超声振荡对多壁碳纳米管/VARTM用环氧树脂复合材料导电性能的影响<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.03.018

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Abstract The dispersion of multi-walled carbon nanotubes (MWNTs) in VARTM epoxy resin (EP) was promoted by ultrasonic oscillations to prepare. MWNTs/EP composites through vacuum assisted resin transfer molding (VARTM) process, and subsequently the conductive properties were studied. Results showed that the conductive properties of the composites increased firstly and then decreased with the increase of ultrasonic time, power and frequency, and the composites with different MWNTs concentration had the similar change tendency. The threshold was reached when the ultrasonic time, power and frequency were 90 min, 80 W and 45 kHz, respectively. The addition of 1% MWNTs could reduce the surface resistance of epoxy resin (10¹² Ω·cm) by 4 orders of magnitude. Meanwhile, the dispersion of MWNTs in EP was verified by scanning electron microscopy (SEM).

Key words： multi-walled carbon nanotube ultrasonic oscillation epoxy resin conductive property

Published: 10 February 2017 Online: 2018-05-02

CLC number:

TB302

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	Articles by authors
	LIU Hesheng
	DUAN Xiangyu
	LAI Jiamei
	HUANG Xingyuan
	CHEN Lele

Cite this article:

LIU Hesheng,DUAN Xiangyu,LAI Jiamei, et al. Effect of Ultrasonic Oscillations on Conductive Properties of Multi-walled Carbon Nanotubes/VARTM Epoxy Resin Composites[J]. Materials Reports, 2017, 31(3): 112-115.

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https://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.03.018 OR https://www.mater-rep.com/EN/Y2017/V31/I3/112

1 Sandler J, Shaffer M S P, Prasse T, et al. Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties[J]. Polymer,1999,40(21):5967.
2 Gojny F H, Wichmann M H G, Fiedler B, et al. Influence of diffe-rent carbon nanotubes on the mechanical properties of epoxy matrix composites-A comparative study[J]. Compos Sci Technol,2005,65(15-16):2300.
3 Whan C J, Won K J, Chae J Y, et al. Electroactive shape-memory polyurethane composites incorporating carbon nanotubes[J]. Macromol Rapid Commun,2005,26(5):412.
4 Fiedler B, Gojny F H, Wichmann M H G, et al. Fundamental aspects of nano-reinforced composites[J]. Compos Sci Technol,2006,66(16):3115.
5 Price G J, White A J, Clifton A A. The effect of high-intensity ultrasound on solid polymers[J]. Polymer,1995,36(26):4919.
6 Sahoo N G, Rana S, Cho J W, et al. Polymer nanocomposites based on functionalized carbon nanotubes[J]. Prog Polym Sci,2010,35(7):837.
7 Shu C, Wang E, Jiang L, et al. High performance cathode based on carbon fiber felt for magnesium-air fuel cells[J]. Int J Hydrogen Energy,2013,38(14):5885.
8 Xiong G H, Liu J H, Sun J. Electronstatic self-assembly preparation and properties of crabon nanotube/epoxy composites[J]. Polym Mater Sci Eng,2013,27(1):136(in Chinese).
熊高虎,刘佳鸿,孙静.碳纳米管/环氧树脂复合材料的静电自组装制备及性能[J].高分子材料科学与工程,2013,27(1):136.
9 Felisberto M, Arias-Durán A, Ramos J A, et al. Influence of filler alignment in the mechanical and electrical properties of carbon nanotubes/epoxy nanocomposites[J]. Physica B: Condensed Matter,2012,407(16):3181.
10 Wang Z, Xu Y, Bajracharya S. The comparison of removing plug by ultrasonic wave, chemical deplugging agent and ultrasound-chemical combination deplugging for near-well ultrasonic processing technology[J]. Ultrason Sonochem,2015,27:339.
11 Chen L, Pang X J, Qu M Z, et al. Fabrication and characterization of polycarbonate/carbon nanotubes composites[J]. Composites Part A: Appl Sci Manuf,2006,37(9):1485.
12 Chen D, Weavers L K, Walker H W. Ultrasonic control of ceramic membrane fouling: Effect of particle characteristics[J]. Water Res,2006,40(4):840.
13 Thompson L H, Doraiswamy L K. Sonochemistry: Science and engineering[J]. Ind Eng Chem Res,1999,38(4):1215.
14 Luican A, Li G, Andrei E Y. Scanning tunneling microscopy and spectroscopy of graphene layers on graphite[J]. Solid State Commun,2009,149(27-28):1151.
15 Raman V, Abbas A. Experimental investigations on ultrasound mediated particle breakage[J]. Ultrason Sonochem,2008,15(1):55.
16 Thoma S G, Ciftcioglu M, Smith D M. Determination of agglome-rate strength distributions: Part 1. Calibration via ultrasonic forces[J]. Powder Technol,1991,68(1):53.
17 Lu K L, Lago R M, Chen Y K, et al. Mechanical damage of carbon nanotubes by ultrasound[J]. Carbon,1996,34(6):814.