一维陶瓷相增强的含碳耐火材料研究进展

doi:10.11896/cldb.24070074

材料导报

2025, Vol. 39

Issue (9): 24070074-9 https://doi.org/10.11896/cldb.24070074

无机非金属及其复合材料

一维陶瓷相增强的含碳耐火材料研究进展

张红¹, 鄢文^2,*, 李楠², 张会¹, 陈哲², 李维泰¹

1 西安建筑科技大学华清学院,西安 710043
2 武汉科技大学先进耐火材料全国重点实验室,武汉 430081

Research Progress of One-dimensional Ceramic Reinforced Carbon-containing Refractories

ZHANG Hong¹, YAN Wen^2,*, LI Nan², ZHANG Hui¹, CHEN Zhe², LI Weitai¹

1 Xi'an University of Architecture and Technology Huaqing College, Xi'an 710043, China
2 The State Key Laboratory of Advanced Refractory Materials, Wuhan University of Science and Technology, Wuhan 430081, China

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摘要含碳耐火材料是钢铁冶炼过程中一种重要的功能耐火材料,其良好的热震稳定性和抗渣侵蚀性显著延长了材料的使用寿命。但含碳耐火材料在高温下易被氧化,从而导致其力学性能和高温服役性能变差,这是其应用受限的主要原因。通过对含碳耐火材料进行一维陶瓷相增强可显著提高其力学性能和高温服役性能,已成为当前含碳耐火材料的研究热点之一。本文以含碳耐火材料为研究对象,详细梳理了分布于基质(碳纤维、碳纳米管、碳化硅晶须、莫来石晶须)和分布于轻骨料-基质界面(轻骨料-碳化硅晶须和轻骨料-尖晶石)两种方式来制备一维陶瓷相增强的含碳耐火材料的相关研究成果,介绍和分析了两种策略下一维陶瓷相增强的含碳耐火材料的力学性能和高温服役性能的研究进展,总结了其制备过程中存在的问题,并展望了含碳耐火材料的未来研究方向。

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关键词: 含碳耐火材料一维陶瓷相基质骨料-基质界面性能优化

Abstract: Carbon-containing refractory is a kind of crucial functional refractory in the process of iron and steel smelting. Its excellent thermal shock stability and slag erosion resistance can significantly improve the service life of the material. However, the mechanical properties and high temperature service performances of carbon-containing refractory become worse due to the fact that the carbon-containing refractories are easy to be oxidized at high temperature, which is the main reason for their limited application. The enhancement of one-dimensional ceramic phase in carbon-containing refractories can remarkably increase their mechanical properties and high temperature service performances, which has become one of the research hotspots of carbon-containing refractories. Herein, the present review takes the carbon-containing refractory as the research object, and detailly discusses the preparation of one-dimensional ceramic reinforced carbon-containing refractories by optimizing the matrix (carbon fiber, carbon nanotubes, SiC whisker, mullite whisker) and regulating the microporous aggregate-matrix interface (microporous aggregate-SiC whisker and microporous aggregate-spinel). The mechanical properties and high temperature service performances of one-dimensional ceramic reinforced carbon-containing refractories under two strategies are introduced, and the problems in the preparation process are also summarized. Meanwhile, the future research direction of carbon-containing refractories is prospected.

Key words: carbon-containing refractory one-dimensional ceramic phase matrix aggregate-matrix interface performance optimization

出版日期: 2025-05-10 发布日期: 2025-04-28

ZTFLH:

TQ175.14

基金资助: 国家自然科学基金(U21A2058);湖北省科技计划项目(2024CSA075);国家级大学生创新训练计划项目(202413679002);陕西省教育厅科研计划项目(23JK0522)

通讯作者: ^*鄢文,博士,武汉科技大学材料学部三级教授、博士研究生导师。目前主要从事耐火材料、熔融金属过滤器等方面的研究工作。yanwen@wust.edu.cn

作者简介: 张红,硕士。现为西安建筑科技大学华清学院专职教师,目前主要研究领域为含碳耐火材料性能增强以及轻量化。

引用本文:

张红, 鄢文, 李楠, 张会, 陈哲, 李维泰. 一维陶瓷相增强的含碳耐火材料研究进展[J]. 材料导报, 2025, 39(9): 24070074-9.
ZHANG Hong, YAN Wen, LI Nan, ZHANG Hui, CHEN Zhe, LI Weitai. Research Progress of One-dimensional Ceramic Reinforced Carbon-containing Refractories. Materials Reports, 2025, 39(9): 24070074-9.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24070074 或 https://www.mater-rep.com/CN/Y2025/V39/I9/24070074

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