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材料导报  2020, Vol. 34 Issue (6): 6044-6048    https://doi.org/10.11896/cldb.19030196
  无机非金属及其复合材料 |
CoO和Cr2O3复合掺杂对金属陶瓷的致密化及抗高温氧化性的影响
林启权, 周行, 董文正, 钦椿凯
湘潭大学焊接机器人与应用技术湖南省重点实验室,湘潭 411105
Effect of CoO and Cr2O3 Composite Doping on Densification and High-temperature Oxidation Resistance of Cermets
LIN Qiquan, ZHOU Hang, DONG Wenzheng, QING Chunkai
Hunan Key Laboratory of Welding Robots and Applied Technologies, Xiangtan University, Xiangtan 411105, China
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摘要 采用粉末冶金技术制备添加CoO和Cr2O3复合掺杂剂的17Ni/(10NiO-NiFe2O4)金属陶瓷,使用XRD、SEM等检测分析了不同含量、不同比例的复合掺杂剂对金属陶瓷材料的物相组成、组织形貌、烧结致密化和抗高温氧化性的影响。结果表明:CoO和Cr2O3复合掺杂后固溶到陶瓷基体相NiFe2O4晶格中,促进了烧结致密化;CoO和Cr2O3复合掺杂有利于生成致密氧化层,有效抑制了氧气向材料内部侵蚀和金属Ni向外迁徙,提高了试样的抗高温氧化性能;当CoO和Cr2O3复合掺杂量为1%(质量分数)(m(CoO)∶m(Cr2O3)=2∶1)时,抗高温氧化性最好,单位面积氧化增重量比未掺杂的试样降低了56.28%。
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林启权
周行
董文正
钦椿凯
关键词:  惰性阳极  17Ni/(10NiO-NiFe2O4)金属陶瓷  CoO  Cr2O3  致密化  抗高温氧化性    
Abstract: The 17Ni/ (10NiO-NiFe2O4) cermets doped with CoO and Cr2O3 compound additives were prepared by powder metallurgy method. XRD, SEM and other means of detection and analysis were used to explore the impact of the CoO and Cr2O3 compound doped on 17Ni/ (10NiO-NiFe2O4) cermet on the phase composition, microstructure, sintering densification and high temperature oxidation resistance. The results showed that CoO and Cr2O3 become solid solution in the NiFe2O4 lattice after composite doping, accelerated the sintering-densification.The CoO and Cr2O3 complex additives helped 17Ni/ (10NiO-NiFe2O4) cermet form a dense oxide layer,which can reduce the diffusion rate of O2 and me-tal Ni,and improved the high temperature oxidation resistance. When the composite doped amount of CoO and Cr2O3 is 1wt% (m (CoO)∶m (Cr2O3)=2∶1),the sample has the best high temperature oxidation resistance, which the oxidation weight gain per unit was 56.28% less than the undoped sample.
Key words:  inert anode    17Ni/ (10NiO-NiFe2O4) cermet    CoO    Cr2O3    densification    high temperature oxidation resistance
               出版日期:  2020-03-25      发布日期:  2020-03-12
ZTFLH:  TF125  
  TG148  
基金资助: 科技部国际合作专项(2010DFA52130);国家自然科学基金(51575467)
作者简介:  林启权,教授,博士研究生导师,湘潭大学。主要从事金属塑性成形理论与模拟技术、板锻造成形工艺、特种材料的制备等研究;董文正,副教授,湘潭大学。主要从事先进塑性加工工艺及装备、塑性加工摩擦与润滑研究。
引用本文:    
林启权, 周行, 董文正, 钦椿凯. CoO和Cr2O3复合掺杂对金属陶瓷的致密化及抗高温氧化性的影响[J]. 材料导报, 2020, 34(6): 6044-6048.
LIN Qiquan, ZHOU Hang, DONG Wenzheng, QING Chunkai. Effect of CoO and Cr2O3 Composite Doping on Densification and High-temperature Oxidation Resistance of Cermets. Materials Reports, 2020, 34(6): 6044-6048.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19030196  或          http://www.mater-rep.com/CN/Y2020/V34/I6/6044
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