O₃-B₂O₃玻璃体系光学、热学及结构的影响[J].光子学报,2008(s1):50.
16 Nesbitt H W, Bancroft G M, et al. Bridging, non-brifging free (O^2-) oxygen in Na₂O-SiO₂ glasses[J].Journal of Non-Crystalline Solids,2011,1(357):173.
17 Chang M. Study on structure and melt properties of Bi₂O₃-ZnO-B₂O₃ lead-free low-temperature sealing glass[D]. Beijing:China Construction Materials Science Research Institute,2014(in Chinese).
常明.Bi₂O₃-ZnO-B₂O₃低温无铅封接玻璃结构及性能研究[D].北京:中国建筑材料科学研究总院,2014.
18 Chen Danping, Jiang Xiongwei, Zhu Congshan. Study on the structure of Bi₂O₃-Li₂O glass[J]. Journal of Inorganic Materials,2002,17(2):202(in Chinese).
陈丹平,姜雄伟,朱从善.Bi₂O₃-Li₂O玻璃的结构研究[J].无机材料学报.2002,17(2):202.
19 Le Yingfeng,Yuan Gecheng,Li Qian, et al. Thermal properties of Bi₂O₃-SiO₂-B₂O₃-Zn O-Al₂O₃ glass powders prepared by sol-gel method[J]. China Powder Science and Technology,2017,23(1):85(in Chinese).
乐迎锋,袁鸽成,李倩,等.溶胶凝胶法制备Bi₂O₃-SiO₂-B₂O₃-ZnO-Al₂O₃系玻璃粉体的热性能[J].中国粉体技术,2017,23(1):85.
20 Ding Kanjunjie, Chen Nan. Preparation, structures, thermal pro-perties and sintering behaviors of B₂O₃-SiO₂-ZnO-BaO-Al₂O₃ glass[J]. Journal of Wuhan University of Technology(Materials Science Edition),2016,31(6):1323.

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