四氧化三铁基材料在锂离子电池负极中的应用研究进展

doi:10.11896/cldb.25040057

材料导报

2026, Vol. 40

Issue (7): 25040057-9 https://doi.org/10.11896/cldb.25040057

无机非金属及其复合材料

四氧化三铁基材料在锂离子电池负极中的应用研究进展

张嘉龙¹, 刘巧宾^1,2, 刘树敏^1,2, 范俊梅^1,2, 孙艳荣^1,2, 武朝阳¹, 李冬至^1,2,*

1 北华航天工业学院材料工程学院,河北廊坊 065000
2 河北省热防护材料重点实验室,河北廊坊 065000

Research Progress on the Application of Fe₃O₄-based Materials as the Anode of Lithium-ion Batteries

ZHANG Jialong¹, LIU Qiaobin^1,2, LIU Shumin^1,2, FAN Junmei^1,2, SUN Yanrong^1,2, WU Zhaoyang¹, LI Dongzhi^1,2,*

1 College of Materials Engineering, North China Institute of Aerospace Engineering, Langfang 065000, Hebei, China
2 Hebei Provincial Key Laboratory of Thermal Protection Materials, Langfang 065000, Hebei, China

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摘要四氧化三铁(Fe₃O₄)作为具有转换反应机制的锂离子电池负极材料,具有理论容量高、资源丰富、成本低等优点,被认为是可代替石墨的极有潜力的材料之一。但该材料的电导率低,且充放电过程中会产生较大的体积膨胀,严重影响其电化学性能和循环稳定性。本文总结了四氧化三铁基锂离子电池负极材料在纳米化和复合化方面的研究进展,并对未来的发展前景进行了展望。

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	张嘉龙
	刘巧宾
	刘树敏
	范俊梅
	孙艳荣
	武朝阳
	李冬至

关键词: 四氧化三铁锂离子电池负极材料复合材料

Abstract: Fe₃O₄, as an anode electrode material for lithium-ion batteries with a conversion reaction mechanism, has the advantages of high theoretical capacity, abundant resources and cost-effectiveness. Consequently, it is regarded as one of the most promising candidates to replace graphite. However, this material exhibits low conductivity and significant volume expansion occurs during the charging and discharging process, which seriously affects its electrochemical performance and cycling stability. This paper provides a comprehensive overview of the research advancements in anode electrode materials for lithium-ion batteries, specifically focusing on iron oxide (Fe₃O₄) in terms of nanomaterialization and composite materials, and also anticipates future prospects in this field.

Key words: ferric oxides lithium-ion batteries anode materials composite materials

发布日期: 2026-04-16

ZTFLH:

O469

基金资助: 河北省高等学校科学技术研究项目(QN2021001);中央引导地方科技发展资金(226Z1007G);河北省高层次人才资助项目(B2024002);廊坊市科技局科学研究与发展计划自筹经费项目(2024011035)

通讯作者: *李冬至,博士,北华航天工业学院材料工程学院讲师、硕士研究生导师。目前主要从事微/纳米材料形貌调控、电化学、锂/钠离子电池负极材料等方面的研究。lidongzhi@iccas.ac.cn

作者简介: 张嘉龙,北华航天工业学院材料工程学院硕士研究生,在李冬至讲师的指导下研究锂离子电池负极材料的制备及应用。

引用本文:

张嘉龙, 刘巧宾, 刘树敏, 范俊梅, 孙艳荣, 武朝阳, 李冬至. 四氧化三铁基材料在锂离子电池负极中的应用研究进展[J]. 材料导报, 2026, 40(7): 25040057-9.
ZHANG Jialong, LIU Qiaobin, LIU Shumin, FAN Junmei, SUN Yanrong, WU Zhaoyang, LI Dongzhi. Research Progress on the Application of Fe₃O₄-based Materials as the Anode of Lithium-ion Batteries. Materials Reports, 2026, 40(7): 25040057-9.

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https://www.mater-rep.com/CN/10.11896/cldb.25040057 或 https://www.mater-rep.com/CN/Y2026/V40/I7/25040057

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