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材料导报  2025, Vol. 39 Issue (16): 24080059-11    https://doi.org/10.11896/cldb.24080059
  高分子与聚合物基复合材料 |
光催化解聚木质素及其模型化合物的研究进展
唐瑞欣1,2, 朱子琪1,2, 王玲1,2, 杨培1,2,*, 周晓燕1,2,*
1 南京林业大学林业资源高效加工利用协同创新中心,南京 210037
2 南京林业大学材料科学与工程学院,南京 210037
Research Progress on Photocatalytic Depolymerization of Lignin and Its Model Compounds
TANG Ruixin1,2, ZHU Ziqi1,2, WANG Ling1,2, YANG Pei1,2,*, ZHOU Xiaoyan1,2,*
1 Collaborative Innovation Center for Efficient Processing and Utilization of Forestry Resources of Nanjing Forestry University, Nanjing 210037, China
2 School of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
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摘要 作为自然界含量最多的天然芳香族化合物,木质素用于生产精细化学品和可再生燃料是绿色化学研究领域的热点之一,其中,木质素高效解聚是实现其高值化利用的关键。近年来,光催化解聚木质素作为一种温和绿色的可持续解聚策略备受关注。该策略能够选择性地断裂C-O和C-C连接键,并将木质素转化为高附加值的芳香族单体。对此,本文概述了用于光催化解聚木质素及其模型化合物的均相和非均相催化剂,进一步阐释了C-O和C-C连接键裂解的反应途径和催化机理,深入探讨了光催化剂结构对催化效率、木质素转化率和产物收率的影响,对比评估了不同的反应装置在光催化解聚木质素体系中的适用性,最后就木质素光催化解聚面临的主要挑战和未来的发展方向提出建议和思路。
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唐瑞欣
朱子琪
王玲
杨培
周晓燕
关键词:  木质素  模型化合物  光催化剂  解聚机理  反应装置    
Abstract: Since lignin is the only renewable biopolymer that has abundant aromatic ring structure in nature, the depolymerization of lignin can provide raw materials for high value-added platform compounds and fine chemicals to relieve the security of fossil energy and the derivative environmental concerns. However, it is difficult to depolymerize lignin into monomeric phenols based on retaining the free phenolic hydroxyl groups and alcohol hydroxyl groups due to the complexity, recalcitrance and low chemical reactivity of lignin itself. Recently, photocatalysis has become a sustainable and fascinated paradigm for the high-quality conversion of lignin because of its ability to accurately cleave the C-O and C-C bonds of lignin and its model compounds under mild conditions. Herein, both homogeneous and heterogeneous photocatalysts were introduced and discussed about how to increase their photocatalytic performances by elemental doping and defect design. This review also analyzed the reaction pathways and mechanisms involved in the process of lignin depolymerization. In addition, the suitability and rationality of different reaction devices were evaluated in a comparative manner, especially in the efficiency and selectivity of photocatalytic depolymerization. Finally, the existing problems and feasible solutions in terms of this strategy were proposed, which may provide the basis and reference for the high-valued green transformation of lignin biomass.
Key words:  lignin    model compound    photocatalyst    depolymerization mechanism    reaction device
出版日期:  2025-08-15      发布日期:  2025-08-15
ZTFLH:  O636.2  
基金资助: 国家自然科学基金(32271784)
通讯作者:  杨培,南京林业大学材料科学与工程学院博士后。目前主要从事生物质基功能材料与绿色胶粘剂等方面的研究工作。peiyang@njfu.edu.cn;周晓燕,博士,南京林业大学材料科学与工程学院教授、博士研究生导师。目前主要从事生物质先进功能材料等方面的研究。zhouxiaoyan@njfu.edu.cn   
作者简介:  唐瑞欣,南京林业大学材料科学与工程学院硕士研究生,在周晓燕教授和杨培博士的指导下开展光催化氧化降解木质素及木材胶粘剂改性方向的研究。
引用本文:    
唐瑞欣, 朱子琪, 王玲, 杨培, 周晓燕. 光催化解聚木质素及其模型化合物的研究进展[J]. 材料导报, 2025, 39(16): 24080059-11.
TANG Ruixin, ZHU Ziqi, WANG Ling, YANG Pei, ZHOU Xiaoyan. Research Progress on Photocatalytic Depolymerization of Lignin and Its Model Compounds. Materials Reports, 2025, 39(16): 24080059-11.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24080059  或          https://www.mater-rep.com/CN/Y2025/V39/I16/24080059
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