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材料导报  2025, Vol. 39 Issue (21): 24090163-10    https://doi.org/10.11896/cldb.24090163
  高分子与聚合物基复合材料 |
网状材料阻燃聚合物的研究进展
潘也唐1,2,*, 李天宇1, 徐云蕾1, 苗伟佳1
1 北京理工大学材料学院,北京 100081
2 国家阻燃材料工程技术研究中心,北京 100095
Advances in Reticular Materials for Flame Retardant Polymers
PAN Yetang1,2,*, LI Tianyu1, XU Yunlei1, MIAO Weijia1
1 School of Materials Science ＆ Engineering, Beijing Institute of Technology, Beijing 100081, China
2 National Engineering Research Center of Flame Retardant Materials, Beijing 100095, China
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摘要 网状化学为新型复合材料的研发提供了新思路。近年来,许多科研人员对网状材料在各种高分子材料中的阻燃效果和机理进行了研究,利用网状材料比表面积大、孔隙率高、易于化学功能化、纳米结构可设计性好等特点,主要对金属有机框架材料(MOFs)、共价有机框架材料(COFs)、氢键有机框架材料(HOFs)的特性进行调整,用于各种聚合物中,设计出阻燃性能更强的聚合物复合材料。网状复合材料的设计是改善聚合物复合材料燃烧性能的新解决方案,非常有必要进行综合和系统的梳理。目前还没有关于网状材料在阻燃领域研究进展的综述,因此本文全面综述了MOFs、COFs和HOFs在阻燃高分子材料方面的最新研究进展,主要针对环氧树脂、聚氨酯及其他聚合物,分析了三种材料在对应聚合物材料中应用的改性策略和阻燃效果,最后对未来基于网状材料的聚合物复合阻燃剂研究面临的机遇和挑战进行简要的评论。
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潘也唐
李天宇
徐云蕾
苗伟佳
关键词:  网状材料  阻燃  阻燃机理  高分子材料    
Abstract: The emergence of reticular materials has introduced innovative approaches in the development of new composite materials, particularly in enhancing fire-retardant properties. Recent studies have focused on the flame retardancy effects and mechanisms of reticular materials in va-rious polymer matrices. Leveraging the characteristics of these materials—including their high specific surface area, large porosity, ease of che-mical functionalization, and excellent design flexibility in nanostructures, researchers have adjusted the properties of metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs) for incorporation into diverse polymers, resulting in the design of composites with improved flame retardancy. The design of reticular composites represents a promising solution for enhancing the combustion performance of polymeric materials. Despite its importance, a comprehensive review on the progress of reticular materials in the field of flame retardancy is still lacking. Therefore, this paper provides a thorough review of the latest advancements in MOFs, COFs, and HOFs concerning flame-retardant polymer materials. It specifically examines modification strategies and flame-retardant effects for epoxy resins, polyurethanes, and other polymers. Finally, we offer a brief commentary on future research opportunities and challenges related to polymer composite flame retardants based on reticular materials.
Key words:  reticular material    flame retardancy    flame retardant mechanism    polymer composite
出版日期:  2025-11-10      发布日期:  2025-11-10
ZTFLH:  TQ317.9  
基金资助: 国家级大学生创新创业训练计划(202410007038X);国家自然科学基金(22375023);重庆市自然科学基金(CSTB2024NSCQ-MSX0452);河北省自然科学基金(E2024105006);中央高校基本科研业务费专项资金(2024CX06053);北京理工大学大学生创新训练计划(BIT2023LH250)
通讯作者:  *潘也唐,博士,副教授、博士研究生导师。主要研究方向为功能高分子与阻燃材料。pyt@bit.edu.cn   
引用本文:    
潘也唐, 李天宇, 徐云蕾, 苗伟佳. 网状材料阻燃聚合物的研究进展[J]. 材料导报, 2025, 39(21): 24090163-10.
PAN Yetang, LI Tianyu, XU Yunlei, MIAO Weijia. Advances in Reticular Materials for Flame Retardant Polymers. Materials Reports, 2025, 39(21): 24090163-10.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24090163  或          https://www.mater-rep.com/CN/Y2025/V39/I21/24090163
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