染料负载型MOFs复合材料用作发光中心材料的研究进展

doi:10.11896/cldb.24060108

材料导报

2025, Vol. 39

Issue (12): 24060108-12 https://doi.org/10.11896/cldb.24060108

金属与金属基复合材料

染料负载型MOFs复合材料用作发光中心材料的研究进展

王逸飞¹, 张月^1,*, 赵鹏程^1,*, 由岫²

1 中国刑事警察学院刑事科学技术学院,沈阳 110035
2 甘肃省公安厅刑警总队,兰州 730000

Research Progress of Dye-supported MOFs Composites as Luminescent Center Materials

WANG Yifei¹, ZHANG Yue^1,*, ZHAO Pengcheng^1,*, YOU Xiu²

1 College of Criminal Science and Technology, Criminal Investigation Police University of China, Shenyang 110035, China
2 Criminal Police Detachment, Gansu Provincial Public Security Department, Lanzhou 730000, China

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摘要随着金属有机框架材料(MOFs)的快速发展,将荧光染料负载到MOFs上形成的复合系统作为一类新型功能性发光材料受到广泛关注。该类材料通过合理设计MOFs主体基质和选择发光基团,实现了从紫外到近红外范围的可控发光,并在白光发射、可调谐发光以及特定波长高效发光等方面展现出巨大的应用潜力。本文介绍了染料负载在MOFs中的不同方式,深入分析了MOFs与染料分子组合的普遍性要求,包括孔径与染料分子尺寸的匹配、相关材料的发光机理、主客体相互作用类型及化学稳定性等。在此基础上,讨论了基于不同负载原理选择的制备方法来优化发光性能。随后,列举了染料负载型MOFs在白光发射、可调谐发光及其他发光方面的最新研究成果,并探讨了其在其他新兴应用中的潜力。最后,综述了当前的研究进展,展望了未来研究方向和应用前景,并指出了其在发光领域的广阔发展潜力。

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关键词: 金属有机框架材料染料负载发光材料光电技术颜色可调性白光发射

Abstract: The rapid development of metal-organic framework materials (MOFs) has generated significant interest in the composite systems formed by integrating fluorescent dyes into MOFs as novel functional luminescent materials. By meticulously designing the MOF matrix and selecting suitable luminescent groups, these materials can achieve controlled luminescence across a wide spectrum, ranging from ultraviolet to near-infrared. This controlled luminescence shows great potential for applications in white light emission, tunable luminescence, and efficient luminescence at specific wavelengths. This review presents the diverse approaches of dye loading in MOFs and analyzes the general requirements for the combination of MOF and dye molecules, encompassing the matching of pore size and the size of dye molecules, the luminescence mechanism of related materials, the type of host-guest interaction, and chemical stability. On this basis, the selection of preparation methods based on different loading principles was studied to optimize the luminescence performance. Subsequently, the latest research on white light emission, tunable luminescence, and other luminescences of dye-supported MOFs materials is reviewed, and their potential in other nascent applications is discussed. Finally, the current research progress is reexamined, the future research direction and application prospects are envisioned, and the broad deve-lopment potential of dye-supported MOFs composites in the luminescence field is indicated.

Key words: metal-organic frame material dye loading luminous material photoelectric technology color adjustability white light emission

出版日期: 2025-06-25 发布日期: 2025-06-19

ZTFLH:

O611.3

基金资助: 公安部科技强警基础工作专项(2022JC03;2023JC05);中国刑事警察学院科学研究项目(D2022044)

通讯作者: ^*张月,中国刑事警察学院刑事科学技术学院讲师。目前主要从事金属有机骨架及其复合材料的合成及传感等方面的研究工作。zhangyue1022_cipuc@163.com
赵鹏程,中国刑事警察学院刑事科学技术学院教授、硕士研究生导师。目前主要从事功能材料、枪弹和发射药分析和公安科技的研究工作。zhaopengcheng@cipuc.edu.cn

作者简介: 王逸飞,现为中国刑事警察学院刑事科学技术学院硕士研究生,在赵鹏程教授和张月老师的指导下进行研究。目前主要研究领域为染料负载型MOFs复合材料的荧光传感检测性能和公安科技等。

引用本文:

王逸飞, 张月, 赵鹏程, 由岫. 染料负载型MOFs复合材料用作发光中心材料的研究进展[J]. 材料导报, 2025, 39(12): 24060108-12.
WANG Yifei, ZHANG Yue, ZHAO Pengcheng, YOU Xiu. Research Progress of Dye-supported MOFs Composites as Luminescent Center Materials. Materials Reports, 2025, 39(12): 24060108-12.

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https://www.mater-rep.com/CN/10.11896/cldb.24060108 或 https://www.mater-rep.com/CN/Y2025/V39/I12/24060108

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