氯碱电解与碱性水电解制氢关键材料的对比与展望

doi:10.11896/cldb.24070135

材料导报

2025, Vol. 39

Issue (17): 24070135-7 https://doi.org/10.11896/cldb.24070135

无机非金属及其复合材料

氯碱电解与碱性水电解制氢关键材料的对比与展望

徐宇翔^1,2, 张冰², 董迁², 朱其轩¹, 唐宏², 陈松³, 徐桂银^1,*

1 东华大学材料科学与工程学院,纤维材料改性国家重点实验室,上海 201620
2 江苏安凯特科技股份有限公司,江苏无锡 214400
3 盐城工学院化学化工学院,江苏盐城 224051

Comparative Analysis and Prospect of Key Materials for Hydrogen Production by Chlor-alkali Electrolysis and Alkaline Water Electrolysis

XU Yuxiang^1,2, ZHANG Bing², DONG Qian², ZHU Qixuan¹, TANG Hong², CHEN Song³, XU Guiyin^1,*

1 State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
2 Jiangsu Ancan Technology Co., Ltd., Wuxi 214400, Jiangsu, China
3 School of Chemistry & Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu, China

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摘要氢能作为绿色清洁能源可以通过电解技术有效获取,氯碱为电解技术工业化生产的典型行业,本文通过研究氯碱工业副产氢和水电解制氢技术,将两种技术发展历程及原理进行对比,总结出技术路线较为成熟的碱性水电解制氢为目前规模化工业生产的最快方法。同时论述电极材料及催化材料和膜材料分别在氯碱电解槽和碱性水电解制氢电解槽中的发展、工业化应用概况和最新研究,通过对比得到碱性水电解制氢与氯碱电解可以相互借鉴的研发思路,系统对比两种技术作为关键性材料的电极和膜的工业化应用概况及发展方向,为实现降低能耗、提高电解槽性能的目的提供理论依据,进一步推动碱性水电解制氢技术的发展。

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	徐宇翔
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	徐桂银

关键词: 电解技术氯碱工业副产氢碱性水电解制氢

Abstract: Hydrogen energy as a green and clean energy can be effectively obtained by electrolysis technology, chlor-alkali is a typical industry in industrialized production of electrolytic technology. The development course and principles of hydrogen production by-product from chlor-alkali industry and alkaline water electrolysis are compared. It is considered that the technical route of alkaline water electrolysis hydrogen production is mature, which is the fastest method for large-scale industrial production at present. At the same time, the development, survey of industrial application and latest research of electrode materials, catalysts and membrane materials in chlor-alkali electrolyzer and alkaline water hydrogen electrolyzer respectively were discussed. Through comparison, the research and development ideas of hydrogen production by alkaline water electrolysis and chlor-alkali electrolysis can learn from each other are obtained, the industrial application and development direction of electrodes and membranes with these two technologies as key materials are compared systematically, which provides basis for reducing energy consumption and improving the performance of electrolyzers, and further promotes the development of hydrogen production by alkaline water electrolysis technology.

Key words: electrolytic technology chlor-alkali by-product hydrogen alkaline water product hydrogen

发布日期: 2025-08-28

ZTFLH:	TQ151
	TQ116

通讯作者: *徐桂银,东华大学材料科学与工程学院、纤维材料改性国家重点实验室研究员、博士研究生导师,麻省理工学院博士后,入选2023全球前2%顶尖科学家。主要研究方向为功能纤维膜在绿色能源与环境修复中的应用。xuguiyin@dhu.edu.cn

作者简介: 徐宇翔,东华大学材料科学与工程学院博士研究生,目前主要研究领域为电解水制氢催化剂材料。

引用本文:

徐宇翔, 张冰, 董迁, 朱其轩, 唐宏, 陈松, 徐桂银. 氯碱电解与碱性水电解制氢关键材料的对比与展望[J]. 材料导报, 2025, 39(17): 24070135-7.
XU Yuxiang, ZHANG Bing, DONG Qian, ZHU Qixuan, TANG Hong, CHEN Song, XU Guiyin. Comparative Analysis and Prospect of Key Materials for Hydrogen Production by Chlor-alkali Electrolysis and Alkaline Water Electrolysis. Materials Reports, 2025, 39(17): 24070135-7.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24070135 或 https://www.mater-rep.com/CN/Y2025/V39/I17/24070135

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