木质素及其复合抗紫外屏蔽材料的研究进展

doi:10.11896/cldb.24080218

材料导报

2025, Vol. 39

Issue (17): 24080218-9 https://doi.org/10.11896/cldb.24080218

高分子与聚合物基复合材料

木质素及其复合抗紫外屏蔽材料的研究进展

黄思淼¹, 李晓玉¹, 吴新宇¹, 连海兰^1,2,*

1 南京林业大学材料科学与工程学院,南京 210037
2 南京林业大学林业资源高效加工利用协同创新中心,南京 210037

Research Progress on UV Resistance of Lignin and Its Composite Materials

HUANG Simiao¹, LI Xiaoyu¹, WU Xinyu¹, LIAN Hailan^1,2,*

1 College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
2 Jiangsu Co-Innovation Centre of Efficient Processing and Utilization of Forest Products, Nanjing Forestry University, Nanjing 210037, China

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摘要木质素因富含酚羟基和酮基等结构,具备天然的广谱紫外防护能力和抗氧化特性,近年来在紫外屏蔽材料中的应用研究受到关注。本文从紫外线的产生、基本特征和吸收原理出发,简单介绍了木质素的结构、紫外吸收机制,综述了木质素在防晒霜、生物可降解紫外屏蔽膜及光管理材料中的应用进展。针对未经处理的木质素的紫外线屏蔽性能较低,且存在形态不规则、分散性差、粒径大和异质性等缺陷,仍不能满足大多数应用需求的问题,概括了木质素与其他紫外屏蔽剂、紫外吸收剂、光稳定剂等多种材料复合后的木质素基复合抗紫外屏蔽材料的研究现状,提出了未来的发展方向,以期为木质素基复合材料抗紫外性能的研究提供参考。

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关键词: 木质素紫外屏蔽木质素复合材料抗氧化性

Abstract: Lignin, due to its abundance of phenolic hydroxyl and carbonyl groups, possesses natural broad-spectrum UV protection and antioxidant pro-perties. In recent years, research on its application in UV-shielding materials has garnered attention. This paper begins by introducing the generation, basic characteristics, and absorption mechanisms of ultraviolet radiation, followed by a brief overview of lignin's structure and its UV absorption mechanism. It then reviews the progress of lignin applications in sunscreen formulations, biodegradable UV-shielding films, and light management materials. Given that untreated lignin exhibits relatively low UV shielding performance and suffers from issues such as irregular morphology, poor dispersibility, large particle size, and heterogeneity, which limit its applicability, the current research status of lignin-based compo-site UV-shielding materials, where lignin is combined with other UV blockers, UV absorbers, and light stabilizers, is summarized. Lastly, future development directions are proposed, offering a reference for further research into enhancing the UV protection performance of lignin-based composite materials.

Key words: lignin UV shielding lignin composites oxidation resistance

发布日期: 2025-08-28

ZTFLH:

TQ423

基金资助: 国家自然科学基金(32071703)

通讯作者: *连海兰,南京林业大学材料科学与工程学院教授、博士研究生导师。主要从事环保型木材胶黏剂与涂料、木质素等生物质纳米复合材料的绿色制备及功能性应用等方面的教学与科研工作。lianhailan@njfu.edu.cn

作者简介: 黄思淼,南京林业大学材料科学与工程学院硕士研究生,在连海兰教授的指导下进行研究。目前主要研究方向为木质素复合材料的绿色制备、环保型木材胶粘剂的合成。

引用本文:

黄思淼, 李晓玉, 吴新宇, 连海兰. 木质素及其复合抗紫外屏蔽材料的研究进展[J]. 材料导报, 2025, 39(17): 24080218-9.
HUANG Simiao, LI Xiaoyu, WU Xinyu, LIAN Hailan. Research Progress on UV Resistance of Lignin and Its Composite Materials. Materials Reports, 2025, 39(17): 24080218-9.

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https://www.mater-rep.com/CN/10.11896/cldb.24080218 或 https://www.mater-rep.com/CN/Y2025/V39/I17/24080218

1 El-Hiti G A, Ahmed D S, Yousif E, et al. Polymers, 2021, 14, 20.
2 Lu T, Solis-Ramos E, Yi Y, et al. Polymer Degradation and Stability, 2018, 154, 203.
3 Nazari M H, Zhang Y, Mahmoodi A, et al. Progress in Organic Coa-tings, 2022, 162, 106573.
4 Tor-Świątek A, Garbacz Ł. Advances in Science and Technology. Research Journal, 2022, 16(3), 282.
5 Kaur R, Thakur N S, Chandna S, et al. Journal of Materials Chemistry B, 2020, 8(2), 260.
6 Xing Q, Buono P, Ruch D, et al. ACS Sustainable Chemistry & Engineering, 2019, 7(4), 4147.
7 Baker L A, Marchetti B, Karsili T N V, et al. Chemical Society Reviews, 2017, 46(12), 3770.
8 Andrady A L, Heikkilä A M, Pandey K K, et al. Photochemical & Photobiological Sciences, 2023, 22(5), 1177.
9 Yu J C, Yu J G, Ho W K, et al. Chemistry of Materials, 2002, 14, 3808.
10 Yin H, Casey P S. Materials Letters, 2014, 121, 8.
11 Agustiany E A, Rasyidur M, Rahmi D N M, et al. Polymer Composites, 2022, 43(8), 4848.
12 Barsberg S, Elder T, Felby C. Chemistry of Materials, 2003, 15, 649.
13 Lanzalunga O, Bietti M. Journal of Photochemistry and Photobiology B:Biology, 2000, 56(2-3), 85.
14 Singer S, Schwarz T, Berneburg M, et al. Grundlagen zur phototherapie, Springer Fachmedien Wiesbaden, DE, 2016, pp. 1.
15 Zhabotinsky A M, Eager M D, Epstein I R. Physical Review Letters, 1993, 71(10), 1526.
16 Bohren C F, Huffman D R. Absorption and Scattering of Light by Small Particles, 2007, 2, 57.
17 Nowicki M, Richter A, Wolf B, et al. Polymer, 2003, 44(21), 6599.
18 Colli L. Physical Review, 1954, 95(4), 892.
19 Yu H, Xu L, Yang F, et al. Bulletin of Environmental Contamination and Toxicology, 2021, 107(2), 221.
20 Sheng Y, Lam S S, Wu Y, et al. Bioresource Technology, 2021, 324, 124631.
21 Zhao Z M, Liu Z H, Pu Y Q, et al. Chemsuschem, 2020, 13(20), 5423.
22 Zakzeski J, Bruijnincx P C A, Jongerius A L, et al. Chemical Reviews, 2010, 110(6), 3552.
23 Chen J C, Liu W X, Yang G H, et al. Chemistry of papermaking plant resources, Science Press, China, 2012, pp. 205 (in Chinese).
陈嘉川, 刘温霞, 杨桂花, 等. 造纸植物资源化学, 科学出版社, 2012, pp. 205.
24 Ou J F, Chen Z D, Zhang H, et al. Transactions of China Pulp and Paper, 2024, 39(2), 61(in Chinese).
欧金芬, 陈振东, 张涵, 等. 中国造纸学报, 2024, 39(2), 61.
25 Gillet S, Aguedo M, Petitjean L, et al. Green Chemistry, 2017, 19(18), 4200.
26 You T, Xu F. Spectroscopy to Current Research in the Chemical and Biological Sciences, 2016, 2016, 235.
27 Lee S C, Tran T M T, Choi J W, et al. International Journal of Biological Macromolecules, 2019, 122, 549.
28 Paulsson M, Parkås J. Bioresources, 2012, 7(4), 5995.
29 Guo Y, Tian D, Shen F, et al. Polymers, 2019, 11(9), 1455.
30 Lim J, Sana B, Krishnan R, et al. Chemistry—An Asian Journal, 2018, 13(3), 284.
31 Li Y, Zhao S, Hu D, et al. ACS Sustainable Chemistry & Engineering, 2022, 10(36), 11856.
32 Antunes F, Mota I F, Fangueiro J F, et al. International Journal of Biological Macromolecules, 2023, 234, 123592.
33 Li Z, Chen L, Qiu X. Industrial Crops and Products, 2024, 208, 117857.
34 Li X, Liu Y, Ren X. International Journal of Biological Macromolecules, 2022, 216, 86.
35 Ban W, Song J, Lucia L A. Industrial & Engineering Chemistry Research, 2007, 46(20), 6480.
36 Mehta M J, Kumar A. Chemistry—A European Journal, 2019, 25(5), 1269.
37 Xiong F, Wu Y, Li G, et al. Industrial & Engineering Chemistry Research, 2018, 57(4), 1207.
38 Hong S, Park J H, Kim O Y, et al. Polymers, 2021, 13, 667.
39 Long H, Hu L, Yang F, et al. Composites Part B: Engineering, 2022, 239, 109968.
40 Shojaeiarani J, Bajwa D S, Ryan C, et al. Industrial Crops and Products, 2022, 183, 114904.
41 Yang W, Zhu Y, He Y, et al. Industrial Crops and Products, 2022, 183, 114965.
42 Zhang Y, Zhou S, Fang X, et al. European Polymer Journal, 2019, 116, 265.
43 Li S, Cui B, Xie H, et al. ACS Applied Materials & Interfaces, 2022, 14(37), 42522.
44 Liu D, Li Y, Qian Y, et al. ACS Sustainable Chemistry & Engineering, 2017, 5(9), 8424.
45 Agumba D O, Kumar B, Panicker P S, et al. Optical Materials, 2022, 133, 112898.
46 Alhaffar M T, Akhtar M N, Ali S A. RSC Advances, 2019, 9, 21265.
47 Li Y Y, Wang Y, Xu J L, et al. Journal of Advances in Physical Chemistry, 2022, 11(3), 79(in Chinese).
李洋洋, 王岩, 许静蕾, 等. 物理化学进展, 2022, 11(3), 79
48 Yu J, Li L, Qian Y, et al. Industrial & Engineering Chemistry Research, 2018, 57(46), 15740.
49 Morsella M, D'alessandro N, Lanterna A E, et al. ACS Omega, 2016, 1(3), 464.
50 Li Y, Yang D, Lu S, et al. ACS Sustainable Chemistry & Engineering, 2019, 7(6), 6234.
51 Li L S, Wang T. Electronic Components and Materials, 2021, 40(4), 328(in Chinese).
李林森, 汪涛. 电子元件与材料, 2021, 40(4), 328.
52 Hong C H, Yang L, Zhu W C. Guangdong Chemical Industry, 2024, 51(14), 62(in Chinese).
洪春水, 杨雷, 祝文才. 广东化工, 2024, 51(14), 62.
53 Gutiérrez-Hernández J M, Escalante A, Murillo-Vázquez R N, et al. Journal of Photochemistry and Photobiology B:Biology, 2016, 163, 156.
54 Wang H, Qiu X, Liu W, et al. Industrial & Engineering Chemistry Research, 2017, 56(39), 11133.
55 Wang H, Lin W, Qiu X, et al. ACS Sustainable Chemistry & Engineering, 2018, 6(3), 3696.
56 Li X, Xiao J, Wei W, et al. International Journal of Biological Macromolecules, 2023, 225, 1405.
57 Song Y, Wu X, Ma C, et al. Journal of Liaoning Petrochemical University, 2024, 44(3), 10(in Chinese).
宋悦, 吴限, 马诚, 等. 辽宁石油化工大学学报, 2024, 44(3), 10.
58 Marković D, Petkovska J, Mladenovic N, et al. Journal of Applied Polymer Science, 2023, 140(19), e53823.
59 Shankar S, Rhim J W. Food Hydrocolloids, 2017, 71, 76.
60 Shankar S, Rhim J W, Won K. International Journal of Biological Macromolecules, 2018, 107, 1724.
61 Qian Y, Qiu X, Zhu S. ACS Sustainable Chemistry & Engineering, 2016, 4(7), 4029.
62 Chen H. Lignocellulose Biorefinery Engineering, 2015, 1, 37.
63 Qiu X, Li Y, Qian Y, et al. ACS Applied Bio Materials, 2018, 1, 1276.
64 Bortolus P, Dellonte S, Faucitano A, et al. Macromolecules, 1986, 19(12), 2916.
65 Nikafshar S, McCracken J, Dunne K, et al. Progress in Organic Coa-tings, 2021, 151, 105843.
66 Kocaefe D, Saha S. Applied Surface Science, 2012, 258(13), 5283.
67 Ohkatsu Y. Journal of the Japan Petroleum Institute, 2008, 51, 191.

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