In Situ Fabrication of Graphene on Polycrystalline Diamond Surface Vapor-Phase-catalyzed by Manganese
WU Guodong1,2, ZHANG Wen1,*, FU Xin1,2, LIU Huiqiang2, WANG Jian3, WANG Bing2, XIONG Ying1,2,*
1 State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China 2 School of Materials and Chemistry, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China 3 School of Mathematics and Physics, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
Abstract: Diamond and graphene both have excellent physical and chemical properties. The combination of them to form graphene-diamond heterojunction can give full play to the excellent properties of both, which has have attracted numerous attentions. In the preparation of graphene-diamond heterojunction devices, the conventional methods, such as transfer method and metal in situ catalyzed method, have the disadvantages of complicated steps, high cost, incomplete graphene coverage and poor crystallographic quality, which seriously hinder the application of such all-carbon devices. In this paper, a new method of in-situ fabrication of graphene on diamond surface was developed, i.e., polycrystalline diamond was catalyzed by manganese vapor to achieve the in-situ growth of graphene on the polycrystalline diamond surface. The results show that the manganese vapor phase has a strong catalytic effect on polycrystalline diamond surface, and the graphene layer generated by this method has high coverage and uniform surface. This novel manganese vapor catalysis method is simple, low-cost and can be accomplished in one step. In this paper, we provide a new technical route for the in-situ growth of high-quality graphene on the diamond surface, and a new idea for the preparation of high performance graphene-diamond heterojunction all-carbon devices.
1 Sang M, Shin J, Kim K, et al. Nanomaterials, 2019, 9, 375. 2 Wu S X, He Q Y, Tan C L, et al. Small, 2013, 9(8), 1160. 3 Fujimoto Y. Modern Physics Letters B, 2021, 35, 2130001. 4 Yu J, Liu G, Sumant A V, et al. Nano Letters, 2012, 12, 1603. 5 Wort C J H, Balmer R S. Materials Today, 2008, 11, 22. 6 Wu Y Z, Jelfzko F, Plenio M B, et al. Angewandte Chemie-International Edition, 2016, 55, 6586. 7 Millan J, Godignon P, Perpina X, et al. IEEE Transactions on Power Electronics, 2014, 29(5), 2155. 8 Yuan Q, Lin C-T, Chee K W A. APL Materials, 2019, 7, 30901. 9 Rizzo D J, Veber G, Cao T, et al. Nature, 2018, 560, 204. 10 Xu X, Liu C, Sun Z, et al. Chemical Society Reviews, 2018, 47, 3099. 11 Freitag M, Steiner M, Martin Y, et al. Nano Letters, 2009, 9(5), 1883. 12 Zhao F, Vrajitoarea A, Jiang Q, et al. Scientific Reports, 2015, 5, 13771. 13 Mirabedini P S, Debnath B, Neupane M R, et al. Applied Physics Letters, 2020, 117, 121901. 14 Asad M, MajdiS, Vorobiev A, et al. IEEE Electroon Device Letters, 2022, 43(2), 300. 15 Ueda K, Mizuno Y, Asano H. Applied Physics Letters, 2020, 117, 092103. 16 Mizuno Y, Ito Y, Ueda K. Carbon, 2021, 182, 669. 17 Wang S, Bqi Q, Chen S. Crystal Research and Technology, 2023, 2300122. 18 Ueda K, Aichi S, Asano H. Diamond and Related Materials, 2016, 63, 148. 19 Kanada S, Nagai M, Ito S, et al. Diamond and Related Materials, 2017, 75, 105. 20 Shen B, Ji Z, Lin Q, et al. Chemistry of Materials, 2022, 34, 3941. 21 Tulić S, Waitz T, Čaolov ová M, et al. Carbon, 2021, 185, 300. 22 Tulić S, Waitz T, Čaolov ová M, et al. ACS Nano, 2019, 13, 4621. 23 Bakharev P V, Huang M, Saxena M, et al. Nature Nanotechnology, 2020, 15, 59. 24 Okpalugo T I T, Papakonstantinou P, Murphy, et al. Carbon, 2005, 43, 153. 25 Habibi A, Khoie S M M, Mahboubi F, et al. Surface & Coatings Technology, 2017, 309, 945. 26 Malard L M, Pimenta M A, Dresselhaus G, et al. Physics Reports, 2009, 473, 51. 27 Yavari F, Kritzinger C, Gaire C, et al. Small, 2010, 6(22), 2535. 28 Hu W, Li Z Y, Yanga J L. The Journal of Chemical Physics, 2013, 138, 054701. 29 Gui Q Z, Wang Z, Cheng C M, et al. Applied Physics Letters, 2022, 121, 211601.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2025, Vol. 39 
