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《材料导报》期刊社  2017, Vol. 31 Issue (20): 119-123    https://doi.org/10.11896/j.issn.1005-023X.2017.020.025
  材料研究 |
抛光砖废渣复合发泡法制备闭孔泡沫陶瓷*
杨赞中1,2, 王涵1, 王永在3, 刘敏1, 丁琪1, 李成峰1, 乐红志1,2, 魏春城1,2
1 山东理工大学材料科学与工程学院,淄博 255049;
2 山东省陶瓷基复合材料示范工程技术研究中心,淄博 255049;
3 山东理工大学分析测试中心,淄博 255049
Preparation of Closed Pore Foamed Ceramics Through Complex Foaming Method by Using Porcelain Tile Residues
YANG Zanzhong1,2, WANG Han1, WANG Yongzai3, LIU Min1, DING Qi1, LI Chengfeng1, YUE Hongzhi1,2, WEI Chuncheng1,2
1 School of Materials Science and Engineering, Shandong University of Technology, Zibo 255049;
2 Shandong Engineering Research Demonstration Center of Ceramic-matrix Composites, Zibo 255049;
3 Analysis and Testing Center, Shandong University of Technology, Zibo 255049
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摘要 以抛光砖废渣粉为主要原料,采用复合发泡法制备高温发泡陶瓷。通过正交试验确定了发泡剂的复合比,研究了复合发泡机制及烧成制度对发泡体孔结构和性能的影响。结果表明,多种发泡剂协同作用,拓宽了单一发泡剂的放气温度区间,利于形成均匀封闭的气孔结构。按炭黑、碳酸钙、氧化铁、碳化硅质量比1∶3∶1.5∶1(四者占反应体系的总质量分数为6.5%)与瓷粉等混合制坯,程序升温至1 160 ℃下保温100 min,可制得闭气孔率为62.94%,气孔直径为1.2~1.9 mm,体积密度为369 kg/m3,吸水率为0.44%,导热系数为0.079 W/(m·K)的闭孔泡沫陶瓷。
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杨赞中
王涵
王永在
刘敏
丁琪
李成峰
乐红志
魏春城
关键词:  抛光砖废渣  闭孔泡沫陶瓷  复合发泡机制  复合发泡剂  烧成制度    
Abstract: The foamed ceramics was prepared by complex foaming process using porcelain tile residues as the raw material. The mass ratio of complex agents was determined by the orthogonal test, and the complex foaming mechanism and the firing system were investigated. It was shown that the temperature range of pore-forming was broadened when the complex agent foaming acted mutually, and that the homogeneous pore structure could be formed. Samples in investigation were prepared by adding complex foaming agents in accordance with the mass fraction (%) of carbon∶calcium carbonate∶iron(Ⅲ) oxide∶silicon carbide=1∶3∶1.5∶1, and being calcined at 1 160 ℃ for 100 min. The closed porosity of the foamed ceramics is 62.94%, and its pore diameters are 1.2—1.9 mm. The volume density, water absorption, and thermal conductivity of the resultant are 369 kg/m3, 0.44%, and 0.079 W/(m·K) respectively.
   
Key words:  polished tile residues    closed pore foamed ceramic    complex foaming mechanism    complex foaming agent    firing scheme
               出版日期:  2017-10-25      发布日期:  2018-05-05
ZTFLH:  TQ174.4+6  
基金资助: *山东省自然科学基金(ZR2012EMM016;ZR2014EL005);山东省科技发展计划(2014GZX201008);淄博市校城融合发展计划(2016ZBXC141);淄博市创新发展重点项目计划(2016CX16A011)
作者简介:  杨赞中:1963年生,博士,教授,博士研究生导师,研究方向为分子筛与微孔功能材料制备与表征 E-mail:yzz@sdut.edu.cn
引用本文:    
杨赞中, 王涵, 王永在, 刘敏, 丁琪, 李成峰, 乐红志, 魏春城. 抛光砖废渣复合发泡法制备闭孔泡沫陶瓷*[J]. 《材料导报》期刊社, 2017, 31(20): 119-123.
YANG Zanzhong, WANG Han, WANG Yongzai, LIU Min, DING Qi, LI Chengfeng, YUE Hongzhi, WEI Chuncheng. Preparation of Closed Pore Foamed Ceramics Through Complex Foaming Method by Using Porcelain Tile Residues. Materials Reports, 2017, 31(20): 119-123.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.020.025  或          http://www.mater-rep.com/CN/Y2017/V31/I20/119
1 Cai Zuguang. The processing of ceramic industrial waste slag [J]. Foshan Ceram, 2002,12(3):11(in Chinese).
蔡祖光. 陶瓷工业废料废渣的处理 [J]. 佛山陶瓷,2002,12(3):11.
2 Miao Songlan, Ma Guanghua, Li Qingtao, et al. Research on the preparation of light-weight ceramic material with the slag polished from building ceramics [J]. J Ceram, 2005,6(2):71(in Chinese).
缪松兰,马光华,李清涛,等. 建筑陶瓷抛光废渣制备轻质陶瓷材料的研究 [J].陶瓷学报,2005,6(2):71.
3 Amoros J L,Orts M J,Garca-Ten J. Effect of the green porous texture on porcelain tile properties [J]. J Am Chem Soc, 2007,27(5):2295.
4 Xia Guanghua, Zhao Xiaodong, Xie Sui, et al. The current situation in utilization of solid waste resource of ceramic industry [J]. Environ Eng, 2012(S2):302(in Chinese).
夏光华,赵晓东,谢穗,等. 陶瓷工业固体废物资源化利用现状 [J]. 环境工程,2012(S2):302.
5 Xi Xiuan, Shui Anze. Effects of magnesium oxychloride and silicon carbide additives on the foaming property during firing for porcelain ceramics and their microstructure [J]. J Eur Chem Soc, 2012,32(12):3035.
6 Zhou Mingkai, Peng Lifen, Wang Huaide, et al. Influence of iron oxide and foaming agent on the performance of coal gangue closed porosity ceramics [J]. China Ceram, 2015,51(2):77(in Chinese).
周明凯,彭丽芬,王怀德,等. 氧化铁和发泡剂对煤矸石闭孔发泡陶瓷的性能影响 [J].中国陶瓷,2015,51(2):77.
7 Wu Zhimin, Xu Jinfeng, Zhang Haixia, et al. Application research on thermal insulating board and fire barrier in building [J]. New Build Mater, 2010(10):1(in Chinese).
吴志敏,许锦峰,张海遐,等. 发泡陶瓷保温板保温系统及防火隔离带建筑应用研究 [J].新型建筑材料,2010(10):1.
8 Liu Bin, Liu Hui, Zhang Chunyan. Application of foamed ceramic thermal insulating board in roof engineering [J]. Chin Overseas Arch, 2012(11):102(in Chinese).
刘彬,刘辉,张春艳. 发泡陶瓷保温板在屋面工程中的应用 [J].中外建筑,2012(11):102.
9 Chi Yuezhang, Yu Aimin, Shen Guangyin, et al. The influence of forming pressure and firing temperature on producing closed porosity ceramics using solid residue and tailings [J]. China Ceram, 2009,45(10):69(in Chinese).
池跃章,余爱民,沈光银,等. 成型压力和烧成温度对利用废渣和尾矿制备闭孔发泡陶瓷的影响 [J].中国陶瓷,2009,45(10):69.
10Yu Kaiming, Jiang Chao, Yu Shaohua. The preparation of alumina foaming porous ceramics [J]. China Ceram, 2014,50(2):51(in Chinese).
余开明,江超,余少华. 氧化铝泡沫多孔陶瓷的制备 [J].中国陶瓷,2014,50(2):51.
11Li Yang, Gong Yingfang, Wang Lin. The preparation of alumina foaming porous ceramics [J]. Bull Chin Ceram Soc, 2014,33(7):1636(in Chinese).
黎阳,宫营方,汪林. 化学结合法低温制备氧化铝泡沫陶瓷的研究 [J].硅酸盐通报,2014,33(7):1636.
12García-Ten J, Saburit A, Bernardo E, et al. Development of light weight porcelain stoneware tiles using foaming agents [J]. J Am Chem Soc, 2012,32:745.
13Bernardin A M, Silva M J, Riella H G. Characterization of cellular ceramics made by porcelain tile residues [J]. Mater Sci Eng A, 2006,437(2):222.
14Shui Anze, Xia Haibin, Zeng Lingke, et al. Preparation of porous thermal insulation building material with tile polished waste[J]. Bull Chin Ceram Soc, 2008,27(1):191(in Chinese).
税安泽,夏海斌,曾令可,等. 利用抛光砖废料制备多孔保温建筑材料 [J].硅酸盐通报,2008,27(1):191.
15Huang Jian, Bao Qifu, Dong Weixia, et al. Research on foam ceramics with silicate waste [J]. China Ceram, 2014,50(12):78(in Chinese).
黄健,包启富,董伟霞,等. 用硅酸盐废弃物制备泡沫陶瓷的研究 [J]. 中国陶瓷,2014,50(12):78.
16Fernández-Jiménez A, De La Torre A G, Palomoa A, et al. Quantitative determination of phases in the alkali activation of fly ash. Part I. Potential ash reactivity [J]. Fuel, 2006,85(5):625.
17Liu Qiuxia, Han Qingrong. Mathematical analyses of factors affec-ting the bubble diameter of foam glass [J]. Bull Chin Ceram Soc, 1999(5):63(in Chinese).
刘秋霞,韩庆荣. 影响泡沫玻璃泡径因素的数学分析 [J]. 硅酸盐通报,1999(5):63.
18Shui Anze, Xi Xiuan, Wang Yanming, et al. Effect of silicon carbide additive on microstructure and properties of porcelain ceramics [J]. Ceram Int, 2010,37(5):1557.
19浙江大学,武汉工业大学,上海化工学院,等. 硅酸盐物理化学 [M]. 中国建筑工业出版社,1987:236.
20Jacobson N S. Kinetics and mechanism of corrosion of SiC by molten salts [J]. J Am Ceram Soc,1986,69:74.
21Gary R,Sun T W,Brown J R. High temperature alkali corrosion of SiC and S3N4[J]. Fuel Process Technol, 1995,44:213.
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