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材料导报  2025, Vol. 39 Issue (24): 24120191-6    https://doi.org/10.11896/cldb.24120191
  无机非金属及其复合材料 |
分散剂对SiO2气凝胶粉体在水性体系中分散性能的影响
廖木子1, 何亮2,3, 王保凯1, 牛梦阳1, 孙畅1, 袁昀琪1, 曹文斌1,*, 王琦1,*
1 北京科技大学材料科学与工程学院,北京 100083
2 武汉理工大学材料科学与工程学院,武汉 430070
3 北新集团建材股份有限公司,北京 100096
Influence of Dispersants on the Dispersion Performance of SiO2 Aerogel Powder in Aqueous Systems
LIAO Muzi1, HE Liang2,3, WANG Baokai1, NIU Mengyang1, SUN Chang1, YUAN Yunqi1,CAO Wenbin1,*, WANG Qi1,*
1 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
2 School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
3 Beijing New Building Materials Public Limited Company, Beijing 100096, China
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摘要 SiO2气凝胶因其具有轻质、多孔结构及独特的光学、热学和声学性能,在建筑节能、航空航天等领域展现出广泛的应用潜力。然而,SiO2气凝胶粉体比表面积大、易团聚、难以在水性体系中分散,限制了其进一步应用。本工作通过添加不同类型的分散剂,降低SiO2气凝胶粉体颗粒间的相互作用力,提高其在水性介质中的分散稳定性。采用扫描电子显微镜、比表面积等表征了SiO2气凝胶的性质,采用激光粒度仪、沉降测试等评价了SiO2气凝胶在水性体系中的分散性能。研究发现,阴离子和非离子型分散剂能显著提高分散性,而阳离子分散剂则导致团聚加剧。通过复配分散剂及优选分散剂用量,进一步优化了分散效果。研究结果为SiO2气凝胶在水性体系中的应用提供了理论依据。
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廖木子
何亮
王保凯
牛梦阳
孙畅
袁昀琪
曹文斌
王琦
关键词:  二氧化硅气凝胶  水性体系  分散剂  分散稳定性    
Abstract: Silica (SiO2) aerogel, due to its lightweight, porous structure, unique optical, thermal and acoustic properties, shows great potential for applications in building energy conservation, aerospace, and other fields. However, silica aerogel powder has a large specific surface area, easy to be agglomerated and difficult to disperse in aqueous systems, all of which limit its further application. This study aims to reduce the interactive forces between SiO2 particles and improve their dispersion stability in aqueous media by adding dispersants. The properties of SiO2 aerogels were characterized by scanning electron microscopy and specific surface area, and the dispersion properties of SiO2 aerogels in aqueous systems were evaluated by laser particle size meter and sedimentation test. The study found that anionic and non-ionic dispersants could significantly improve dispersion, while cationic dispersants led to increased agglomeration. By combining dispersants and optimizing the amount of dispersant, the dispersion effect was further optimized. The findings provide a theoretical basis for the application of SiO2 aerogel in aqueous systems.
Key words:  SiO2 aerogel    aqueous systems    dispersants    dispersion stability
出版日期:  2025-12-25      发布日期:  2025-12-17
ZTFLH:  TB321  
基金资助: 国家重点研发计划(2023YFB3812304)
通讯作者:  *曹文斌,博士,北京科技大学材料科学与工程学院教授、博士研究生导师。目前主要从事半导体光催化材料及其产业化应用研究。wbcao@ustb.edu.cn;王琦,博士,北京科技大学材料科学与工程学院教授、博士研究生导师。目前主要从事功能陶瓷材料制备及热管理应用研究。wangqi15@ustb.edu.cn   
作者简介:  廖木子,北京科技大学材料科学与工程学院硕士研究生,在王琦教授的指导下进行研究。目前主要研究领域为气凝胶材料合成及应用。
引用本文:    
廖木子, 何亮, 王保凯, 牛梦阳, 孙畅, 袁昀琪, 曹文斌, 王琦. 分散剂对SiO2气凝胶粉体在水性体系中分散性能的影响[J]. 材料导报, 2025, 39(24): 24120191-6.
LIAO Muzi, HE Liang, WANG Baokai, NIU Mengyang, SUN Chang, YUAN Yunqi,CAO Wenbin, WANG Qi. Influence of Dispersants on the Dispersion Performance of SiO2 Aerogel Powder in Aqueous Systems. Materials Reports, 2025, 39(24): 24120191-6.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24120191  或          https://www.mater-rep.com/CN/Y2025/V39/I24/24120191
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