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材料导报  2025, Vol. 39 Issue (5): 24010233-12    https://doi.org/10.11896/cldb.24010233
  无机非金属及其复合材料 |
SAMs在n-i-p型钙钛矿太阳能电池界面工程中的应用
陈浩霖1,2, 赵佳薇1,2, 张俊豪1,2, 于博1,2, 张强飞1,2, 罗倪1,*, 刘振国1,2,*
1 西北工业大学宁波研究院,浙江 宁波 315000
2 西北工业大学柔性电子研究院,西安 710000
Applications of Self-assembled Monolayers for Interface Engineering of n-i-p Perovskite Solar Cells
CHEN Haolin1,2, ZHAO Jiawei1,2, ZHANG Junhao1,2, YU Bo1,2, ZHANG Qiangfei1,2, LUO Ni1,*, LIU Zhenguo1,2,*
1 Ningbo Institute of Northwestern Polytechnical University, Ningbo 315000, Zhejiang, China
2 Institute of Flexible Electronics, Northwestern Polytechnical University, Xi’an 710000, China
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摘要 钙钛矿太阳能电池(PSCs)因其优异的光电性能,被誉为极具发展前景的第三代太阳能电池。然而,PSCs各功能层界面处的非辐射复合影响着器件的光电性能和稳定性。自组装单分子层(SAMs)作为抑制器件界面非辐射复合的界面工程材料,在制备高效稳定PSCs的研究中取得了实际效果。因此,本综述总结了SAMs在n-i-p型PSCs界面工程中的应用,并对非辐射复合路径和SAMs进行介绍。最后,基于当前SAMs在PSCs中的研究趋势作出展望,助力PSCs技术的进一步发展。
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陈浩霖
赵佳薇
张俊豪
于博
张强飞
罗倪
刘振国
关键词:  钙钛矿太阳能电池  非辐射复合  自组装单分子层  界面工程    
Abstract: Perovskite solar cells (PSCs) are considered as the promising third generation solar cells due to their excellent photoelectric performance. However, the non-radiative recombination at the interfaces of the functional layers of PSCs affects the photoelectric performance and stability of the devices. Self-assembled monolayers (SAMs), as interface engineering materials to suppress non-radiative recombination at the device interfaces, have achieved practical results in fabricating highly efficient and stable PSCs. Therefore, this reviews summarizes the application of SAMs in the interface engineering of n-i-p PSCs, and also introduces non-radiative recombination pathways and SAMs. Finally, based on the current research trends of SAMs in PSCs, an outlook is made to facilitate the further development of PSCs technology.
Key words:  perovskite solar cells    non-radiative recombination    self-assembled monolayers    interface engineering
出版日期:  2025-03-10      发布日期:  2025-03-18
ZTFLH:  TB34  
基金资助: 宁波市重点研发计划(2023Z151);工业和信息化部高质量发展专项(TC220A04A-206);浙江省“尖兵”“领雁”研发攻关计划项目(2024C01251(SD2))
通讯作者:  *罗倪,工学博士,现为西北工业大学宁波研究院博士后,目前主要从事钙钛矿太阳能电池、电子浆料和发光材料的研究。luoni0515@163.com
刘振国,西北工业大学宁波研究院研究员,主要研究领域为功能分子树脂合成、配方优化、特种高分子薄膜材料,以及高分子高性能复合材料的开发和应用,已掌握了相关高分子特种材料的核心关键技术。iamzgliu@nwpu.edu.cn   
作者简介:  陈浩霖,西北工业大学柔性电子研究院硕士研究生,在刘振国研究员的指导下进行研究。目前主要研究领域为钙钛矿太阳能电池。
引用本文:    
陈浩霖, 赵佳薇, 张俊豪, 于博, 张强飞, 罗倪, 刘振国. SAMs在n-i-p型钙钛矿太阳能电池界面工程中的应用[J]. 材料导报, 2025, 39(5): 24010233-12.
CHEN Haolin, ZHAO Jiawei, ZHANG Junhao, YU Bo, ZHANG Qiangfei, LUO Ni, LIU Zhenguo. Applications of Self-assembled Monolayers for Interface Engineering of n-i-p Perovskite Solar Cells. Materials Reports, 2025, 39(5): 24010233-12.
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https://www.mater-rep.com/CN/10.11896/cldb.24010233  或          https://www.mater-rep.com/CN/Y2025/V39/I5/24010233
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