The special structure and excellent properties of carbon nanotubes make it the preferred filler for composites. This paper summarized the development of the studies on the orientation and alignment of CNTs in polymers induced by electric field. The factors which influence the orientation and alignment of CNTs in electric field are analyzed, such as electric field type, surface functionalization of CNTs, application time, CNTs size and content. The improvement of CNTs alignment reinforced composites in mechanical, electrical, and thermal properties is discussed. The mechanisms of orientation of CNTs and the characterization method of CNTs orientation degree were analyzed.
董怀斌,李长青,邹霞辉. 电场诱导碳纳米管在聚合物中定向有序排列的研究进展[J]. 《材料导报》期刊社, 2018, 32(3): 427-433.
Huaibin DONG,Changqing LI,Xiahui ZOU. Research Progress of Orientation and Alignment of Carbon Nanotubes in Polymer Implemented by Applying Electric Field. Materials Reports, 2018, 32(3): 427-433.
Hou L C, Liu H H, Wang N , et al. Preparation and characterization of carboxylic multi-walled carbon nanotubes/PA6 composites by solution mixing process[J]. Acta Material Composite Sinica, 2013,30(1):45(in Chinese).
Mannik J, Goldsmith B R, Kane A , et al. Chemically induced conductance switching in carbon nanotube circuits[J]. Physical Review Letters, 2006,97(1):1.
3
Ovak J P, Snow E S, Houser E J , et al. Nerve agent detection using networks of single-walled carbon nanotubes[J]. Applied Physics Letters, 2003,83(19):4026.
4
Liu Z, Cai W, He L , et al. In vivo biodistribution and highly efficient tumor targeting of carbon nanotubes in mice[J]. Nature Nanotechnology, 2007,2:47.
5
Zhou R, Wang P, Chang H C . Bacteria capture, concentration and detection by alternating current dielectrophoresis and self-assembly of dispersed single-wall carbon nanotubes[J]. Electrophoresis, 2006,27:1376.
6
Lu X, Chen Z . Curved pi-conjugation, aromaticity, and the related chemistry of small fullerenes (
7
Hong S, Myung S . Nanotube electronics: A flexible approach to mobility[J]. Nature Nanotechnology, 2007,2(4):207.
8
Thostenson E T, Ren Z, Chou T W . Advances in the science and technology of carbon nanotubes and their composites: A review[J]. Composites Science and Technology, 2001,61:1899.
9
Chen Z, Yang Y, Wu Z , et al. Electric-fieldenhanced assembly of single-walled carbon nanotubes on a solid surface[J]. Journal of Physical Chemistry B, 2005,109:5473.
10
Hone J, Llaguno M C, Nemes N M , et al. Electrical and thermal transport properties of magnetically aligned single wall carbon nanotube films[J]. Applied Physics Letters, 2000,77:666.
11
Hobbie E K, Wang H, Kim H , et al. Optical measurements of structure and orientation in sheared carbon-nanotube suspensions[J]. Review of Scientific Instruments, 2003,74:1244.
12
Valentini D, Puglia P, Carniato F , et al. Use of plasma fluorinated single-walled carbon nanotubes for the preparation of nanocomposites with epoxy matrix[J]. Composites Science and Technology, 2008,68:1008.
13
Zhang Hongyan . Preparation of unsaturated resin/graphite nanosheets conductive composites induced by electric field[D]. Xiamen:Huaqiao University, 2006(in Chinese).
13
张红艳 . 电场诱导制备不饱和树脂/纳米石墨微片复合导电材料[D]. 厦门:华侨大学, 2006.
14
Yamamoto K, Akita S, Nakayama Y . Orientation and purification of carbon nanotubes using ac electrophoresis[J]. Journal of Physics D—Applied Physics, 1998,31(8):34.
15
Lu Q, Liu S, Gan Z Y , et al. Directional technology of carbon nanotubes in various dispersants[J]. Nanotechnology and Precision Engineering, 2009,7(1):1(in Chinese).
Benedict L X, Louie S G, Cohen M L . Static polarizabilities of singlewall carbon nanotubes[J]. Physical Review B, 1995,52(11):8541.
18
Zhu S Q, Zhu W H, Ye H H . Controlled processing of carbon nanotubes[J]. Chenistry Bulletin, 2004,10:744(in Chinese).
18
朱世琴, 朱为宏, 叶红华 . 碳纳米管的定向操作[J]. 化学通报, 2004,10:744.
19
Martin C A , Sandler J K W, Windle A H, et al. Electric field-induced aligned multi-wall carbon nanotube networks in epoxy composites[J]. Polymer, 2005,46:877.
20
Li Yuxin . Prepation and property of carbon nanotubes hierarchical composites by chemical/electrophoretic method[D]. Harbin:Harbin Institute of Technology, 2014(in Chinese).
Barrau S, Demont P, Peigny A , et al. DC and AC conductivity of carbon nanotubes-polyepoxy composites[J]. Macromolecules, 2003,36(14):5187.
22
Zheng Guodong, Zhang Qingjie, Deng Huoying , et al. Effect of different functionalized carbon nanotubes on mechanical properties of MWCNTs-carbon fiber/epoxy composites[J]. Acta Materiae Compositae Sinica, 2015,32(3):640(in Chinese).
Zhang Mingyan, Sui Shan, Chen Jinyu , et al. Study of properties of functional multi-walled carbon nanotubes/epoxy nanocomposites[J]. Transactions of China Electrotechnical Society, 2014,29(4):97(in Chinese).
Ma P C, Mo S Y, Tang B Z , et al. Dispersion, interfacial interaction and re-agglomeration of functionalized carbon nanotubes in epoxy composites[J]. Carbon, 2010,48(6):1824.
25
Ma C, Zhang W, Zhu Y F , et al. Alignment and dispersion of functionalized carbon nanotubes in polymer composites induced by an electric field[J]. Carbon, 2008,46:706.
26
Rosca I D, Watari F, Uo M , et al. Oxidation of multiwalled carbon nanotubes by nitric acid[J]. Carbon, 2005,43(15):3124.
27
Marshall M W, Popa N S, Shapter J G . Measurement of functio-nalised carbon nanotube carboxylic acid groups using a simple chemical process[J]. Carbon, 2006,44(7):1137.
28
Koerner H, Jacobs D, Tomlin D W , et al. Tuning polymer nanocomposite morphology: AC electric field manipulation of epoxy-montmorillonite (clay) suspensions[J]. Advanced Materials, 2004,16(4):297.
29
Oliva-Aviles A I, Aviles F, Sosa V , et al. Dielectrophoretic mode-ling of the dynamic carbon nanotube network formation in viscous media under alternating current electric fields[J]. Carbon, 2014,69:342.
30
Chapkin W A , McNerny D Q, Aldridge M F, et al. Real-time assessment of carbon nanotube alignment in a polymer matrix under an applied electric field via polarized Raman spectroscopy[J]. Polymer Testing, 2016,56:29.
31
Park C, Wilkinson J, Banda S , et al. Aligned single-wall carbon nanotubes polymer composite using an electric field[J]. Journal of Polymer Science B, 2006,44:1751.
32
Marco M, Maurizio N, Luigi T , et al. The alignment of single walled carbon nanotubes in an epoxy resin by applying a DC electric field[J]. Carbon, 2012,50:2453.
33
Jiang Q, Wang X, Zhu Y T , et al. Mechanical, electrical and thermal properties of aligned carbon nanotube/polyimide composites[J]. Composites:Part B, 2014,56:408.
34
Risi C L S, Hattenhauer I, Ramos A , et al. A contribution from dielectric analysis to the study of the formation of multi-wall carbon nanotubes percolated networks in epoxy resin under an electric field[J]. Materials Chemistry and Physics, 2015,160:289.
35
Murugesh A K, Uthayanan A, Lekakou C . Electrophoresis and orientation of multiple wall carbon nanotubes in polymer solution[J]. Applied Physics A, 2010,100:135.
36
Zhang R P, Zhu Y F, Ma C , et al. Alignment of carbon nanotubes in poly(methyl methacrylate) composites induced by electric field[J]. Journal of Nanoscience and Nanotechnology, 2009,9:2887.
37
Ymamoto K, Akita S, Nakayama Y . Orientation and purification of carbon nanotubes using ac electrophoresis[J]. Journal of Physics D:Applied Physics, 1998,31:34.
38
Ymamoto K, Akita S, Nakayama Y . Orientation of carbon nanotubes using electrophoresis[J]. Japanese Journal of Applied Phy-sics, 1996,35:917.
39
Hong C E, Lee J H, Kalappa P , et al. Effects of oxidative conditions on properties of multi-walled carbon nanotubes in polymer nanocomposites[J]. Composites Science and Technology, 2007,67(6):1027.
40
Senthil K M, Lee S H, Kim T Y , et al. DC electric field assisted alignment of carbon nanotubes on metal electrodes[J]. Solid-State Electronics, 2003,47:2075.
41
Ma P C, Siddiqui N A, Maroom G , et al. Dispersion and functiona-lization of carbon nanotubes for polymer-based nanocomposites: A review[J]. Composites Part A:Applied Science and Manufac-turing, 2010,41:1345.
42
Ma C, Liu H Y, Du X , et al. Fracture resistance, thermal and electrical properties of epoxy composites containing aligned carbon nanotubes by low magnetic field[J]. Composites Science and Technology, 2015,114:126.
43
Gupta P, Rajput M, Singla N , et al. Electric field and current assisted alignment of CNT inside polymer matrix and its effects on electrical and mechanical properties[J]. Polymer, 2016,89:119.
44
Wang Q, Dai J, Li W , et al. The effects of CNT alignment on electrical conductivity and mechanical properties of SWNT/epoxy nanocomposites[J]. Composites Science and Technology, 2008,68:1644.
45
Felisberto M, Arias D A, Ramos J A . Influence of filler alignment in the mechanical and electrical properties of carbon nanotubes/epoxy nanocomposites[J]. Physica B:Condensed Matter, 2012,407:3181.
46
Shafi U K, Jayaram R P, Jang-Kyo K , et al. Effects of carbon nanotube alignment onelectrical and mechanical properties of epoxy nanocomposites[J]. Composites Part A:Applied Science and Manufactu-ring, 2013,49:26.
47
Barrau S, Demont P, Peigny A , et al. DC and AC conductivity of carbon nanotubes-polyepoxy composites[J]. Macromolecules, 2003,36(14):5187.
48
Zhu Y F, Ma C, Zhang W , et al. Alignment of multiwalled carbon nanotubes in bulk epoxy composites via electric field[J]. Journal of Applied Physics, 2009,105(5):431.
49
Bauhofer W, Kovacs J Z . A review and analysis of electrical percolation in carbon nanotube composites[J]. Composites Science and Technology, 2009,69:1486.
50
Prassea T, Cavaille J Y, Bauhoferb W , et al. Electric anisotropy of carbon nanofibre/epoxy resin composites due to electric field induced alignment[J]. Composites Science and Technology, 2003,63:1835.
51
Ladani R B, Wu S, Kinloch A J , et al. Improving the toughness and electrical conductivity of epoxy nanocomposites by using aligned carbon nanofibres[J]. Composites Science and Technology, 2015,117:146.
52
Castellano J, Akin C, Giraldo G , et al. Electrokinetics of scalable, electric-field-assisted fabrication of vertically aligned carbon-nanotube/polymer composites[J]. Journal of Applied Physics, 2015,117:214306.
53
Laruani M M, Khamse E J, Asadollahi Z , et al. Effect of aligned carbon nanotubes on electrical conductivity behaviour in polycarbo-nate matrix[J]. Journal of Materials Science, 2012,35(3):305.
54
Fischer J E, Zhou W, Vavro J , et al. Magnetically aligned single wall carbon nanotube films:preferred orientation and anisotropic transport properties[J]. Journal of Applied Physics, 2003,93(4):2157.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2018, Vol. 32 
